Integration of high capacity materials into interdigitated mesostructured electrodes for high energy and high power density primary microbatteries

Pikul, James H.; Liu, Jinyun; Braun, Paul V.; King, William P.

doi:10.1016/j.jpowsour.2016.03.034

Title: Integration of high capacity materials into interdigitated mesostructured electrodes for high energy and high power density primary microbatteries

Journal Article · Tue Mar 22 00:00:00 EDT 2016 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2016.03.034· OSTI ID:1875509

Pikul, James H. ^[1]; Liu, Jinyun ^[1]; Braun, Paul V. ^[1]; King, William P. ^[1]

Univ. of Illinois at Urbana-Champaign, IL (United States)

Microbatteries are increasingly important for powering electronic systems, however, the volumetric energy density of microbatteries lags behind that of conventional format batteries. This paper reports a primary microbattery with energy density 45.5 μWh cm^–2 μm^–1 and peak power 5300 μW cm^–2 μm^–1, enabled by the integration of large volume fractions of high capacity anode and cathode chemistry into porous micro-architectures. The interdigitated battery electrodes consist of a lithium metal anode and a mesoporous manganese oxide cathode. The key enabler of the high energy and power density is the integration of the high capacity manganese oxide conversion chemistry into a mesostructured high power interdigitated bicontinuous cathode architecture and an electrodeposited dense lithium metal anode. Here, the resultant energy density is greater than previously reported three-dimensional microbatteries and is comparable to commercial conventional format lithium-based batteries.

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Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE

Grant/Contract Number:: FG02-07ER46471; AC05-06OR23100

OSTI ID:: 1875509

Alternate ID(s):: OSTI ID: 1341183

Journal Information:: Journal of Power Sources, Vol. 315; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 27 works

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References (29)

