Selective alkane activation with single-site atoms on amorphous support

Hock, Adam S.; Schweitzer, Neil M.; Miller, Jeffrey T.; Hu, Bo

Title: Selective alkane activation with single-site atoms on amorphous support

Patent · Tue Oct 12 00:00:00 EDT 2021

OSTI ID:1859925

Hock, Adam S.; Schweitzer, Neil M.; Miller, Jeffrey T.; Hu, Bo

The present invention relates generally to catalysts and methods for use in olefin production. More particularly, the present invention relates to novel amorphously supported single-center, Lewis acid metal ions and use of the same as catalysts.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Number(s):: 11,141,714

Application Number:: 14/946,453

OSTI ID:: 1859925

Resource Relation:: Patent File Date: 11/19/2015

Country of Publication:: United States

Language:: English

References (14)

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Dehydrogenation and oxydehydrogenation of paraffins to olefins Bhasin, M. M.; McCain, J. H.; Vora, B. V. Applied Catalysis A: General, Vol. 221, Issue 1-2, p. 397-419 https://doi.org/10.1016/S0926-860X(01)00816-X	journal	November 2001
Single-Site Heterogeneous Catalysts Thomas, John Meurig; Raja, Robert; Lewis, Dewi W. Angewandte Chemie International Edition, Vol. 44, Issue 40, p. 6456-6482 https://doi.org/10.1002/anie.200462473	journal	October 2005
Control of Dispersion of Ni ²⁺ Ions via Chelate Ligands in the Preparation of Ni/SiO ₂ Materials. A XAFS Study Carriat, J. Y.; Che, M.; Kermarec, M. Journal of the American Chemical Society, Vol. 120, Issue 9 https://doi.org/10.1021/ja9725561	journal	February 1998
Isolated Fe ^II on Silica As a Selective Propane Dehydrogenation Catalyst Hu, Bo; Schweitzer, Neil M.; Zhang, Guanghui ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00248	journal	May 2015
Identification of a Pt ₃ Co Surface Intermetallic Alloy in Pt–Co Propane Dehydrogenation Catalysts Cesar, Laryssa Goncalves; Yang, Ce; Lu, Zheng ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.9b00549	journal	April 2019
Coordination catalyst systems employing chromium support-agglomerate and method of their preparation Shih, Keng-Yu; Denton, Dean A.; Glemza, Rimantas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6946420 US Patent Document 6,946,420	patent	September 2005
Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes Ren, T.; Patel, M.; Blok, K. Energy, Vol. 31, Issue 4 https://doi.org/10.1016/j.energy.2005.04.001	journal	March 2006
The synthesis of highly dispersed noble and base metals on silica via strong electrostatic adsorption: I. Amorphous silica Jiao, Ling; Regalbuto, John R. Journal of Catalysis, Vol. 260, Issue 2 https://doi.org/10.1016/j.jcat.2008.09.022	journal	December 2008
Catalytic Conversion of Hydrocarbons Huppke, Walter F. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/2279198 US Patent Document 2,279,198	patent	April 1942
Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism Hu, Bo; “Bean” Getsoian, Andrew; Schweitzer, Neil M. Journal of Catalysis, Vol. 322 https://doi.org/10.1016/j.jcat.2014.10.018	journal	February 2015
Structure and Density of Active Zn Species in Zn/H-ZSM5 Propane Aromatization Catalysts Biscardi, Joseph A.; Meitzner, George D.; Iglesia, Enrique Journal of Catalysis, Vol. 179, Issue 1 https://doi.org/10.1006/jcat.1998.2177	journal	October 1998
Silica-Grafted Diethylzinc and a Silsesquioxane-Based Zinc Alkyl Complex as Catalysts for the Alternating Oxirane−Carbon Dioxide Copolymerization Duchateau, Robbert; van Meerendonk, Wouter J.; Huijser, Saskia Organometallics, Vol. 26, Issue 17 https://doi.org/10.1021/om700367x	journal	July 2007
Silicon based nanospheres and nanowires Gole, James L.; Wang, Zhong L. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7186669 US Patent Document 7,186,669	patent	March 2007

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