Enhancing Oxygen Reduction Activity and Cr Tolerance of Solid Oxide Fuel Cell Cathodes by a Multiphase Catalyst Coating

Niu, Yinghua; Zhou, Yucun; Lv, Weiqiang; Chen, Yu; Zhang, Yanxiang; Zhang, Weilin; Luo, Zheyu; Kane, Nicholas; Ding, Yong; Soule, Luke; Liu, Yuchen; He, Weidong; Liu, Meilin

doi:10.1002/adfm.202100034

Title: Enhancing Oxygen Reduction Activity and Cr Tolerance of Solid Oxide Fuel Cell Cathodes by a Multiphase Catalyst Coating

Journal Article · Wed Mar 10 00:00:00 EST 2021 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202100034· OSTI ID:1877394

Niu, Yinghua ^[1];

^[2]; Lv, Weiqiang ^[3]; Chen, Yu ^[4]; Zhang, Yanxiang ^[5]; Zhang, Weilin ^[2]; Luo, Zheyu ^[2]; Kane, Nicholas ^[2]; Ding, Yong ^[2]; Soule, Luke ^[2]; Liu, Yuchen ^[2]; He, Weidong ^[6];

^[2]

Georgia Inst. of Technology, Atlanta, GA (United States); Univ. of Electronic Science and Technology of China, Chengdu (China)
Georgia Inst. of Technology, Atlanta, GA (United States)
Univ. of Electronic Science and Technology of China, Chengdu (China)
South China Univ. of Technology, Guangzhou (China)
Harbin Inst. of Technology (China)
Univ. of Electronic Science and Technology of China, Chengdu (China); Harbin Inst. of Technology (China)

Intermediate temperature solid oxide fuel cells (IT-SOFCs) are cost-effective and efficient energy conversion systems. Here, the sluggish oxygen reduction reaction (ORR) and the degradation of cathodes are critical challenges to the commercialization of IT-SOFCs. Here, a highly efficient multiphase (MP) catalyst coating, consisting of Ba_1–xCo_0.7Fe_0.2Nb_0.1O_3–δ (BCFN) and BaCO₃, to enhance the ORR activity and durability of the state-of-the-art lanthanum strontium cobalt ferrite (La_0.6Sr_0.4Co_0.2Fe_0.8O_3–δ, LSCF) cathode is reported. The conformal MP catalyst-coated LSCF cathode shows a polarization resistance (R_p) of 0.048 Ω cm² at 650 °C, about one order of magnitude smaller than that of the bare LSCF. In an accelerated Cr-poisoning test, the degradation rate of the catalyst-coated LSCF electrode is 10^–3 Ω cm² h^–1 (0.59% h^–1) over 200 h, only one fifth of the degradation rate of the bare LSCF electrode at 750 °C. In addition, anode-supported single cells with the MP catalyst-coated LSCF cathode show a dramatically enhanced peak power density (1.4 W cm^–2 vs 0.67 W cm^–2 at 750 °C) and increased durability against Cr and H₂O. Both experimental results and density functional theory-based calculations indicate that the BCFN phase improves the ORR activity while the BaCO₃ phase enhances the stability of the LSCF cathode.

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Research Organization:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); National Natural Science Foundation of China (NSFC); China Scholarship Council

Grant/Contract Number:: FE0031201; DE‐FE0031201; EE0008439

OSTI ID:: 1877394

Alternate ID(s):: OSTI ID: 1804181; OSTI ID: 2205165

Journal Information:: Advanced Functional Materials, Vol. 31, Issue 19; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (67)

