Structural Assessment of Fluorine, Chlorine, Bromine, Iodine, and Hydroxide Substitutions in Lead Arsenate Apatites (Mimetites)–Pb5(AsO4)3X

Sordyl, Julia; Puzio, Bartosz; Manecki, Maciej; Borkiewicz, Olaf; Topolska, Justyna; Zelek-Pogudz, Sylwia

doi:10.3390/min10060494

Title: Structural Assessment of Fluorine, Chlorine, Bromine, Iodine, and Hydroxide Substitutions in Lead Arsenate Apatites (Mimetites)–Pb₅(AsO₄)₃X

Journal Article · Fri May 29 00:00:00 EDT 2020 · Minerals

DOI:https://doi.org/10.3390/min10060494· OSTI ID:1755174

Sordyl, Julia ^[1];

^[1];

^[1]; Borkiewicz, Olaf ^[2]; Topolska, Justyna ^[1];

^[1]

AGH - Univ. of Science and Technology, Krakow (Poland)
Argonne National Lab. (ANL), Argonne, IL (United States)

Five lead-arsenate apatites (mimetites)-Pb₅(AsO₄)₃X—where X denotes fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and hydroxide (OH)—were synthesized via precipitation from aqueous solutions. The crystal structures were determined through Rietveld refinement of powder synchrotron X-ray data. All the compounds crystallized in the hexagonal class symmetry (space group P6₃/m). The Rietveld refinement indicated that mimetite-Cl, -Br, -I, and -OH had an anion deficiency at position X. Substitution of halogens in a mimetite structure brought about systematic changes in unit-cell parameters, interatomic distances, and metaprism twist angles φ, proportional to the substituted halogen’s ionic radius. Mimetite-OH did not follow the linear correlations determined within the series. Twist angle φ, a useful device for monitoring changes in apatite topology, ranged from 20.34° for mimetite-F to 11.42° for mimetite-I. The geometric method has been proposed for determining the diameter of hexagonal channels hosting halogens in apatites. A comparison of the results with halogenated pyromorphites showed similar systematic trends: the substitutions in mimetites have comparable effect on the interatomic distances as in their phosphorous analogues.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; Polish National Science Centre (NCN)

Grant/Contract Number:: AC02-06CH11357; 2017/27/N/ST10/00776

OSTI ID:: 1755174

Journal Information:: Minerals, Vol. 10, Issue 6; ISSN 2075-163X

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Title: Structural Assessment of Fluorine, Chlorine, Bromine, Iodine, and Hydroxide Substitutions in Lead Arsenate Apatites (Mimetites)–Pb5(AsO4)3X

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