Synthesis, crystal structure, EPR, and DFT studies of an unusually distorted vanadium(ii) complex
- Rensselaer Polytechnic Inst., Troy, NY (United States). Baruch ‘60 Center for Biochemical Solar Energy Research
- Universitat de Barcelona (Spain)
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Boston College, Chestnut Hill, MA (United States)
- Rensselaer Polytechnic Inst., Troy, NY (United States)
We report the synthesis and structure of the most highly distorted four-coordinate d3 ion known to date that also serves as the second known example of a bis(biphenolato) transition metal complex. We demonstrate the application of density functional theory to calculate the magnetic parameters derived from the experimental and simulated EPR spectra.
- Research Organization:
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC); National Science Foundation (NSF)
- Grant/Contract Number:
- FG02-07ER15903; 1560266
- OSTI ID:
- 1978892
- Alternate ID(s):
- OSTI ID: 1879771
- Journal Information:
- Dalton Transactions, Vol. 51, Issue 32; ISSN 1477-9226
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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