Evolution of the electronic properties of transition metal nanoclusters on graphite surface

Journal Article · Tue Jun 15 00:00:00 EDT 2010 · Journal of Experimental and Theoretical Physics

DOI:https://doi.org/10.1134/S1063776110060117· OSTI ID:21443501

Borman, V D; Tronin, V N; Troyan, V I ^[1]

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1. National Research Nuclear University (MEPhI) (Russian Federation)

The electronic properties of nanoclusters of transition (Ni, Co, Cr) and noble (Au, Cu) metals deposited on the surface of highly oriented pyrolytic graphite (HOPG) are studied using the method of X-ray photoelectron spectroscopy. The laws of variation of a change {Delta}E{sub b} in the binding energies of core-level electrons in the initial ({Delta}E{sub i}) and final ({Delta}E{sub f}) states of atoms in nanoclusters, the intrinsic widths {gamma} of photoelectron lines, and their singularity indices {alpha} as functions of the metal cluster size d are determined. A qualitative difference in behavior of the {Delta}E{sub i}(d) and {alpha}(d) values in metals of the two groups (Ni, Cr versus Co, Cu) is found. The values of the final-state energy ({Delta}E{sub f} < 0) and the line width ({Delta}{gamma} > 0) in the clusters of all metals studied vary in a similar manner. It is shown that a significant contribution to E{sub i} is due to a transfer of the valence-shell electrons at the cluster-substrate interface, which is caused by the contact potential difference. The value of an uncompensated charge per nanocluster is determined as a function of the cluster size and the number of atoms in the cluster. The behavior of {Delta}E{sub f}(d) is controlled by the Coulomb energy of a charged cluster and by a decrease in the efficiency of electron screening, which is different in the metals studied. The broadening of photoelectron lines is determined by a spread of the cluster sizes and by lower electron screening in the final Fermi system. An asymmetry of the core-level electron spectra of nanoclusters can be explained using notions about the electron-hole pair excitation near the Fermi level. The effect of the structure of the density of electron states in the d band of transition metals on the asymmetry of photoelectron lines is considered and it is concluded that this structure near the Fermi level qualitatively changes with a decrease in the nanocluster size. The obtained results indicate that the behavior of the electron subsystem of clusters of the d-metals in a size range of 2-10 nm under consideration is close to the behavior of a normal Fermi system.

• OSTI ID: 21443501
• Journal Information: Journal of Experimental and Theoretical Physics, Vol. 110, Issue 6; Other Information: DOI: 10.1134/S1063776110060117; Copyright (c) 2010 Pleiades Publishing, Ltd.; ISSN 1063-7761
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
77 NANOSCIENCE AND NANOTECHNOLOGY
BINDING ENERGY
CHROMIUM
COBALT
COPPER
ELECTRON SPECTRA
ELECTRONIC STRUCTURE
ELECTRONS
EXCITATION
FERMI LEVEL
GOLD
GRAPHITE
INTERFACES
LINE WIDTHS
NANOSTRUCTURES
NICKEL
POTENTIALS
SOLID CLUSTERS
SUBSTRATES
SURFACES
X-RAY PHOTOELECTRON SPECTROSCOPY
CARBON
ELECTRON SPECTROSCOPY
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
FERMIONS
LEPTONS
METALS
MINERALS
NONMETALS
PHOTOELECTRON SPECTROSCOPY
SPECTRA
SPECTROSCOPY
TRANSITION ELEMENTS