Synthesis of Nanoceria with Varied Ratios of Ce3+/Ce4+ Utilizing Soluble Borate Glass

Ranasinghe, Kisa S.; Singh, Rajnish; Leshchev, Denis; Vasquez, Angel; Stavitski, Eli; Foster, Ian

doi:10.3390/nano12142363

Title: Synthesis of Nanoceria with Varied Ratios of Ce3+/Ce4+ Utilizing Soluble Borate Glass

Journal Article · Sun Jul 10 00:00:00 EDT 2022 · Nanomaterials

DOI:https://doi.org/10.3390/nano12142363· OSTI ID:1875631

Ranasinghe, Kisa S.; Singh, Rajnish;

; Vasquez, Angel; Stavitski, Eli; Foster, Ian

Mixed-valence cerium oxide nanoparticles (nanoceria) have been investigated with pronounced interest due to a wide range of biomedical and industrial applications that arises from its remarkable redox catalytic properties. However, there is no understanding of how to control the formation of these two types of nanoceria to obtain Ce³⁺/Ce⁴⁺ ratios required in various applications. In this work, using a soluble borate glass, nanoceria with specific ratios of Ce³⁺/Ce⁴⁺ are created and extracted via controlled glass-melting parameters. Glass embedded with nanoceria as well as nanoceria extracted from the glass were studied via XANES and fitted with the Multivariate Curve Resolution (MCR) technique to calculate the ratio of Ce³⁺/Ce⁴⁺. Results show that mixed-valence nanoceria with specific ratios are hermetically sealed within the glass for long durations. When the glass dissolves, the mixed-valence nanoceria are released, and the extracted nanoceria have unchanged Ce³⁺/Ce⁴⁺ ratios. Furthermore, TEM investigation on released nanoceria show that the nanoceria consist of several different structures. Although nanocrystal structures of Ce₇O₁₂, Ce₁₁O₂₀, and Ce₂O₃ contribute to the reduced state, a new quasi-stable phase of CeO1.66 has been observed as well.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0012704.; SC0012704

OSTI ID:: 1875631

Alternate ID(s):: OSTI ID: 1983129

Journal Information:: Nanomaterials, Journal Name: Nanomaterials Vol. 12 Journal Issue: 14; ISSN 2079-4991

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Switzerland

Language:: English

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36 MATERIALS SCIENCE
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soluble
borate glass
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Title: Synthesis of Nanoceria with Varied Ratios of Ce3+/Ce4+ Utilizing Soluble Borate Glass

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