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Title: Template synthesis of highly crystalline and monodisperse iron oxide pigments of nanosize

Journal Article · · Materials Research Bulletin

Synthesis of highly crystalline and monodisperse iron oxide nanoparticles is reported. The separation of Fe centers through site-specific binding to a polysaccharide-alginate matrix enables the generation of particles with a monodisperse or narrow size distribution character, resulting in transparent pigments. Site-specific interactions coupled with gel like character of alginate is proposed as the mechanism behind generation of lower particle sizes. Alginate-Fe complexes developed were subjected to heat treatment to provide for crystalline character and development of hematite ({alpha}-Fe{sub 2}O{sub 3}). Conditions most ideal for achieving monodispersity and lower sizes have been optimized and confirmed through microscopic and photon correlation spectroscopic measurements.

OSTI ID:
20891932
Journal Information:
Materials Research Bulletin, Vol. 41, Issue 10; Other Information: DOI: 10.1016/j.materresbull.2006.03.017; PII: S0025-5408(06)00104-8; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
Country of Publication:
United States
Language:
English