Synthesis and Characterization of Copolymers and Nanocomposites from Limonene, Styrene and Organomodified-Clay Using Ultrasonic Assisted Method

Derdar, Hodhaifa; Mitchell, Geoffey Robert; Chaibedraa, Sarra; Mahendra, Vidhura Subash; Cherifi, Zakaria; Bachari, Khaldoun; Chebout, Redouane; Touahra, Fouzia; Meghabar, Rachid; Belbachir, Mohammed

doi:10.3390/polym14142820

Title: Synthesis and Characterization of Copolymers and Nanocomposites from Limonene, Styrene and Organomodified-Clay Using Ultrasonic Assisted Method

Journal Article · Mon Jul 11 00:00:00 EDT 2022 · Polymers

DOI:https://doi.org/10.3390/polym14142820· OSTI ID:1875970

Derdar, Hodhaifa;

; Chaibedraa, Sarra;

; Cherifi, Zakaria;

; Chebout, Redouane; Touahra, Fouzia; Meghabar, Rachid; Belbachir, Mohammed

In the present work, we report a simple synthesis method for preparation of copolymers and nanocomposites from limonene and styrene using clay as a catalyst. The copolymerization reaction is carried out by using a proton exchanged clay as a catalyst called Mag-H+. The effect of temperature, reaction time and amount of catalyst were studied, and the obtained copolymer structure (lim-co-sty) is characterized by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (1H-NMR) and differential scanning calorimetry (DSC). The molecular weight of the obtained copolymer is determined by gel permeation chromatography (GPC) and is about 4500 g·mol−1. The (lim-co-sty/Mag 1%, 3%, 7% and 10% by weight of clay) nanocomposites were prepared through polymer/clay mixture in solution method using ultrasonic irradiation, in the presence of Mag-CTA+ as green nano-reinforcing filler. The Mag-CTA+ is organophilic silicate clay prepared through a direct exchange process, using cetyltrimethylammonuim bromide (CTAB). The prepared lim-co-sty/Mag nanocomposites have been extensively characterized by FT-IR spectroscopy, X-ray diffraction (XRD), scanning electronic microscopy (SEM) and transmission electronic microscopy (TEM). TEM analysis confirms the results obtained by XRD and clearly show that the obtained nanocomposites are partially exfoliated for the lower amount of clay (1% and 3% wt) and intercalated for higher amounts of clay (7% and 10% wt). Moreover, thermogravimetric analysis (TGA) indicated an enhancement of thermal stability of nanocomposites compared with the pure copolymer.

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Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office

Grant/Contract Number:: Green Thermosets Reference UID/Multi/04044/2019

OSTI ID:: 1875970

Journal Information:: Polymers, Journal Name: Polymers Vol. 14 Journal Issue: 14; ISSN 2073-4360

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Switzerland

Language:: English

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