Mapping growth windows in quaternary perovskite oxide systems by hybrid molecular beam epitaxy

Brahlek, Matthew; Zhang, Lei; Zhang, Hai-Tian; Lapano, Jason; Engel-Herbert, Roman; Dedon, Liv R.; Martin, Lane W.

doi:10.1063/1.4962388

Title: Mapping growth windows in quaternary perovskite oxide systems by hybrid molecular beam epitaxy

Journal Article · Mon Sep 05 00:00:00 EDT 2016 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4962388· OSTI ID:22594289

Brahlek, Matthew; Zhang, Lei; Zhang, Hai-Tian; Lapano, Jason; Engel-Herbert, Roman ^[1]; Dedon, Liv R.; Martin, Lane W. ^[2]

Department of Materials Science and Engineering, Pennsylvania State University, University Park, Pennsylvania 16801 (United States)
Department of Materials Science and Engineering, University of California, Berkeley, California 94720 (United States)

Requisite to growing stoichiometric perovskite thin films of the solid-solution A′{sub 1-x}A{sub x}BO{sub 3} by hybrid molecular beam epitaxy is understanding how the growth conditions interpolate between the end members A'BO{sub 3} and ABO{sub 3}, which can be grown in a self-regulated fashion, but under different conditions. Using the example of La{sub 1-x}Sr{sub x}VO{sub 3}, the two-dimensional growth parameter space that is spanned by the flux of the metal-organic precursor vanadium oxytriisopropoxide and composition, x, was mapped out. The evolution of the adsorption-controlled growth window was obtained using a combination of X-ray diffraction, atomic force microscopy, reflection high-energy electron-diffraction (RHEED), and Rutherford backscattering spectroscopy. It is found that the stoichiometric growth conditions can be mapped out quickly with a single calibration sample using RHEED. Once stoichiometric conditions have been identified, the out-of-plane lattice parameter can be utilized to precisely determine the composition x. This strategy enables the identification of growth conditions that allow the deposition of stoichiometric perovskite oxide films with random A-site cation mixing, which is relevant to a large number of perovskite materials with interesting properties, e.g., high-temperature superconductivity and colossal magnetoresistance, that emerge in solid solution A′{sub 1-x}A{sub x}BO{sub 3}.

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OSTI ID:: 22594289

Journal Information:: Applied Physics Letters, Vol. 109, Issue 10; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951

Country of Publication:: United States

Language:: English

References (41)

