Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries

Rodrigo, Nuwanthi D.; Jayawardana, Chamithri; Rynearson, Leah; Hu, Enyuan; Yang, Xiao-Qing; Lucht, Brett L.

doi:10.1149/1945-7111/ac9d0a

Title: Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries

Journal Article · Thu Nov 03 00:00:00 EDT 2022 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/1945-7111/ac9d0a· OSTI ID:1896953

;

; Hu, Enyuan;

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An investigation of alternative lithium salts, lithium tetrafluoroborate (LiBF ₄ ), lithium difluoro(oxalato)borate (LiDFOB) and lithium hexafluorophosphate (LiPF ₆ ), in novel ester-based (methyl acetate/fluoroethylene carbonate- MA/FEC or methyl propionate/fluoroethylene carbonate- MP/FEC) electrolyte formulations has been conducted in LiNi _0.6 Co _0.2 Mn _0.2 O ₂ (NCM622)/graphite cells to improve low temperature cycling performance of lithium ion batteries at −20 °C. Improved low temperature performance was observed with all the lithium salts in MA/FEC electrolyte while comparable room temperature (25 °C) capacities were observed with LiPF ₆ salt only. Detailed ex-situ analysis of surface films generated with LiBF ₄ , LiDFOB and LiPF ₆ in ester-based electrolytes reveals that the solid electrolyte interphase (SEI) is predominately composed of lithium salt decompaction products and addition of 10% FEC (by volume%) may not be sufficient at forming a protective SEI.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: SC0012704

OSTI ID:: 1896953

Alternate ID(s):: OSTI ID: 1894424; OSTI ID: 1898591

Report Number(s):: BNL-223721-2022-JAAM

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Vol. 169 Journal Issue: 11; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (35)

