Partitioning of rare earths in multiphase nuclear waste glass‐ceramics

Chen, Hua; Marcial, José; Ahmadzadeh, Mostafa; Patil, Deepak; McCloy, John

doi:10.1111/ijag.15726

Title: Partitioning of rare earths in multiphase nuclear waste glass‐ceramics

Journal Article · Sun May 24 00:00:00 EDT 2020 · International Journal of Applied Glass Science

DOI:https://doi.org/10.1111/ijag.15726· OSTI ID:1804962

Chen, Hua ^[1];

^[2]; Ahmadzadeh, Mostafa ^[2];

^[2];

^[2]

Washington State University Pullman WA USA, Inner Mongolia University of Science and Technology Baotou PR China
Washington State University Pullman WA USA

Abstract Alumino‐borosilicate glass‐ceramics (GCs) containing alkali (Na), alkaline earth (Ca), rare earth (RE) (one of La … Lu, Y), and transition metals (Zr and Mo) were formulated to test the effects of composition and RE cation size on the crystallization of simulated nuclear waste GCs. Eight‐oxide glasses were formulated in the peraluminous ([Na ₂ O _excess ]=[Na ₂ O]‐[Al ₂ O ₃ ]‐[ZrO ₂ ]<0) region with 10 mol.% RE ₂ O ₃ and 15 mol.% B ₂ O ₃ . Glasses were melted and quenched, reheated, and slow‐cooled to promote crystallization, and then characterized using quantitative X‐ray diffraction and electron probe microanalysis. Transition metal phases [powellite (Ca,Na,RE)MoO ₄ and zirconia (Zr,RE)O ₂ or zircon (Zr,RE)SiO ₄ ] always formed, while borosilicate (RE ₃ BSi ₂ O ₁₀ ) or silicate [oxyapatite (RE,Ca,Na) ₁₀ Si ₆ O ₂₆ or keiviite (RE ₂ Si ₂ O ₇ )] plus borate (REBO ₃ ) phases also formed, depending on the size of the RE cation and hence its preferred coordination number. All crystalline phases were found to contain RE elements, and often phases incorporated other cations (Zr, Ca, B) which were not nominally part of their pure stoichiometry. These results suggested that the glass formulation and RE size strongly influenced the RE environment in the glass and hence the crystal phases formed. The formation of RE borosilicate, versus separate RE borate and RE silicate phases, also suggested original differences in the glass structure.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: DE‐NE0008431

OSTI ID:: 1804962

Journal Information:: International Journal of Applied Glass Science, Journal Name: International Journal of Applied Glass Science Vol. 11 Journal Issue: 4; ISSN 2041-1286

Publisher:: Wiley-BlackwellCopyright Statement

Country of Publication:: United States

Language:: English

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