Flexible and Extensive Platinum Ion Gel Condensers for Programmable Catalysis

Onn, Tzia Ming; Oh, Kyung-Ryul; Adrahtas, Demetra Z.; Soeherman, Jimmy K.; Hopkins, Justin A.; Frisbie, C. Daniel; Dauenhauer, Paul J.

doi:10.1021/acsnano.3c09815

Title: Flexible and Extensive Platinum Ion Gel Condensers for Programmable Catalysis

Journal Article · Tue Dec 26 00:00:00 EST 2023 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.3c09815· OSTI ID:2263306

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Univ. of Minnesota, Minneapolis, MN (United States)

Catalytic condensers composed of ion gels separating a metal electrode from a platinum-on-carbon active layer were fabricated and characterized to achieve more powerful, high surface area dynamic heterogeneous catalyst surfaces. Ion gels comprised of poly(vinylidene difluoride)/1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide were spin coated as a 3.8 μm film on a Au surface, after which carbon sputtering of a 1.8 nm carbon film and electron-beam evaporation of 2 nm Pt clusters created an active surface exposed to reactant gases. Electronic characterization indicated that most charge condensed within the Pt nanoclusters upon application of a potential bias, with the condenser device achieving a capacitance of ~20 μF/cm² at applied frequencies of up to 120 Hz. The maximum charge of ~10¹⁴ |e^–| cm^–2 was condensed under stable device conditions at 200 °C on catalytic films with ~10¹⁵ sites cm^–2. Grazing incidence infrared spectroscopy measured carbon monoxide adsorption isobars, indicating a change in the CO* binding energy of ~19 kJ mol^–1 over an applied potential bias of only 1.25 V. Finally, condensers were also fabricated on flexible, large area Kapton substrates allowing stacked or tubular form factors that facilitate high volumetric active site densities, ultimately enabling a fast and powerful catalytic condenser that can be fabricated for programmable catalysis applications.

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Research Organization:: Univ. of Minnesota, Minneapolis, MN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0023464

OSTI ID:: 2263306

Journal Information:: ACS Nano, Vol. 18, Issue 1; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
energy
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Title: Flexible and Extensive Platinum Ion Gel Condensers for Programmable Catalysis

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References (52)

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