A robust and active hybrid catalyst for facile oxygen reduction in solid oxide fuel cells Chen, Yu; Chen, Yan; Ding, Dong Energy & Environmental Science, Vol. 10, Issue 4 https://doi.org/10.1039/C6EE03656B	journal	January 2017
Influence of Water Vapor on Performance Degradation and Microstructural Change of (La,Sr)(Co,Fe)O ₃₋ _δ Cathode Kim, Minkyu; Muroyama, Hiroki; Matsui, Toshiaki Journal of The Electrochemical Society, Vol. 166, Issue 16 https://doi.org/10.1149/2.0641915jes	journal	January 2019
Atomic Layer Deposition Functionalized Composite SOFC Cathode La _0.6 Sr _0.4 Fe _0.8 Co _0.2 O _3-δ -Gd _0.2 Ce _0.8 O _1.9 : Enhanced Long-Term Stability Gong, Yunhui; Patel, Rajankumar L.; Liang, Xinhua Chemistry of Materials, Vol. 25, Issue 21 https://doi.org/10.1021/cm402879r	journal	October 2013
Rapid chromium quantification in solid oxide fuel cell cathodes Andreas Schuler, J.; Tanasini, Pietro; Hessler-Wyser, Aïcha Scripta Materialia, Vol. 63, Issue 8 https://doi.org/10.1016/j.scriptamat.2010.06.046	journal	October 2010
Chromium Poisoning Effects on Surface Exchange Kinetics of La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O _3−δ Huang, Yi-Lin; Hussain, A. Mohammed; Pellegrinelli, Christopher ACS Applied Materials & Interfaces, Vol. 9, Issue 19 https://doi.org/10.1021/acsami.7b02762	journal	May 2017
Phase stability of BaCo1?yFeyO3?? by first principles calculations Yoshiya, M. Solid State Ionics, Vol. 172, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.02.053	journal	August 2004
Promoted Cr-poisoning tolerance of La2NiO4+δ-coated PrBa0.5Sr0.5Co1.5Fe0.5O5+δ cathode for intermediate temperature solid oxide fuel cells Li, Jin; Li, Jun; Yan, Dong Electrochimica Acta, Vol. 270 https://doi.org/10.1016/j.electacta.2018.03.053	journal	April 2018
Highly sulfur poisoning-tolerant BaCeO ₃ -impregnated La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O _{3− δ} cathodes for solid oxide fuel cells Wang, Cheng Cheng; Luo, Dawei; Jiang, San Ping Journal of Physics D: Applied Physics, Vol. 51, Issue 43 https://doi.org/10.1088/1361-6463/aadf4c	journal	September 2018
Time-Dependence of Surface Composition, Transport Properties Degradation, and Thermodynamic Consideration of La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O _3- _δ under Chromium Poisoning Budiman, R. A.; Bagarinao, K. D.; Liu, S. S. Journal of The Electrochemical Society, Vol. 165, Issue 14 https://doi.org/10.1149/2.0721814jes	journal	January 2018
La0.6Sr0.4Co0.2Fe0.8O3−δ cathodes infiltrated with samarium-doped cerium oxide for solid oxide fuel cells Nie, Lifang; Liu, Mingfei; Zhang, Yujun Journal of Power Sources, Vol. 195, Issue 15 https://doi.org/10.1016/j.jpowsour.2010.02.049	journal	August 2010
Advances in layered oxide cathodes for intermediate temperature solid oxide fuel cells Tarancón, Albert; Burriel, Mónica; Santiso, José Journal of Materials Chemistry, Vol. 20, Issue 19 https://doi.org/10.1039/b922430k	journal	January 2010
Barium Carbonate Nanoparticles as Synergistic Catalysts for the Oxygen Reduction Reaction on La_0.6Sr_0.4Co_0.2Fe_0.8O_3−δ Solid-Oxide Fuel Cell Cathodes Hong, Tao; Brinkman, Kyle S.; Xia, Changrong ChemElectroChem, Vol. 3, Issue 5, p. 805-813 https://doi.org/10.1002/celc.201500529	journal	February 2016
BaCoO _2.22 : the most oxygen-deficient certified cubic perovskite Mentré, Olivier; Iorgulescu, Mihaela; Huvé, Marielle Dalton Transactions, Vol. 44, Issue 23 https://doi.org/10.1039/C4DT03874F	journal	January 2015
