Modulation of the Effective Metal-Support Interactions for the Selectivity of Ceria Supported Noble Metal Nanoclusters in Atmospheric CO2 Hydrogenation

Guo, Yu; Liu, Zongyuan; Zhang, Feng; Wang, De‐Jiu; Yuan, Kun; Huang, Ling; Liu, Hai‐Chao; Senanayake, Sanjaya D.; Rodriguez, Jose A.; Yan, Chun‐Hua; Zhang, Ya‐Wen

doi:10.1002/cctc.202001531

Title: Modulation of the Effective Metal-Support Interactions for the Selectivity of Ceria Supported Noble Metal Nanoclusters in Atmospheric CO₂ Hydrogenation

Journal Article · Thu Dec 03 00:00:00 EST 2020 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.202001531· OSTI ID:1756300

Guo, Yu ^[1]; Liu, Zongyuan ^[2];

^[3]; Wang, De‐Jiu ^[1]; Yuan, Kun ^[1]; Huang, Ling ^[1]; Liu, Hai‐Chao ^[1]; Senanayake, Sanjaya D. ^[2];

^[2]; Yan, Chun‐Hua ^[1]; Zhang, Ya‐Wen ^[1]

Peking Univ., Beijing (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Stony Brook Univ., NY (United States)

Abstract Ever‐increasing attention is paid to the sustainable utilization of CO ₂ in the atmosphere out of environmental and economic considerations. The deep‐going clarification of the effective and ineffective metal‐support interactions (MSI) in the supported catalysts for the catalytic performance of CO ₂ hydrogenation is particularly needed to design highly active nanocatalysts. How to tune the MSI to be effective for the selectivity of goal hydrogenation products is a significant but rather challenging subject. In this work, we demonstrate that the selectivity in CO ₂ hydrogenation can be regulated from preferential CH ₄ production to preferential CO production by varying the nature of the electronic MSI for ceria supported noble metal nanoclusters, and the effective MSI play a pivotal role for the catalytic systems with opposite hydrogenation selectivity. The modulation of the effective MSI for the selectivity in CO ₂ hydrogenation sheds new light on the comprehensive understanding of the MSI and interfacial effects in terms of tailoring and controlling the performance of supported heterogeneous catalysts.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1756300

Alternate ID(s):: OSTI ID: 1804580

Report Number(s):: BNL-220784-2021-JAAM

Journal Information:: ChemCatChem, Vol. 13, Issue 3; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Modulation of the Effective Metal-Support Interactions for the Selectivity of Ceria Supported Noble Metal Nanoclusters in Atmospheric CO₂ Hydrogenation