A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture

Mao, Haiyan; Tang, Jing; Day, Gregory S.; Peng, Yucan; Wang, Haoze; Xiao, Xin; Yang, Yufei; Jiang, Yuanwen; Chen, Shuo; Halat, David M.; Lund, Alicia; Lv, Xudong; Zhang, Wenbo; Yang, Chongqing; Lin, Zhou; Zhou, Hong-Cai; Pines, Alexander; Cui, Yi; Reimer, Jeffrey A.

doi:10.1126/sciadv.abo6849

Title: A scalable solid-state nanoporous network with atomic-level interaction design for carbon dioxide capture

Journal Article · Wed Aug 03 00:00:00 EDT 2022 · Science Advances

DOI:https://doi.org/10.1126/sciadv.abo6849· OSTI ID:1886938

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Univ. of California, Berkeley, CA (United States)
Stanford Univ., CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)
Texas A & M Univ., College Station, TX (United States)
Stanford Univ., CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Covalent Metrology, Sunnyvale, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry

Carbon capture and sequestration reduces carbon dioxide emissions and is critical in accomplishing carbon neutrality targets. Here, we demonstrate new sustainable, solid-state, polyamine-appended, cyanuric acid–stabilized melamine nanoporous networks (MNNs) via dynamic combinatorial chemistry (DCC) at the kilogram scale toward effective and high-capacity carbon dioxide capture. Polyamine-appended MNNs reaction mechanisms with carbon dioxide were elucidated with double-level DCC where two-dimensional heteronuclear chemical shift correlation nuclear magnetic resonance spectroscopy was performed to demonstrate the interatomic interactions. We distinguished ammonium carbamate pairs and a mix of ammonium carbamate and carbamic acid during carbon dioxide chemisorption. The coordination of polyamine and cyanuric acid modification endows MNNs with high adsorption capacity (1.82 millimoles per gram at 1 bar), fast adsorption time (less than 1 minute), low price, and extraordinary stability to cycling by flue gas. This work creates a general industrialization method toward carbon dioxide capture via DCC atomic-level design strategies.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: AC02-76SF00515; FE0026472; AC02-05CH11231

OSTI ID:: 1886938

Alternate ID(s):: OSTI ID: 1893124

Journal Information:: Science Advances, Vol. 8, Issue 31; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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