Improved calculations of pore size distribution for relatively large, irregular slit-shaped mesopore structure Huang, Baiyu; Bartholomew, Calvin H.; Woodfield, Brian F. Microporous and Mesoporous Materials, Vol. 184 https://doi.org/10.1016/j.micromeso.2013.10.008	journal	January 2014
Enhanced Cr-tolerance of an SOFC cathode by an efficient electro-catalyst coating Pei, Kai; Zhou, Yucun; Xu, Kang Nano Energy, Vol. 72 https://doi.org/10.1016/j.nanoen.2020.104704	journal	June 2020
Degradation Mechanisms of La–Sr–Co–Fe–O[sub 3] SOFC Cathodes Simner, S. P.; Anderson, M. D.; Engelhard, M. H. Electrochemical and Solid-State Letters, Vol. 9, Issue 10 https://doi.org/10.1149/1.2266160	journal	January 2006
Composition and microstructure optimization and operation stability of barium deficient Ba1−xCo0.7Fe0.2Nb0.1O3−δ perovskite oxide electrodes Wang, Fucun; Chen, Dengjie; Shao, Zongping Electrochimica Acta, Vol. 103 https://doi.org/10.1016/j.electacta.2013.04.054	journal	July 2013
Cr-poisoning of a LaNi0.6Fe0.4O3 cathode under current load Stodolny, M. K.; Boukamp, B. A.; Blank, D. H. A. Journal of Power Sources, Vol. 209 https://doi.org/10.1016/j.jpowsour.2012.02.083	journal	July 2012
A niobium and tantalum co-doped perovskite cathode for solid oxide fuel cells operating below 500 °C Li, Mengran; Zhao, Mingwen; Li, Feng Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms13990	journal	January 2017
Survey of materials selection for ceramic fuel cells II. Cathodes and anodes Steele, B. Solid State Ionics, Vol. 86-88 https://doi.org/10.1016/0167-2738(96)00291-3	journal	July 1996
Structural, magnetic and electrical analysis of La1−x Nd x CrO3 (0.00 < x < 0.15): synthesised by sol–gel citrate combustion method Selvadurai, A. Paul Blessington; Pazhanivelu, V.; Jagadeeshwaran, C. Journal of Sol-Gel Science and Technology, Vol. 80, Issue 3 https://doi.org/10.1007/s10971-016-4151-8	journal	July 2016
In situ study of strontium segregation in La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O _3−δ in ambient atmospheres using high-temperature environmental scanning electron microscopy Niania, Mathew; Podor, Renaud; Britton, T. Ben Journal of Materials Chemistry A, Vol. 6, Issue 29 https://doi.org/10.1039/C8TA01341A	journal	January 2018
Mechanism of La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O ₃ cathode degradation Oh, Dongjo; Gostovic, Danijel; Wachsman, Eric D. Journal of Materials Research, Vol. 27, Issue 15 https://doi.org/10.1557/jmr.2012.222	journal	July 2012
Porous YFe0.5Co0.5O3 thin sheets as cathode for intermediate-temperature solid oxide fuel cells Cui, Jiajia; Wang, Junkai; Fan, Weiwei International Journal of Hydrogen Energy, Vol. 42, Issue 31 https://doi.org/10.1016/j.ijhydene.2017.05.109	journal	August 2017
Improving La0.6Sr0.4Co0.2Fe0.8O3−δ cathode performance by infiltration of a Sm0.5Sr0.5CoO3−δ coating Lou, Xiaoyuan; Wang, Shizhong; Liu, Ze Solid State Ionics, Vol. 180, Issue 23-25 https://doi.org/10.1016/j.ssi.2009.06.014	journal	October 2009
Thermal stability of Ba(Zr0.8−xCexY0.2)O2.9 ceramics in carbon dioxide Tu, C. -S.; Chien, R. R.; Schmidt, V. H. Journal of Applied Physics, Vol. 105, Issue 10 https://doi.org/10.1063/1.3117835	journal	May 2009
Effects of Pr3+-deficiency on structure and properties of PrBaCo2O5+δ cathode material–A comparison with Ba2+-deficiency case Jiang, Xuening; Shi, Yuchao; Zhou, Wenlong Journal of Power Sources, Vol. 272 https://doi.org/10.1016/j.jpowsour.2014.08.091	journal	December 2014