Reduction Reactions of Carbonate Solvents for Lithium Ion Batteries Seo, D. M.; Chalasani, D.; Parimalam, B. S. ECS Electrochemistry Letters, Vol. 3, Issue 9 https://doi.org/10.1149/2.0021409eel	journal	January 2014
Carbonate Free Electrolyte for Lithium Ion Batteries Containing γ-Butyrolactone and Methyl Butyrate Lazar, Michael L.; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 162, Issue 6 https://doi.org/10.1149/2.0601506jes	journal	January 2015
The low temperature performance of Li-ion batteries Zhang, S. S.; Xu, K.; Jow, T. R. Journal of Power Sources, Vol. 115, Issue 1 https://doi.org/10.1016/S0378-7753(02)00618-3	journal	March 2003
Lithium Plating Behavior in Lithium-Ion Cells Bugga, Ratnakumar V.; Smart, Marshall C. 216th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.3393860	conference	January 2010
Insights into the Dual Role of Lithium Difluoro(oxalato)borate Additive in Improving the Electrochemical Performance of NMC811\|\|Graphite Cells Dong, Qingyu; Guo, Feng; Cheng, Zhenjie ACS Applied Energy Materials, Vol. 3, Issue 1 https://doi.org/10.1021/acsaem.9b01894	journal	December 2019
Fundamentals and Challenges of Lithium Ion Batteries at Temperatures between −40 and 60 °C Hou, Junbo; Yang, Min; Wang, Deyu Advanced Energy Materials, Vol. 10, Issue 18 https://doi.org/10.1002/aenm.201904152	journal	February 2020
Ester-Based Electrolytes for Fast Charging of Energy Dense Lithium-Ion Batteries Logan, E. R.; Hall, D. S.; Cormier, Marc M. E. The Journal of Physical Chemistry C, Vol. 124, Issue 23 https://doi.org/10.1021/acs.jpcc.0c02370	journal	May 2020
The Effect of Additives upon the Performance of MCMB/LiNi _x Co _1−x O ₂ Li-Ion Cells Containing Methyl Butyrate-Based Wide Operating Temperature Range Electrolytes Smart, Marshall C.; Lucht, Brett L.; Dalavi, Swapnil Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.058206jes	journal	January 2012
Properties of PC-EA Solvent and Its Solution of LiBOB Comparison of Linear Esters to Linear Carbonates for Use in Lithium Batteries Ding, Michael S.; Jow, T. Richard Journal of The Electrochemical Society, Vol. 152, Issue 6 https://doi.org/10.1149/1.1914757	journal	January 2005
A novel electrolyte additive for improving the interfacial stability of high voltage lithium nickel manganese oxide cathode Huang, Wenna; Xing, Lidan; Zhang, Ruiqin Journal of Power Sources, Vol. 293 https://doi.org/10.1016/j.jpowsour.2015.05.070	journal	October 2015
Improved Low Temperature Performance of Graphite/Li Cells Using Isoxazole as a Novel Cosolvent in Electrolytes Rodrigo, Nuwanthi D.; Tan, Sha; Shadike, Zulipiya Journal of The Electrochemical Society, Vol. 168, Issue 7 https://doi.org/10.1149/1945-7111/ac11a6	journal	July 2021
New Li-ion electrolytes for low temperature applications Herreyre, S.; Huchet, O.; Barusseau, S. Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00670-X	journal	July 2001
Lithium-ion batteries. A look into the future Scrosati, Bruno; Hassoun, Jusef; Sun, Yang-Kook Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01388b	journal	January 2011
Generation and Evolution of the Solid Electrolyte Interphase of Lithium-Ion Batteries Heiskanen, Satu Kristiina; Kim, Jongjung; Lucht, Brett L. Joule, Vol. 3, Issue 10 https://doi.org/10.1016/j.joule.2019.08.018	journal	October 2019
Ethylene carbonate-free electrolytes for Li-ion battery: Study of the solid electrolyte interphases formed on graphite anodes Ehteshami, Niloofar; Ibing, Lukas; Stolz, Lukas Journal of Power Sources, Vol. 451 https://doi.org/10.1016/j.jpowsour.2020.227804	journal	March 2020
Role of Lithium Salt on Solid Electrolyte Interface (SEI) Formation and Structure in Lithium Ion Batteries Nie, Mengyun; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 161, Issue 6 https://doi.org/10.1149/2.054406jes	journal	January 2014
The Impact of CO ₂ Evolved from VC and FEC during Formation of Graphite Anodes in Lithium-Ion Batteries Schwenke, K. Uta; Solchenbach, Sophie; Demeaux, Julien Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.0821910jes	journal	January 2019
Surface Analysis of Electrodes from Cells Containing Electrolytes with Stabilizing Additives Exposed to High Temperature Li, W.; Xiao, A.; Lucht, B. L. Journal of The Electrochemical Society, Vol. 155, Issue 9 https://doi.org/10.1149/1.2949507	journal	January 2008
Li ion batteries for aerospace applications Marsh, R. A.; Vukson, S.; Surampudi, S. Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00584-5	journal	July 2001
Low temperature performance of graphite electrode in Li-ion cells Zhang, S. S.; Xu, K.; Jow, T. R. Electrochimica Acta, Vol. 48, Issue 3 https://doi.org/10.1016/S0013-4686(02)00620-5	journal	December 2002
Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance Smart, M. C.; Ratnakumar, B. V.; Chin, K. B. Journal of The Electrochemical Society, Vol. 157, Issue 12 https://doi.org/10.1149/1.3501236	journal	January 2010
Temperature and Concentration Dependence of the Ionic Transport Properties of Lithium-Ion Battery Electrolytes Landesfeind, Johannes; Gasteiger, Hubert A. Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0571912jes	journal	January 2019
The use of ethyl acetate and methyl propanoate in combination with vinylene carbonate as ethylene carbonate-free solvent blends for electrolytes in Li-ion batteries Petibon, R.; Harlow, J.; Le, D. B. Electrochimica Acta, Vol. 154 https://doi.org/10.1016/j.electacta.2014.12.084	journal	February 2015
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Role of Solution Structure in Solid Electrolyte Interphase Formation on Graphite with LiPF ₆ in Propylene Carbonate Nie, Mengyun; Abraham, Daniel P.; Seo, Daniel M. The Journal of Physical Chemistry C, Vol. 117, Issue 48 https://doi.org/10.1021/jp409765w	journal	November 2013
An All-Fluorinated Ester Electrolyte for Stable High-Voltage Li Metal Batteries Capable of Ultra-Low-Temperature Operation Holoubek, John; Yu, Mingyu; Yu, Sicen ACS Energy Letters, Vol. 5, Issue 5 https://doi.org/10.1021/acsenergylett.0c00643	journal	April 2020
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation Michan, Alison L.; Parimalam, Bharathy. S.; Leskes, Michal Chemistry of Materials, Vol. 28, Issue 22 https://doi.org/10.1021/acs.chemmater.6b02282	journal	November 2016
A new approach toward improved low temperature performance of Li-ion battery Zhang, S. S.; Xu, K.; Jow, T. R. Electrochemistry Communications, Vol. 4, Issue 11 https://doi.org/10.1016/S1388-2481(02)00490-3	journal	November 2002
Enabling the Low-Temperature Cycling of NMC\|\|Graphite Pouch Cells with an Ester-Based Electrolyte Cho, Yoon-Gyo; Li, Mingqian; Holoubek, John ACS Energy Letters, Vol. 6, Issue 5 https://doi.org/10.1021/acsenergylett.1c00484	journal	May 2021
A Study of Three Ester Co-Solvents in Lithium-Ion Cells Ma, Xiaowei; Arumugam, Rajalakshmi S.; Ma, Lin Journal of The Electrochemical Society, Vol. 164, Issue 14 https://doi.org/10.1149/2.0411714jes	journal	January 2017
Electrochemical impedance study on the low temperature of Li-ion batteries Zhang, S. S.; Xu, K.; Jow, T. R. Electrochimica Acta, Vol. 49, Issue 7 https://doi.org/10.1016/j.electacta.2003.10.016	journal	March 2004
A Study of the Physical Properties of Li-Ion Battery Electrolytes Containing Esters Logan, E. R.; Tonita, Erin M.; Gering, K. L. Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0271802jes	journal	January 2018
Investigation of the Electrode-Electrolyte Interphase in Ester-Based Electrolytes in NCM523/Graphite Cells Rodrigo, Nuwanthi D.; Jayawardana, Chamithri; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 169, Issue 3 https://doi.org/10.1149/1945-7111/ac5a19	journal	March 2022
Ethylene carbonate-based ternary mixed solvent electrolytes for rechargeable lithium batteries Tobishima, Shin-Ichi; Hayashi, Katsuya; Saito, Kei-Ichi Electrochimica Acta, Vol. 40, Issue 5 https://doi.org/10.1016/0013-4686(95)00004-X	journal	April 1995

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