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Title: Micro-PIXE Analysis of Trace Elements in Sulfides

Journal Article · · AIP Conference Proceedings
DOI:https://doi.org/10.1063/1.1619754· OSTI ID:20632616
;  [1];  [2];  [3];  [4]
  1. Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)
  2. Philippine Geothermal, Makati City, (Philippines)
  3. Dept. of Geol. Sci., Univ. Manitoba, Winnipeg, MB, R3T 2N2 (Canada)
  4. Dept. Earth and Planet. Sci., Univ. New Mexico, Albuquerque, NM 87131 (United States)

Micro-scale Proton-induced X-ray Emission (PIXE) of trace elements (TE) in sulfides provides insights into geologic processes including magmatic system evolution, ore forming events, and fluid-flow processes. The Los Alamos nuclear microprobe was used to determine TE concentrations and ratios in sulfides from diverse geologic environments including hydrothermal ore deposits, coal seams, and metamorphic rocks. Pyrrhotite (Po) from silicic volcanics contains high Cu and Ni; Po from the Clear Lake volcanic field has higher Mo than does Po from other volcanic fields. Coal pyrites contain high Cu, As, Se, Mo and Pb, and show high As/Se and Mo/Se in marine influenced sulfides from the Lower Kittanning coal, but not in other marine-influenced coals. Sulfides are amenable to micro-PIXE studies because of the difficulties in obtaining the homogeneous standards required for many other TE microanalytical techniques.

OSTI ID:
20632616
Journal Information:
AIP Conference Proceedings, Vol. 680, Issue 1; Conference: 17. international conference on the application of accelerators in research and industry, Denton, TX (United States), 12-16 Nov 2002; Other Information: DOI: 10.1063/1.1619754; (c) 2003 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
Country of Publication:
United States
Language:
English

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