A Highly Efficient Multi-phase Catalyst Dramatically Enhances the Rate of Oxygen Reduction Chen, Yu; Choi, YongMan; Yoo, Seonyoung Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.02.008	journal	May 2018
Development of lanthanum strontium cobalt ferrite perovskite electrodes of solid oxide fuel cells – A review Jiang, San Ping International Journal of Hydrogen Energy, Vol. 44, Issue 14 https://doi.org/10.1016/j.ijhydene.2019.01.212	journal	March 2019
Pd-promoted La0.6Sr0.4Co0.2Fe0.8O3 cathodes Sahibzada, M. Solid State Ionics, Vol. 113-115, Issue 1-2 https://doi.org/10.1016/S0167-2738(98)00294-X	journal	December 1998
A highly active, CO ₂ -tolerant electrode for the oxygen reduction reaction Chen, Yu; Yoo, Seonyoung; Choi, YongMan Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/C8EE01140K	journal	January 2018
In situ exsolution of Co/CoOx core-shell nanoparticles on double perovskite porous nanotubular webs: A synergistically active catalyst for soot efficient oxidation Fang, Fan; Feng, Nengjie; Zhao, Peng Chemical Engineering Journal, Vol. 372 https://doi.org/10.1016/j.cej.2019.04.176	journal	September 2019
A kinetic study of oxygen reduction reaction on La2NiO4 cathodes by means of impedance spectroscopy Escudero, M. J.; Aguadero, A.; Alonso, J. A. Journal of Electroanalytical Chemistry, Vol. 611, Issue 1-2 https://doi.org/10.1016/j.jelechem.2007.08.006	journal	December 2007
Influence of order-disorder transitions on oxygen permeability through selected nonstoichiometric perovskite-type oxides Kruidhof, H.; Bouwmeester, H.; Vdoorn, R. Solid State Ionics, Vol. 63-65 https://doi.org/10.1016/0167-2738(93)90202-E	journal	September 1993
Impedance spectroscopy analysis of La1 − xSritxMnO3-yttria-stabilized zirconia electrode kinetics Siebert, E.; Hammouche, A.; Kleitz, M. Electrochimica Acta, Vol. 40, Issue 11 https://doi.org/10.1016/0013-4686(94)00361-4	journal	August 1995
Efficient Electro-Catalysts for Enhancing Surface Activity and Stability of SOFC Cathodes Ding, Dong; Liu, Mingfei; Liu, Zhangbo Advanced Energy Materials, Vol. 3, Issue 9 https://doi.org/10.1002/aenm.201200984	journal	May 2013
Characterization and evaluation of BaCo0.7Fe0.2Nb0.1O3−δ as a cathode for proton-conducting solid oxide fuel cells Lin, Ye; Zhou, Wei; Sunarso, Jaka International Journal of Hydrogen Energy, Vol. 37, Issue 1 https://doi.org/10.1016/j.ijhydene.2011.09.010	journal	January 2012
Cathode materials for solid oxide fuel cells: a review Sun, Chunwen; Hui, Rob; Roller, Justin Journal of Solid State Electrochemistry, Vol. 14, Issue 7 https://doi.org/10.1007/s10008-009-0932-0	journal	October 2009
Effect of cathode and electrolyte transport properties on chromium poisoning in solid oxide fuel cells Fergus, J. International Journal of Hydrogen Energy, Vol. 32, Issue 16 https://doi.org/10.1016/j.ijhydene.2006.08.005	journal	November 2007
Novel BaCo0.7Fe0.3−yNbyO3−δ (y=0–0.12) as a cathode for intermediate temperature solid oxide fuel cell Zhu, Chengjun; Liu, Xiaomei; Yi, Cuishan Electrochemistry Communications, Vol. 11, Issue 5 https://doi.org/10.1016/j.elecom.2009.02.034	journal	May 2009
A comparative investigation of chromium deposition at air electrodes of solid oxide fuel cells Jiang, S. P.; Zhang, J. P.; Zheng, X. G. Journal of the European Ceramic Society, Vol. 22, Issue 3 https://doi.org/10.1016/S0955-2219(01)00280-1	journal	March 2002
