Combined light- and heat-induced shape memory behavior of anthracene-based epoxy elastomers

Li, Yuzhan; Goswami, Monojoy; Zhang, Yuehong; Liu, Tuan; Zhang, Jinwen; Kessler, Michael R.; Wang, Liwei; Rios, Orlando

doi:10.1038/s41598-020-77246-0

Title: Combined light- and heat-induced shape memory behavior of anthracene-based epoxy elastomers

Journal Article · Thu Nov 19 00:00:00 EST 2020 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-020-77246-0· OSTI ID:1720189

Li, Yuzhan; Goswami, Monojoy; Zhang, Yuehong; Liu, Tuan; Zhang, Jinwen;

;

; Rios, Orlando

AbstractThe development of multi-stimuli-responsive shape memory polymers has received increasing attention because of its scientific and technological significance. In this work, epoxy elastomers with reversible crosslinks are synthesized by polymerizing an anthracene-functionalized epoxy monomer, a diepoxy comonomer, and a dicarboxylic acid curing agent. The synthesized elastomers exhibit active responses to both light and heat enabled by the incorporated anthracene groups. When exposed to 365 nm UV light, additional crosslinking points are created by the photo-induced dimerization of pendant anthracene groups. The formation of the crosslinking points increases modulus and glass transition temperature of the elastomers, allowing for the fixation of a temporary shape at room temperature. The temporary shape remains stable until an external heat stimulus is applied to trigger the scission of the dimerized anthracene, which reduces the modulus and glass transition temperature and allows the elastomers to recover their original shapes. The effects of external stimuli on the thermal and dynamic mechanical properties of the elastomers are investigated experimentally and are correlated with molecular dynamics simulations that reveal the changes of structure and dynamics of the anthracene molecules and flexible chains.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office; US Air Force Office of Scientific Research (AFOSR); Chinese Scholarship Council

Grant/Contract Number:: AC05-00OR22725; FA-9550-12-1-0108; 201506600009

OSTI ID:: 1720189

Alternate ID(s):: OSTI ID: 1731069

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Vol. 10 Journal Issue: 1; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (37)

Shape-Memory Polymers Lendlein, Andreas; Kelch, Steffen Angewandte Chemie International Edition, Vol. 41, Issue 12, p. 2034-2057 https://doi.org/10.1002/1521-3773(20020617)41:12<2034::AID-ANIE2034>3.0.CO;2-M	journal	June 2002
Multifunctional Shape-Memory Polymers Behl, Marc; Razzaq, Muhammad Yasar; Lendlein, Andreas Advanced Materials, Vol. 22, Issue 31 https://doi.org/10.1002/adma.200904447	journal	June 2010
A Fascinating Metallo-Supramolecular Polymer Network with Thermal/Magnetic/Light-Responsive Shape-Memory Effects Anchored by Fe ₃ O ₄ Nanoparticles Du, Lan; