Mechanochemistry-Induced Strong Metal–Support Interactions Construction toward Enhanced Hydrogenation

Li, Meijia; Zhang, Tianyu; Yang, Shi-Ze; Sun, Yifan; Zhang, Junyan; Polo-Garzon, Felipe; Siniard, Kevin M.; Yu, Xinbin; Wu, Zili; Driscoll, Darren M.; Ivanov, Alexander S.; Chen, Hao; Yang, Zhenzhen; Dai, Sheng

doi:10.1021/acscatal.2c05730

Title: Mechanochemistry-Induced Strong Metal–Support Interactions Construction toward Enhanced Hydrogenation

Journal Article · Wed Apr 19 00:00:00 EDT 2023 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.2c05730· OSTI ID:1992713

^[1]; Zhang, Tianyu ^[2];

^[3];

^[1]; Zhang, Junyan ^[1];

^[1];

^[2]; Yu, Xinbin ^[1];

^[1];

^[4];

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^[5]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Arizona State Univ., Tempe, AZ (United States)
Hunan Univ., Changsha (China); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

The construction of strong metal–support interactions (SMSIs) represented an attractive approach to producing supported noble metal nanocatalysts possessing enhanced stability by overlayer encapsulation. The development of facile approaches capable of achieving efficient, controllable, and extensive SMSI overlayer formation, particularly under neat and ambient conditions, is a long-standing challenge. In this work, a mechanochemistry-driven pathway was deployed for efficient and controllable SMSI construction under neat and ambient conditions to customize the capsulation degree and overlayer structures toward enhanced catalysis. The reducibility of the additives and the high interaction efficiency provided by the mechanochemical treatment could afford abundant active intermediates (e.g., Ti³⁺ species and oxygen defects) within a short time to induce and tune the overlayer encapsulation. This facile approach could be extensively deployed to TiO2-derived nanocatalysts with diverse phases, diverse reducible metal oxides-involved systems, and different supported noble metal nanoparticles. Enhanced hydrogenation activity was achieved by the as-afforded nanocatalysts upon SMSI construction and further tuned by the encapsulation degree.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1992713

Journal Information:: ACS Catalysis, Vol. 13, Issue 9; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (71)