Chromium deposition and poisoning on Ba0.9Co0.7Fe0.2Nb0.1O3−δ cathode of solid oxide fuel cells Wang, Jingle; Yang, Zhibin; Yang, Kaichuang Electrochimica Acta, Vol. 289 https://doi.org/10.1016/j.electacta.2018.08.092	journal	November 2018
Ba 1−x Co 0.9−y Fe y Nb 0.1 O 3−δ ( x = 0–0.15, y = 0–0.9) as cathode materials for solid oxide fuel cells Yang, Zhi-Bin; Han, Min-Fang; Zhu, Peiyu International Journal of Hydrogen Energy, Vol. 36, Issue 15 https://doi.org/10.1016/j.ijhydene.2011.04.045	journal	July 2011
Investigation of Ba fully occupied A-site BaCo0.7Fe0.3−xNbxO3−δ perovskite stabilized by low concentration of Nb for oxygen permeation membrane Cheng, Yunfei; Zhao, Hailei; Teng, Deqiang Journal of Membrane Science, Vol. 322, Issue 2 https://doi.org/10.1016/j.memsci.2008.05.065	journal	September 2008
An effective strategy to enhancing tolerance to contaminants poisoning of solid oxide fuel cell cathodes Chen, Yu; Yoo, Seonyoung; Li, Xiaxi Nano Energy, Vol. 47 https://doi.org/10.1016/j.nanoen.2018.03.043	journal	May 2018
Chromium deposition and poisoning of cathodes of solid oxide fuel cells – A review Jiang, San Ping; Chen, Xinbing International Journal of Hydrogen Energy, Vol. 39, Issue 1 https://doi.org/10.1016/j.ijhydene.2013.10.042	journal	January 2014
Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3−δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation Zhao, Ling; Amarasinghe, Sudath; Jiang, San Ping Electrochemistry Communications, Vol. 37 https://doi.org/10.1016/j.elecom.2013.10.019	journal	December 2013
Sr Segregation in Perovskite Oxides: Why It Happens and How It Exists Koo, Bonjae; Kim, Kyeounghak; Kim, Jun Kyu Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.07.016	journal	August 2018
Nanoscale and nano-structured electrodes of solid oxide fuel cells by infiltration: Advances and challenges Jiang, San Ping International Journal of Hydrogen Energy, Vol. 37, Issue 1 https://doi.org/10.1016/j.ijhydene.2011.09.067	journal	January 2012
Intermediate temperature solid oxide fuel cells Brett, Daniel J. L.; Atkinson, Alan; Brandon, Nigel P. Chemical Society Reviews, Vol. 37, Issue 8 https://doi.org/10.1039/b612060c	journal	January 2008
Stability and performance of La0.6Sr0.4Co0.2Fe0.8O3-δ nanostructured cathodes with Ce0.8Gd0.2O1.9 surface coating dos Santos-Gómez, L.; Porras-Vázquez, J. M.; Losilla, E. R. Journal of Power Sources, Vol. 347 https://doi.org/10.1016/j.jpowsour.2017.02.045	journal	April 2017
Cathodic Polarization Phenomena of Perovskite Oxide Electrodes with Stabilized Zirconia Takeda, Y. Journal of The Electrochemical Society, Vol. 134, Issue 11 https://doi.org/10.1149/1.2100267	journal	January 1987
Mechanisms of Performance Degradation of (La,Sr)(Co,Fe)O _3-δ Solid Oxide Fuel Cell Cathodes Wang, Hongqian; Yakal-Kremski, Kyle J.; Yeh, Ted Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.0031607jes	journal	January 2016
Effect of Sr Content and Strain on Sr Surface Segregation of La _{1– x} Sr _x Co _0.2 Fe _0.8 O _3−δ as Cathode Material for Solid Oxide Fuel Cells Yu, Yang; Ludwig, Karl F.; Woicik, Joseph C. ACS Applied Materials & Interfaces, Vol. 8, Issue 40 https://doi.org/10.1021/acsami.6b07118	journal	September 2016
Modeling Elementary Heterogeneous Chemistry and Electrochemistry in Solid-Oxide Fuel Cells Zhu, Huayang; Kee, Robert J.; Janardhanan, Vinod M. Journal of The Electrochemical Society, Vol. 152, Issue 12 https://doi.org/10.1149/1.2116607	journal	January 2005