Porous Mn2O3 microsphere as a superior anode material for lithium ion batteries Deng, Yuanfu; Li, Zhanen; Shi, Zhicong RSC Advances, Vol. 2, Issue 11 https://doi.org/10.1039/c2ra20062g	journal	January 2012
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Ultrahigh-Energy-Density Microbatteries Enabled by New Electrode Architecture and Micropackaging Design Lai, Wei; Erdonmez, Can K.; Marinis, Thomas F. Advanced Materials, Vol. 22, Issue 20 https://doi.org/10.1002/adma.200903650	journal	May 2010
Three-dimensional electrodes and battery architectures Arthur, Timothy S.; Bates, Daniel J.; Cirigliano, Nicolas MRS Bulletin, Vol. 36, Issue 7 https://doi.org/10.1557/mrs.2011.156	journal	July 2011
Nanoporous Polymer-Ceramic Composite Electrolytes for Lithium Metal Batteries Tu, Zhengyuan; Kambe, Yu; Lu, Yingying Advanced Energy Materials, Vol. 4, Issue 2, Article No. 1300654 https://doi.org/10.1002/aenm.201300654	journal	September 2013
All-Solid Lithium Electrodes with Mixed-Conductor Matrix Boukamp, B. A. Journal of The Electrochemical Society, Vol. 128, Issue 4 https://doi.org/10.1149/1.2127495	journal	January 1981
A quick method of measuring the capacity versus discharge rate for a dual lithium-ion insertion cell undergoing cycling Doyle, Marc; Newman, John; Reimers, Jan Journal of Power Sources, Vol. 52, Issue 2 https://doi.org/10.1016/0378-7753(94)02012-4	journal	December 1994
High-power lithium ion microbatteries from interdigitated three-dimensional bicontinuous nanoporous electrodes Pikul, James H.; Gang Zhang, Hui; Cho, Jiung Nature Communications, Vol. 4, Article No. 1732 https://doi.org/10.1038/ncomms2747	journal	April 2013
Rapid prototyping of micropower sources by laser direct-write Piqué, A.; Arnold, C. B.; Kim, H. Applied Physics A, Vol. 79, Issue 4-6 https://doi.org/10.1007/s00339-004-2586-1	journal	September 2004
Three-Dimensional Battery Architectures Long, Jeffrey W.; Dunn, Bruce; Rolison, Debra R. Chemical Reviews, Vol. 104, Issue 10, p. 4463-4492 https://doi.org/10.1021/cr020740l	journal	October 2004
Effect of vinylene carbonate as additive to electrolyte for lithium metal anode Ota, Hitoshi; Shima, Kunihisa; Ue, Makoto Electrochimica Acta, Vol. 49, Issue 4 https://doi.org/10.1016/j.electacta.2003.09.010	journal	February 2004
A High-Voltage, Solid-State Battery System Liang, Charles C.; Epstein, James; Boyle, Gerard H. Journal of The Electrochemical Society, Vol. 116, Issue 10 https://doi.org/10.1149/1.2411560	journal	January 1969
High power rechargeable batteries Braun, Paul V.; Cho, Jiung; Pikul, James H. Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4 https://doi.org/10.1016/j.cossms.2012.05.002	journal	August 2012
A fully integrated microbattery for an implantable microelectromechanical system Albano, F.; Lin, Y. S.; Blaauw, D. Journal of Power Sources, Vol. 185, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.08.061	journal	December 2008
Characterization and optimization of a printed, primary silver–zinc battery Braam, Kyle T.; Volkman, Steven K.; Subramanian, Vivek Journal of Power Sources, Vol. 199 https://doi.org/10.1016/j.jpowsour.2011.09.076	journal	February 2012
Fabrication of micro lithium-ion battery with 3D anode and 3D cathode by using polymer wall Yoshima, Kazuomi; Munakata, Hirokazu; Kanamura, Kiyoshi Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.045	journal	June 2012
Lithium cycling efficiency and conductivity for high dielectric solvent/low viscosity solvent mixed systems Tobishima, Shin-ichi; Okada, Takeshi Electrochimica Acta, Vol. 30, Issue 12 https://doi.org/10.1016/0013-4686(85)87019-5	journal	December 1985
Spongelike Nanosized Mn ₃ O ₄ as a High-Capacity Anode Material for Rechargeable Lithium Batteries Gao, Jie; Lowe, Michael A.; Abruña, Héctor D. Chemistry of Materials, Vol. 23, Issue 13 https://doi.org/10.1021/cm201039w	journal	July 2011
Microscopic Nickel-Zinc Batteries for Use in Autonomous Microsystems Humble, Paul H.; Harb, John N.; LaFollette, Rodney Journal of The Electrochemical Society, Vol. 148, Issue 12 https://doi.org/10.1149/1.1417975	journal	January 2001
Laser direct write of planar alkaline microbatteries Arnold, C. B.; Kim, H.; Piqué, A. Applied Physics A, Vol. 79, Issue 3 https://doi.org/10.1007/s00339-004-2736-5	journal	August 2004
An all-in-one nanopore battery array Liu, Chanyuan; Gillette, Eleanor I.; Chen, Xinyi Nature Nanotechnology, Vol. 9, Issue 12 https://doi.org/10.1038/nnano.2014.247	journal	November 2014
3D Printing of Interdigitated Li-Ion Microbattery Architectures Sun, Ke; Wei, Teng-Sing; Ahn, Bok Yeop Advanced Materials, Vol. 25, Issue 33, p. 4539-4543 https://doi.org/10.1002/adma.201301036	journal	June 2013
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism Ding, Fei; Xu, Wu; Graff, Gordon L. Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456 https://doi.org/10.1021/ja312241y	journal	March 2013
Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Wang, Hailiang; Cui, Li-Feng; Yang, Yuan Journal of the American Chemical Society, Vol. 132, Issue 40, p. 13978-13980 https://doi.org/10.1021/ja105296a	journal	October 2010
Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes Zhang, Huigang; Yu, Xindi; Braun, Paul V. Nature Nanotechnology, Vol. 6, Issue 5, p. 277-281 https://doi.org/10.1038/nnano.2011.38	journal	March 2011
Pore-controlled synthesis of Mn ₂ O ₃ microspheres for ultralong-life lithium storage electrode Chang, Liang; Mai, Liqiang; Xu, Xu RSC Adv., Vol. 3, Issue 6 https://doi.org/10.1039/C2RA22735E	journal	January 2013
Electrochemical Stability of Orthopedic Porous NiTi Shape Memory Alloys Treated by Different Surface Modification Techniques Wu, Shuilin; Liu, Xiangmei; Hu, Tao Journal of The Electrochemical Society, Vol. 156, Issue 6 https://doi.org/10.1149/1.3110945	journal	January 2009
Interconnected hollow carbon nanospheres for stable lithium metal anodes Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng Nature Nanotechnology, Vol. 9, Issue 8 https://doi.org/10.1038/nnano.2014.152	journal	July 2014
Thin-film lithium and lithium-ion batteries Bates, J. Solid State Ionics, Vol. 135, Issue 1-4 https://doi.org/10.1016/S0167-2738(00)00327-1	journal	November 2000

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High performance, environmentally benign and integratable Zn//MnO ₂ microbatteries Lai, Wenhui; Wang, Yang; Lei, Zhanwu Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/c7ta10936a	journal	January 2018
High strength metallic wood from nanostructured nickel inverse opal materials Pikul, James H.; Özerinç, Sezer; Liu, Burigede Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-018-36901-3	journal	January 2019

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