Defect-Regulated Frustrated-Lewis-Pair Behavior of Boron Nitride in Ambient Pressure Hydrogen Activation Chen, Hao; Xiong, Chuanye; Moon, Jisue Journal of the American Chemical Society, Vol. 144, Issue 24 https://doi.org/10.1021/jacs.2c00343	journal	May 2022
Strong Metal–Support Interactions between Gold Nanoparticles and Nonoxides Tang, Hailian; Wei, Jiake; Liu, Fei Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b11306	journal	December 2015
Advances in Quantum Mechanochemistry: Electronic Structure Methods and Force Analysis Stauch, Tim; Dreuw, Andreas Chemical Reviews, Vol. 116, Issue 22 https://doi.org/10.1021/acs.chemrev.6b00458	journal	October 2016
Ultralong-lifetime Ti/RuO₂–IrO₂@Pt anodes with a strong metal–support interaction for efficient electrochemical mineralization of perfluorooctanoic acid Zhou, Jianjun; Wang, Tian; Cheng, Cheng Nanoscale, Vol. 14, Issue 9 https://doi.org/10.1039/D1NR08098A	journal	January 2022
Strong metal-support interaction promoted scalable production of thermally stable single-atom catalysts Liu, Kaipeng; Zhao, Xintian; Ren, Guoqing Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14984-9	journal	March 2020
How Temperature Affects the Mechanism of CO Oxidation on Au/TiO ₂ : A Combined EPR and TAP Reactor Study of the Reactive Removal of TiO ₂ Surface Lattice Oxygen in Au/TiO ₂ by CO Widmann, Daniel; Krautsieder, Anke; Walter, Patrick ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b01219	journal	July 2016
Strong Metal–Support Interactions between Pt Single Atoms and TiO ₂ Han, Bing; Guo, Yalin; Huang, Yike Angewandte Chemie International Edition, Vol. 59, Issue 29 https://doi.org/10.1002/anie.202003208	journal	May 2020
A new approach to prepare Ti3+ self-doped TiO2 via NaBH4 reduction and hydrochloric acid treatment Fang, Wenzhang; Xing, Mingyang; Zhang, Jinlong Applied Catalysis B: Environmental, Vol. 160-161 https://doi.org/10.1016/j.apcatb.2014.05.031	journal	November 2014
Mechanochemical synthesis of porous organic materials Zhang, Pengfei; Dai, Sheng Journal of Materials Chemistry A, Vol. 5, Issue 31 https://doi.org/10.1039/C7TA04829G	journal	January 2017
Epitaxial Growth of Lattice-Mismatched Core-Shell TiO ₂ @MoS ₂ for Enhanced Lithium-Ion Storage Dai, Rui; Zhang, Anqi; Pan, Zhichang Small, Vol. 12, Issue 20 https://doi.org/10.1002/smll.201600237	journal	April 2016
Strong Metal–Support Interactions Achieved by Hydroxide-to-Oxide Support Transformation for Preparation of Sinter-Resistant Gold Nanoparticle Catalysts Wang, Liang; Zhang, Jian; Zhu, Yihan ACS Catalysis, Vol. 7, Issue 11 https://doi.org/10.1021/acscatal.7b01947	journal	October 2017
Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks Trunk, Matthias; Teichert, Johannes F.; Thomas, Arne Journal of the American Chemical Society, Vol. 139, Issue 10 https://doi.org/10.1021/jacs.6b13147	journal	March 2017
Strong Metal–Support Interaction Boosts Activity, Selectivity, and Stability in Electrosynthesis of H₂O₂ Zhang, Junming; Ma, Jun; Choksi, Tej S. Journal of the American Chemical Society, Vol. 144, Issue 5 https://doi.org/10.1021/jacs.1c12157	journal	January 2022
Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts Matsubu, John C.; Zhang, Shuyi; DeRita, Leo Nature Chemistry, Vol. 9, Issue 2 https://doi.org/10.1038/nchem.2607	journal	September 2016
Polymer Mechanochemistry: From Destructive to Productive Li, Jun; Nagamani, Chikkannagari; Moore, Jeffrey S. Accounts of Chemical Research, Vol. 48, Issue 8 https://doi.org/10.1021/acs.accounts.5b00184	journal	July 2015
Fully exposed palladium cluster catalysts enable hydrogen production from nitrogen heterocycles Dong, Chunyang; Gao, Zirui; Li, Yinlong Nature Catalysis, Vol. 5, Issue 6 https://doi.org/10.1038/s41929-022-00769-4	journal	April 2022
Harnessing strong metal–support interactions via a reverse route Wu, Peiwen; Tan, Shuai; Moon, Jisue Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16674-y	journal	June 2020
Overturning CO₂ Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions Xin, Hui; Lin, Le; Li, Rongtan Journal of the American Chemical Society, Vol. 144, Issue 11 https://doi.org/10.1021/jacs.1c12603	journal	March 2022
Correlating Heat of Adsorption of CO to Reaction Selectivity: Geometric Effects vs Electronic Effects in Neopentane Isomerization over Pt and Pd Catalysts Childers, David; Saha, Arindom; Schweitzer, Neil ACS Catalysis, Vol. 3, Issue 11 https://doi.org/10.1021/cs400527p	journal	October 2013
Deep Understanding of Strong Metal Interface Confinement: A Journey of Pd/FeO _x Catalysts Liu, Jixing; Wang, Lu; Okejiri, Francis ACS Catalysis, Vol. 10, Issue 15 https://doi.org/10.1021/acscatal.0c01447	journal	July 2020
Lithium Charge Storage Mechanisms of Cross-Linked Triazine Networks and Their Porous Carbon Derivatives See, Kimberly A.; Hug, Stephan; Schwinghammer, Katharina Chemistry of Materials, Vol. 27, Issue 11 https://doi.org/10.1021/acs.chemmater.5b00772	journal	May 2015
Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides Tan, Mingwu; Yang, Yanling; Yang, Ying Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-29045-6	journal	March 2022
Photoinduced Strong Metal–Support Interaction for Enhanced Catalysis Chen, Hao; Yang, Zhenzhen; Wang, Xiang Journal of the American Chemical Society, Vol. 143, Issue 23 https://doi.org/10.1021/jacs.0c12817	journal	June 2021
Sinter-Resistant Nanoparticle Catalysts Achieved by 2D Boron Nitride-Based Strong Metal–Support Interactions: A New Twist on an Old Story Chen, Hao; Yang, Shi-Ze; Yang, Zhenzhen ACS Central Science, Vol. 6, Issue 9 https://doi.org/10.1021/acscentsci.0c00822	journal	September 2020
Machine Learning Method Reveals Hidden Strong Metal‐Support Interaction in Microscopy Datasets Blum, Thomas; Graves, Jeffery; Zachman, Michael J. Small Methods, Vol. 5, Issue 5 https://doi.org/10.1002/smtd.202100035	journal	February 2021
Supported Pd catalysts for solvent-free benzyl alcohol selective oxidation: Effects of calcination pretreatments and reconstruction of Pd sites Wang, Xueming; Wu, Guangjun; Guan, Naijia Applied Catalysis B: Environmental, Vol. 115-116 https://doi.org/10.1016/j.apcatb.2011.12.011	journal	April 2012
A Sacrificial Coating Strategy Toward Enhancement of Metal–Support Interaction for Ultrastable Au Nanocatalysts Zhan, Wangcheng; He, Qian; Liu, Xiaofei Journal of the American Chemical Society, Vol. 138, Issue 49 https://doi.org/10.1021/jacs.6b10472	journal	December 2016
Alcohol-Induced Low-Temperature Blockage of Supported-Metal Catalysts for Enhanced Catalysis Polo-Garzon, Felipe; Blum, Thomas F.; Fung, Victor ACS Catalysis, Vol. 10, Issue 15 https://doi.org/10.1021/acscatal.0c02452	journal	July 2020
Preparation of iron oxide nanoparticles by mechanical milling Arbain, Roshaida; Othman, Munirah; Palaniandy, Samayamutthirian Minerals Engineering, Vol. 24, Issue 1 https://doi.org/10.1016/j.mineng.2010.08.025	journal	January 2011
Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO ₂ Catalysts for Nitrobenzene Hydrogenation Chen, Peirong; Khetan, Abhishek; Yang, Fengkai ACS Catalysis, Vol. 7, Issue 2 https://doi.org/10.1021/acscatal.6b02963	journal	January 2017
Comparative second harmonic generation and X-ray photoelectron spectroscopy studies of the UV creation and O2 healing of Ti3+ defects on (110) rutile TiO2 surfaces Shultz, Ashley N.; Jang, Winyann; Hetherington, W. M. Surface Science, Vol. 339, Issue 1-2 https://doi.org/10.1016/0039-6028(95)00650-8	journal	September 1995
Metal–Support Interactions in Metal/Oxide Catalysts and Oxide–Metal Interactions in Oxide/Metal Inverse Catalysts Li, Yangyang; Zhang, Yunshang; Qian, Kun ACS Catalysis, Vol. 12, Issue 2 https://doi.org/10.1021/acscatal.1c04854	journal	January 2022
Harnessing Strong Metal–Support Interaction to Proliferate the Dry Reforming of Methane Performance by In Situ Reduction Jeon, Ok Sung; Lee, Hyesung; Lee, Kug-Seung ACS Applied Materials & Interfaces, Vol. 14, Issue 10 https://doi.org/10.1021/acsami.1c20889	journal	March 2022
Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity Freakley, S. J.; He, Q.; Harrhy, J. H. Science, Vol. 351, Issue 6276 https://doi.org/10.1126/science.aad5705	journal	February 2016
The role of oxygen vacancy-Ti3+ states on TiO2 nanotubes' surface in dye-sensitized solar cells Zhang, Xiaobo; Tian, Hanmin; Wang, Xiangyan Materials Letters, Vol. 100 https://doi.org/10.1016/j.matlet.2013.02.116	journal	June 2013
Metal-Support Interactions in Rh/CeO2, Rh/TiO2, and Rh/Nb2O5 Catalysts as Inferred from CO2 Methanation Activity Deleitenburg, C.; Trovarelli, A. Journal of Catalysis, Vol. 156, Issue 1 https://doi.org/10.1006/jcat.1995.1244	journal	September 1995
Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts Lin, Lili; Zhou, Wu; Gao, Rui Nature, Vol. 544, Issue 7648 https://doi.org/10.1038/nature21672	journal	March 2017
Interfacial oxygen vacancy layer of a Z-scheme BCN–TiO₂ heterostructure accelerating charge carrier transfer for visible light photocatalytic H₂ evolution Xing, Xiaolei; Zhu, Huihui; Zhang, Min Catalysis Science & Technology, Vol. 8, Issue 14 https://doi.org/10.1039/C8CY01035H	journal	January 2018
Sinter-resistant metal nanoparticle catalysts achieved by immobilization within zeolite crystals via seed-directed growth Zhang, Jian; Wang, Liang; Zhang, Bingsen Nature Catalysis, Vol. 1, Issue 7 https://doi.org/10.1038/s41929-018-0098-1	journal	July 2018
Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity van Deelen, Tom W.; Hernández Mejía, Carlos; de Jong, Krijn P. Nature Catalysis, Vol. 2, Issue 11 https://doi.org/10.1038/s41929-019-0364-x	journal	November 2019
Light-Induced Synergistic Multidefect Sites on TiO ₂ /SiO ₂ Composites for Catalytic Dehydrogenation Saputera, Wibawa Hendra; Tahini, Hassan A.; Sabsabi, Mohammad ACS Catalysis, Vol. 9, Issue 3 https://doi.org/10.1021/acscatal.8b04891	journal	February 2019
Strong Metal–Support Interactions between Gold Nanoparticles and ZnO Nanorods in CO Oxidation Liu, Xiaoyan; Liu, Ming-Han; Luo, Yi-Chia Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja3033235	journal	June 2012
A Magnetically Separable Pd Single‐Atom Catalyst for Efficient Selective Hydrogenation of Phenylacetylene Zhao, Linmin; Qin, Xuetao; Zhang, Xirui Advanced Materials, Vol. 34, Issue 20 https://doi.org/10.1002/adma.202110455	journal	April 2022
Strong Metal–Support Interaction of Ru on TiO ₂ Derived from the Co-Reduction Mechanism of Ru _x Ti _{1– x} O ₂ Interphase Zhang, Yaru; Yan, Wenjie; Qi, Haifeng ACS Catalysis, Vol. 12, Issue 3 https://doi.org/10.1021/acscatal.1c04785	journal	January 2022
Size-dependent strong metal-support interaction in TiO2 supported Au nanocatalysts Du, Xiaorui; Huang, Yike; Pan, Xiaoli Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19484-4	journal	November 2020
Oxidative strong metal–support interactions (OMSI) of supported platinum-group metal catalysts Tang, Hailian; Su, Yang; Guo, Yalin Chemical Science, Vol. 9, Issue 32 https://doi.org/10.1039/C8SC01392F	journal	January 2018
Dynamical Observation and Detailed Description of Catalysts under Strong Metal–Support Interaction Zhang, Shuyi; Plessow, Philipp N.; Willis, Joshua J. Nano Letters, Vol. 16, Issue 7 https://doi.org/10.1021/acs.nanolett.6b01769	journal	June 2016
Strong metal-support interactions induced by an ultrafast laser Zhang, Jian; Zhu, Dezhi; Yan, Jianfeng Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-27000-5	journal	November 2021
Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction Li, Siwei; Xu, Yao; Chen, Yifu Angewandte Chemie International Edition, Vol. 56, Issue 36 https://doi.org/10.1002/anie.201705002	journal	August 2017
Structure Sensitivity of Au‐TiO ₂ Strong Metal–Support Interactions Zhang, Yunshang; Liu, Jin‐Xun; Qian, Kun Angewandte Chemie International Edition, Vol. 60, Issue 21 https://doi.org/10.1002/anie.202101928	journal	April 2021
Surface Science Studies of the Photoactivation of TiO ₂ New Photochemical Processes Thompson, Tracy L.; Yates, John T. Chemical Reviews, Vol. 106, Issue 10 https://doi.org/10.1021/cr050172k	journal	October 2006
Ultrastable Hydroxyapatite/Titanium-Dioxide-Supported Gold Nanocatalyst with Strong Metal-Support Interaction for Carbon Monoxide Oxidation Tang, Hailian; Liu, Fei; Wei, Jiake Angewandte Chemie International Edition, Vol. 55, Issue 36 https://doi.org/10.1002/anie.201601823	journal	July 2016
Oxidative Strong Metal–Support Interactions between Metals and Inert Boron Nitride Song, Tongyuan; Dong, Jinhu; Li, Rongtan The Journal of Physical Chemistry Letters, Vol. 12, Issue 17 https://doi.org/10.1021/acs.jpclett.1c00934	journal	April 2021
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide Tauster, S. J.; Fung, S. C.; Garten, R. L. Journal of the American Chemical Society, Vol. 100, Issue 1 https://doi.org/10.1021/ja00469a029	journal	January 1978
Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition Lu, Junling; Fu, Baosong; Kung, Mayfair C. Science, Vol. 335, Issue 6073 https://doi.org/10.1126/science.1212906	journal	March 2012
Classical strong metal–support interactions between gold nanoparticles and titanium dioxide Tang, Hailian; Su, Yang; Zhang, Bingsen Science Advances, Vol. 3, Issue 10 https://doi.org/10.1126/sciadv.1700231	journal	October 2017
Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and Catalytic Hydrogenation of Olefins vom Stein, Thorsten; Peréz, Manuel; Dobrovetsky, Roman Angewandte Chemie International Edition, Vol. 54, Issue 35 https://doi.org/10.1002/anie.201504109	journal	July 2015
Self-doped Ti 3+ -enhanced TiO 2 nanoparticles with a high-performance photocatalysis Xing, Mingyang; Fang, Wenzhang; Nasir, Muhammad Journal of Catalysis, Vol. 297 https://doi.org/10.1016/j.jcat.2012.10.014	journal	January 2013
Solvent-free microwave synthesis of ultra-small Ru-Mo2C@CNT with strong metal-support interaction for industrial hydrogen evolution Wu, Xueke; Wang, Zuochao; Zhang, Dan Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-24322-2	journal	June 2021
Increasing the Oxygen-Evolution Reaction Performance of Nanotubular Titanium Oxynitride-Supported Ir Nanoparticles by a Strong Metal–Support Interaction Bele, Marjan; Jovanovič, Primož; Marinko, Živa ACS Catalysis, Vol. 10, Issue 22 https://doi.org/10.1021/acscatal.0c03688	journal	November 2020
Reaction-Induced Strong Metal–Support Interactions between Metals and Inert Boron Nitride Nanosheets Dong, Jinhu; Fu, Qiang; Li, Haobo Journal of the American Chemical Society, Vol. 142, Issue 40 https://doi.org/10.1021/jacs.0c08139	journal	September 2020
Supported Metal Clusters: Synthesis, Structure, and Catalysis Gates, B. C. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a003	journal	May 1995
Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction Li, Siwei; Xu, Yao; Chen, Yifu Angewandte Chemie, Vol. 129, Issue 36 https://doi.org/10.1002/ange.201705002	journal	August 2017
Enhanced Hydrogenation Properties of Pd Single Atom Catalysts with Atomically Dispersed Ba Sites as Electronic Promoters Zhang, Ying; Cheng, Yujie; Wang, Xilun ACS Catalysis, Vol. 12, Issue 24 https://doi.org/10.1021/acscatal.2c04626	journal	November 2022
Wet-Chemistry Strong Metal–Support Interactions in Titania-Supported Au Catalysts Zhang, Jian; Wang, Hai; Wang, Liang Journal of the American Chemical Society, Vol. 141, Issue 7 https://doi.org/10.1021/jacs.8b10864	journal	January 2019
Towards stable catalysts by controlling collective properties of supported metal nanoparticles Prieto, Gonzalo; Zečević, Jovana; Friedrich, Heiner Nature Materials, Vol. 12, Issue 1 https://doi.org/10.1038/nmat3471	journal	November 2012
Understanding the Strong Metal–Support Interaction (SMSI) Effect in Cu_xNi_1–x/CeO₂ (0 < x < 1) Nanoparticles for Enhanced Catalysis Figueiredo, Wallace T.; Della Mea, Guilherme B.; Segala, Maximiliano ACS Applied Nano Materials, Vol. 2, Issue 4 https://doi.org/10.1021/acsanm.9b00569	journal	April 2019
In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO ₂ Catalyst: Importance of Strong Metal-Support Interactions for the Cleavage of O-H Bonds Carrasco, Javier; López-Durán, David; Liu, Zongyuan Angewandte Chemie International Edition, Vol. 54, Issue 13 https://doi.org/10.1002/anie.201410697	journal	February 2015
Enhanced CO ₂ Methanation Activity of Ni/Anatase Catalyst by Tuning Strong Metal–Support Interactions Li, Jian; Lin, Yaping; Pan, Xiulian ACS Catalysis, Vol. 9, Issue 7 https://doi.org/10.1021/acscatal.9b00401	journal	May 2019
Manipulating Copper Dispersion on Ceria for Enhanced Catalysis: A Nanocrystal‐Based Atom‐Trapping Strategy Sun, Yifan; Polo‐Garzon, Felipe; Bao, Zhenghong Advanced Science, Vol. 9, Issue 8 https://doi.org/10.1002/advs.202104749	journal	January 2022
Strong metal-support interactions Tauster, S. J. Accounts of Chemical Research, Vol. 20, Issue 11 https://doi.org/10.1021/ar00143a001	journal	November 1987

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
strong metal−support interaction
mechanochemistry
supported noble metal catalyst
encapsulation
hydrogenation

Title: Mechanochemistry-Induced Strong Metal–Support Interactions Construction toward Enhanced Hydrogenation

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