Ultrafast Charge Transfer and Electron Delocalization in a Cyanide-Bridged Ru-Ru Dimer Investigated with Femtosecond Transient X-Ray and IR Spectroscopies

Conference · Mon Dec 28 00:00:00 EST 2020

OSTI ID:1783696

Poulter, Benjamin I. ^[1]; Biasin, Elisa ^[2]; Liekhus-Schmaltz, Chelsea E. ^[3]; Arrell, Christopher ^[4]; Augustin, Sven ^[4]; Cirelli, Claudio ^[4]; Cordones-Hahn, Amy ^[5]; Johnson, Phillip ^[4]; Knopp, Gregor ^[4]; Milne, Christopher ^[4]; Alonso-Mori, Roberto ^[6]; Ozerov, Dmitry ^[4]; Reinhard, Marco ^[5]; Sandwisch, Jason W. ^[7]; Sokaras, Dimosthenis ^[5]; Usov, Ivan ^[4]; Weakly, Robert B. ^[1]; Govind, Niranjan  ^[8]; Schoenlein, Robert W. ^[5]; Khalil, Munira H. ^[3]

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1. UNIVERSITY OF WASHINGTON (MAIN CAMPUS)
2. SLAC NATIONAL ACCELERATOR LABORATORY
3. UNIVERSITY OF WASHINGTON
4. Paul Scherrer Institute, Switzerland
5. Stanford University
6. SLAC National Accelerator Laboratory
7. University of Washington
8. BATTELLE (PACIFIC NW LAB)

Transient IR and X-Ray spectroscopies were used to investigate excited state delocalization of a mixed valence Ru based donor-bridge-acceptor complex on a femtosecond timescale revealing the role of the electron density on the Ru-CN-Ru fragment

• Research Organization: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 1783696
• Report Number(s): PNNL-SA-155150
• Resource Relation: Conference: International Conference on Ultrafast Phenomena, November 16-19, 2020, Washington, DC. OSA Technical Digest
• Country of Publication: United States
• Language: English