Rational SOFC material design: new advances and tools Liu, Meilin; Lynch, Matthew E.; Blinn, Kevin Materials Today, Vol. 14, Issue 11 https://doi.org/10.1016/S1369-7021(11)70279-6	journal	November 2011
Electrode reaction at Pt, O2(g)/stabilized zirconia interfaces. Part I: Theoretical consideration of reaction model Mizusaki, J. Solid State Ionics, Vol. 22, Issue 4 https://doi.org/10.1016/0167-2738(87)90149-4	journal	February 1987
Controlling cation segregation in perovskite-based electrodes for high electro-catalytic activity and durability Li, Yifeng; Zhang, Wenqiang; Zheng, Yun Chemical Society Reviews, Vol. 46, Issue 20 https://doi.org/10.1039/C7CS00120G	journal	January 2017
Effective Promotion of Oxygen Reduction Reaction by in Situ Formation of Nanostructured Catalyst Chen, Yu; Yoo, Seonyoung; Zhang, Weilin ACS Catalysis, Vol. 9, Issue 8 https://doi.org/10.1021/acscatal.9b01738	journal	June 2019
Mechanism of Cr deposition and its application in the development of Cr-tolerant cathodes of solid oxide fuel cells Jiang, San Ping; Zhen, Yongda Solid State Ionics, Vol. 179, Issue 27-32 https://doi.org/10.1016/j.ssi.2008.01.006	journal	September 2008
Toward Reducing the Operation Temperature of Solid Oxide Fuel Cells: Our Past 15 Years of Efforts in Cathode Development Yang, Guangming; Su, Chao; Shi, Huangang Energy & Fuels, Vol. 34, Issue 12 https://doi.org/10.1021/acs.energyfuels.0c01887	journal	July 2020
Surface segregation and poisoning in materials for low-temperature SOFCs Druce, John; Téllez, Helena; Hyodo, Junji MRS Bulletin, Vol. 39, Issue 9 https://doi.org/10.1557/mrs.2014.170	journal	September 2014
Materials for Intermediate-Temperature Solid-Oxide Fuel Cells Kilner, John A.; Burriel, Mónica Annual Review of Materials Research, Vol. 44, Issue 1 https://doi.org/10.1146/annurev-matsci-070813-113426	journal	July 2014
Chromium deposition and poisoning in dry and humidified air at (La0.8Sr0.2)0.9MnO3+δ cathodes of solid oxide fuel cells Chen, Xinbing; Zhen, Yongda; Li, Jian International Journal of Hydrogen Energy, Vol. 35, Issue 6 https://doi.org/10.1016/j.ijhydene.2009.12.185	journal	March 2010
Mechanism for the enhanced oxygen reduction reaction of La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O _3−δ by strontium carbonate Li, Mei; Sun, Zhongti; Yang, Wenqiang Physical Chemistry Chemical Physics, Vol. 19, Issue 1 https://doi.org/10.1039/C6CP06204K	journal	January 2017
Enhancing SOFC cathode performance by surface modification through infiltration Ding, Dong; Li, Xiaxi; Lai, Samson Yuxiu Energy & Environmental Science, Vol. 7, Issue 2 https://doi.org/10.1039/c3ee42926a	journal	January 2014
Highly chromium contaminant tolerant BaO infiltrated La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O _3−δ cathodes for solid oxide fuel cells Chen, Kongfa; Ai, Na; O'Donnell, Kane M. Physical Chemistry Chemical Physics, Vol. 17, Issue 7 https://doi.org/10.1039/C4CP04172K	journal	January 2015

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25 ENERGY STORAGE
cathodes
Cr tolerance
multiphase catalysts
oxygen reduction reactions
solid oxide fuel cells

Title: Enhancing Oxygen Reduction Activity and Cr Tolerance of Solid Oxide Fuel Cell Cathodes by a Multiphase Catalyst Coating

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