Highly Conductive SrVO ₃ as a Bottom Electrode for Functional Perovskite Oxides Moyer, Jarrett A.; Eaton, Craig; Engel-Herbert, Roman Advanced Materials, Vol. 25, Issue 26 https://doi.org/10.1002/adma.201300900	journal	May 2013
Possible highT c superconductivity in the Ba?La?Cu?O system Bednorz, J. G.; M�ller, K. A. Zeitschrift f�r Physik B Condensed Matter, Vol. 64, Issue 2 https://doi.org/10.1007/bf01303701	journal	June 1986
Metal-insulator transitions Paesler, Michael Journal of Non-Crystalline Solids, Vol. 130, Issue 1 https://doi.org/10.1016/0022-3093(91)90162-y	journal	June 1991
Fillingness dependence of electronic structures in strongly correlated electron systems: Titanates and vanadates Tokura, Y. Journal of Physics and Chemistry of Solids, Vol. 53, Issue 12 https://doi.org/10.1016/0022-3697(92)90152-4	journal	December 1992
Ferromagnetic compounds of manganese with perovskite structure Jonker, G. H.; Van Santen, J. H. Physica, Vol. 16, Issue 3 https://doi.org/10.1016/0031-8914(50)90033-4	journal	March 1950
Electrical conductivity of ferromagnetic compounds of manganese with perovskite structure Van Santen, J. H.; Jonker, G. H. Physica, Vol. 16, Issue 7-8 https://doi.org/10.1016/0031-8914(50)90104-2	journal	July 1950
Physical properties of polycrystalline SrVO3−δ Maekawa, Takuji; Kurosaki, Ken; Yamanaka, Shinsuke Journal of Alloys and Compounds, Vol. 426, Issue 1-2 https://doi.org/10.1016/j.jallcom.2006.02.026	journal	December 2006
Growth and properties of GdTiO3 films prepared by hybrid molecular beam epitaxy Moetakef, Pouya; Ouellette, Daniel G.; Zhang, Jack Y. Journal of Crystal Growth, Vol. 355, Issue 1 https://doi.org/10.1016/j.jcrysgro.2012.06.052	journal	September 2012
Elastic and thermodynamic properties of AVO3 (A=Sr, Pb) perovskites Parveen, Atahar; Gaur, N. K. Physica B: Condensed Matter, Vol. 407, Issue 3 https://doi.org/10.1016/j.physb.2011.11.023	journal	February 2012
First-principles calculations of the elastic and electronic properties of the cubic perovskites SrMO3 (M=Ti, V, Zr and Nb) in comparison with SrSnO3 Shein, I. R.; Kozhevnikov, V. L.; Ivanovskii, A. L. Solid State Sciences, Vol. 10, Issue 2 https://doi.org/10.1016/j.solidstatesciences.2007.09.013	journal	February 2008
Further experimental investigations on some ferromagnetic oxidic compounds of manganese with perovskite structure Volger, J. Physica, Vol. 20, Issue 1-6 https://doi.org/10.1016/s0031-8914(54)80015-2	journal	January 1954
Colossal magnetoresistive manganites Tokura, Y.; Tomioka, Y. Journal of Magnetism and Magnetic Materials, Vol. 200, Issue 1-3 https://doi.org/10.1016/s0304-8853(99)00352-2	journal	October 1999
Observation of the quantum Hall effect in δ-doped SrTiO3 Matsubara, Y.; Takahashi, K. S.; Bahramy, M. S. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11631	journal	May 2016
Epitaxial SrTiO₃ films with electron mobilities exceeding 30,000 cm² V^-1 s^-1 Son, Junwoo; Moetakef, Pouya; Jalan, Bharat Nature Materials, Vol. 9, Issue 6, p. 482-484 https://doi.org/10.1038/nmat2750	journal	April 2010
Unexpected mass acquisition of Dirac fermions at the quantum phase transition of a topological insulator Sato, T.; Segawa, Kouji; Kosaka, K. Nature Physics, Vol. 7, Issue 11 https://doi.org/10.1038/nphys2058	journal	August 2011
Materials Fundamentals of Molecular Beam Epitaxy Tsao, Jeffrey Y.; Harbison, James P. Physics Today, Vol. 46, Issue 10 https://doi.org/10.1063/1.2809075	journal	October 1993
Defects and transport in complex oxide thin films Ohnishi, Tsuyoshi; Shibuya, Keisuke; Yamamoto, Takahisa Journal of Applied Physics, Vol. 103, Issue 10 https://doi.org/10.1063/1.2921972	journal	May 2008
Molecular beam epitaxy of SrTiO3 with a growth window Jalan, Bharat; Moetakef, Pouya; Stemmer, Susanne Applied Physics Letters, Vol. 95, Issue 3 https://doi.org/10.1063/1.3184767	journal	July 2009
Stoichiometry optimization of homoepitaxial oxide thin films using x-ray diffraction LeBeau, James M.; Engel-Herbert, Roman; Jalan, Bharat Applied Physics Letters, Vol. 95, Issue 14 https://doi.org/10.1063/1.3243696	journal	October 2009
Enhancing the electron mobility of SrTiO3 with strain Jalan, Bharat; Allen, S. James; Beltz, Glenn E. Applied Physics Letters, Vol. 98, Issue 13 https://doi.org/10.1063/1.3571447	journal	March 2011
Electric field-tunable Ba _x Sr _{1− x} TiO ₃ films with high figures of merit grown by molecular beam epitaxy Mikheev, Evgeny; Kajdos, Adam P.; Hauser, Adam J. Applied Physics Letters, Vol. 101, Issue 25 https://doi.org/10.1063/1.4773034	journal	December 2012
Stoichiometry-driven metal-to-insulator transition in NdTiO ₃ /SrTiO ₃ heterostructures Xu, Peng; Phelan, Daniel; Seok Jeong, Jong Applied Physics Letters, Vol. 104, Issue 8 https://doi.org/10.1063/1.4866867	journal	February 2014
Surface reconstructions in molecular beam epitaxy of SrTiO ₃ Kajdos, Adam P.; Stemmer, Susanne Applied Physics Letters, Vol. 105, Issue 19 https://doi.org/10.1063/1.4901726	journal	November 2014
