Ecologically-based clean-up criteria for nitroaromatic explosives using toxicity test results

Conference · Sun Dec 31 00:00:00 EST 1995

OSTI ID:211932

Duh, D; Roberts, B; Buzgo, S ^[1]

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1. IT Corp., Somerset, NJ (United States)

A former trinitrotoluene (TNT) production and storage facility was the focus of a Remedial Investigation (RI). Contaminants identified during the RI included 2,4-dinitrotoluene (DNT), 2,6-DNT, and 2,4,6-TNT, PCBs, arsenic, lead and chromium. The Conceptual Site Model determined there to be several complete exposure pathways. One of these identified a route by which soil invertebrate communities could be affected through dermal contact and ingestion of soil contaminants. Maintenance of the soil invertebrate community was chosen as the assessment endpoints for this pathway in the Ecological Risk Assessment. The corresponding measurement endpoint was survival of earthworms in 14-day toxicity tests in which they were exposed to site soils. Seven surficial soil samples were collected from Areas of Concern. Each sample was evaluated for acute toxicity to earthworms using standard USEPA protocols. Chemical concentrations were also measured. An artificial soil was used as the control and diluent to establish the Lethal Concentration (LC{sub 50}) of the test soils to earthworms. From the toxicity test results and the corresponding chemical analysis, a matrix of toxicity and contaminant levels was developed. This table was used to determine a concentration of each contaminant at which no acute lethality would be expected. Lower bounds to the chemical specific LC{sub 50} values were determined and, based on sample-specific toxicity units, appropriate LC{sub 50} values were derived (333 mg/kg 2,4-DNT, 182 mg/kg 2,6-DNT, and 1960 mg/kg 2,4,6TNT). Extrapolation of this level to a chronic No Observable Adverse Effect Level (NOAEL) provided a means of proposing site-specific ecologically based clean-up criteria for the constituents of concern which would be protective of the chosen assessment endpoint.

• OSTI ID: 211932
• Report Number(s): CONF-9511137-; ISBN 1-880611-03-1; TRN: IM9617%%248
• Resource Relation: Conference: 2. Society of Environmental Toxicology and Chemistry (SETAC) world conference, Vancouver (Canada), 5-9 Nov 1995; Other Information: PBD: 1995; Related Information: Is Part Of Second SETAC world congress (16. annual meeting): Abstract book. Global environmental protection: Science, politics, and common sense; PB: 378 p.
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
56 BIOLOGY AND MEDICINE
APPLIED STUDIES
45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE
CHEMICAL INDUSTRY
REMEDIAL ACTION
NITRO COMPOUNDS
TOXICITY
POLYCHLORINATED BIPHENYLS
ARSENIC
LEAD
SOILS
LAND POLLUTION
BIOLOGICAL INDICATORS
ANNELIDS
SENSITIVITY
ENVIRONMENTAL EXPOSURE PATHWAY