Chemical and Light-Absorption Properties of Water-Soluble Organic Aerosols in Northern California and Photooxidant Production by Brown Carbon Components

Jiang, Wenqing; Ma, Lan; Niedek, Christopher; Anastasio, Cort; Zhang, Qi

doi:10.1021/acsearthspacechem.3c00022

Title: Chemical and Light-Absorption Properties of Water-Soluble Organic Aerosols in Northern California and Photooxidant Production by Brown Carbon Components

Journal Article · Mon Apr 24 00:00:00 EDT 2023 · ACS Earth and Space Chemistry

DOI:https://doi.org/10.1021/acsearthspacechem.3c00022· OSTI ID:1971265

^[1];

^[2]; Niedek, Christopher ^[1];

^[2];

^[1]

Department of Environmental Toxicology, University of California, 1 Shields Avenue, Davis, California 95616, United States, Agricultural and Environmental Chemistry Graduate Program, University of California, 1 Shields Avenue, Davis, California 95616, United States
Agricultural and Environmental Chemistry Graduate Program, University of California, 1 Shields Avenue, Davis, California 95616, United States, Department of Land, Air, and Water Resources, University of California, 1 Shields Avenue, Davis, California 95616, United States

Atmospheric brown carbon (BrC) can impact the radiative balance of the earth and form photooxidants. However, the light absorption and photochemical properties of BrC from different sources remain poorly understood. To address this gap, dilute water extracts of particulate matter (PM) samples collected at Davis, CA over one year were analyzed using high resolution aerosol mass spectrometry (HR-AMS) and UV–vis spectroscopy. Positive matrix factorization (PMF) on combined AMS and UV–vis data resolved five water-soluble organic aerosol (WSOA) factors with distinct mass spectra and UV–vis spectra: a fresh and an aged water-soluble biomass burning OA (_WSBBOA_fresh and _WSBBOA_aged) and three oxygenated OA (_WSOOAs). _WSBBOA_fresh is the most light-absorbing, with a mass absorption coefficient (MAC_{365 nm}) of 1.1 m² g^–1, while the _WSOOAs are the least (MAC_{365 nm} = 0.01– 0.1 m² g^–1). These results, together with the high abundance of _WSBBOAs (~52% of the WSOA mass), indicate that biomass burning activities such as residential wood burning and wildfires are an important source of BrC in northern California. The concentrations of aqueous-phase photooxidants, i.e., hydroxyl radical (·OH), singlet molecular oxygen (¹O₂*), and oxidizing triplet excited states of organic carbon (3C*), were also measured in the PM extracts during illumination. Oxidant production potentials (PP_OX) of the five WSOA factors were explored. The photoexcitation of BrC chromophores from BB emissions and in OOAs is a significant source of ¹O₂* and ³C*. By applying our PPOX values to archived AMS data at dozens of sites, we found that oxygenated organic species play an important role in photooxidant formation in atmospheric waters.

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Research Organization:: Univ. of California, Davis, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0022140; AGS-2220307

OSTI ID:: 1971265

Alternate ID(s):: OSTI ID: 1974153

Journal Information:: ACS Earth and Space Chemistry, Journal Name: ACS Earth and Space Chemistry Vol. 7 Journal Issue: 5; ISSN 2472-3452

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
biomass burning organic aerosols
oxygenated organic aerosols
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hydroxyl radical
singlet oxygen
triplet excited state of organic carbon
aqueous-phase reactions
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absorption
anions
ions
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