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Title: Status of Tritium Permeation Barrier Development in the EU

Journal Article · · Fusion Science and Technology
OSTI ID:20854013
 [1];  [2];  [2];  [3]
  1. Forschungszentrum Karlsruhe (Germany)
  2. ENEA Fusion Division (Italy)
  3. CEA Saclay (France)

Tritium permeation can be significantly reduced by a suitable barrier on the structural materials of a future fusion power plant. Since alumina has the capability of tritium permeation reduction, the development of such coatings on ferritic martensitic steels by different techniques like hot-dip aluminizing (HDA) by Forschungszentrum Karlsruhe, Germany (FZK) and chemical vapor deposition (CVD) by Commissariat a l'Energie Atomique, France (CEA) was funded by the European Commission (EC) during the last 10 years. The final objective was to identify a so-called reference coating for structural components of a lithium-lead cooled blanket.This paper describes the process specifications and the results of the corresponding hydrogen permeation measurements, performed at ENEA, Brasimone, Italy. The results for CVD and HDA coating showed clearly, that Permeation Reduction Factor's (PRF) of >1000 were sufficiently exceeded in H{sub 2} gas, but much lower values were obtained in the Pb-17Li melt. The post mortem analysis revealed that surface imperfections and spallation of parts of the coatings were responsible for the too low PRF's. Because of shifting of priorities and changes in the blanket design from WCLL to HCLL, the EU funding of all major R and D activities was postponed in 2002 until the redesign of the European Blanket Concepts was finished.

OSTI ID:
20854013
Journal Information:
Fusion Science and Technology, Vol. 47, Issue 4; Other Information: Copyright (c) 2006 American Nuclear Society (ANS), United States, All rights reserved. http://epubs.ans.org/; Country of input: International Atomic Energy Agency (IAEA); ISSN 1536-1055
Country of Publication:
United States
Language:
English