Self-regulated growth of LaVO3 thin films by hybrid molecular beam epitaxy Zhang, Hai-Tian; Dedon, Liv R.; Martin, Lane W. Applied Physics Letters, Vol. 106, Issue 23 https://doi.org/10.1063/1.4922213	journal	June 2015
Accessing a growth window for SrVO3 thin films Brahlek, Matthew; Zhang, Lei; Eaton, Craig Applied Physics Letters, Vol. 107, Issue 14 https://doi.org/10.1063/1.4932198	journal	October 2015
Electronic properties of semiconductor alloy systems Jaros, M. Reports on Progress in Physics, Vol. 48, Issue 8 https://doi.org/10.1088/0034-4885/48/8/001	journal	August 1985
Electronic and ionic transport properties and other physical aspects of perovskites Goodenough, J. B. Reports on Progress in Physics, Vol. 67, Issue 11 https://doi.org/10.1088/0034-4885/67/11/r01	journal	September 2004
Vegard’s law Denton, A. R.; Ashcroft, N. W. Physical Review A, Vol. 43, Issue 6 https://doi.org/10.1103/physreva.43.3161	journal	March 1991
Structural, electronic, and magnetic properties of ${La}_{x}$ ${Sr}_{1 - x}$ ${VO}_{3}$ (0.1≤ x ≤1.0) Mahajan, A. V.; Johnston, D. C.; Torgeson, D. R. Physical Review B, Vol. 46, Issue 17 https://doi.org/10.1103/physrevb.46.10973	journal	November 1992
Change of electronic properties on the doping-induced insulator-metal transition in ${La}_{1 - x}$ ${Sr}_{x}$ ${VO}_{3}$ Inaba, F.; Arima, T.; Ishikawa, T. Physical Review B, Vol. 52, Issue 4 https://doi.org/10.1103/physrevb.52.r2221	journal	July 1995
Topological-Metal to Band-Insulator Transition in $({Bi}_{1 - x} {In}_{x})_{2} {Se}_{3}$ Thin Films Brahlek, Matthew; Bansal, Namrata; Koirala, Nikesh Physical Review Letters, Vol. 109, Issue 18 https://doi.org/10.1103/PhysRevLett.109.186403	journal	October 2012
Mott-Hubbard Transition versus Anderson Localization in Correlated Electron Systems with Disorder Byczuk, Krzysztof; Hofstetter, Walter; Vollhardt, Dieter Physical Review Letters, Vol. 94, Issue 5 https://doi.org/10.1103/physrevlett.94.056404	journal	February 2005
Doping a Mott insulator: Physics of high-temperature superconductivity Lee, Patrick A.; Nagaosa, Naoto; Wen, Xiao-Gang Reviews of Modern Physics, Vol. 78, Issue 1 https://doi.org/10.1103/revmodphys.78.17	journal	January 2006
Growth of SrVO ₃ thin films by hybrid molecular beam epitaxy Eaton, Craig; Moyer, Jarrett A.; Alipour, Hamideh M. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 33, Issue 6 https://doi.org/10.1116/1.4927439	journal	November 2015
Hybrid molecular beam epitaxy for the growth of stoichiometric BaSnO ₃ Prakash, Abhinav; Dewey, John; Yun, Hwanhui Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 33, Issue 6 https://doi.org/10.1116/1.4933401	journal	November 2015
Topological Phase Transition and Texture Inversion in a Tunable Topological Insulator Xu, S. -Y.; Xia, Y.; Wray, L. A. Science, Vol. 332, Issue 6029 https://doi.org/10.1126/science.1201607	journal	March 2011
Single-crystalline BaTiO ₃ films grown by gas-source molecular beam epitaxy Matsubara, Yuya; Takahashi, Kei S.; Tokura, Yoshinori Applied Physics Express, Vol. 7, Issue 12 https://doi.org/10.7567/apex.7.125502	journal	November 2014
Topological phase transition and texture inversion in a tunable topological insulator Xu, S. Y.; Xia, Y.; Wray, L. A. American Association for the Advancement of Science (AAAS) https://doi.org/10.5167/uzh-55165	text	January 2011
Metal-insulator transitions Imada, Masatoshi; Fujimori, Atsushi; Tokura, Yoshinori Reviews of Modern Physics, Vol. 70, Issue 4, p. 1039-1263 https://doi.org/10.1103/revmodphys.70.1039	journal	October 1998
Unexpected mass acquisition of Dirac fermions at the quantum phase transition of a topological insulator Sato, T.; Segawa, Kouji; Kosaka, K. arXiv https://doi.org/10.48550/arxiv.1205.3654	text	January 2012
Surface Reconstructions in Molecular Beam Epitaxy of SrTiO3 Kajdos, Adam P.; Stemmer, Susanne arXiv https://doi.org/10.48550/arxiv.1410.8830	text	January 2014

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Surface Characterizations and Selective Etching of Sr‐Rich Segregation on Top of SrVO ₃ Thin‐Films Grown by Pulsed Laser Deposition Bourlier, Yoan; Frégnaux, Mathieu; Bérini, Bruno ChemNanoMat, Vol. 5, Issue 5 https://doi.org/10.1002/cnma.201900017	journal	March 2019
Strong carrier localization in 3d transition metal oxynitride LaVO _3−x N _x epitaxial thin films Sano, M.; Hirose, Y.; Nakao, S. Journal of Materials Chemistry C, Vol. 5, Issue 7 https://doi.org/10.1039/c6tc04160d	journal	January 2017
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75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
ATOMIC FORCE MICROSCOPY
CALIBRATION
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Title: Mapping growth windows in quaternary perovskite oxide systems by hybrid molecular beam epitaxy

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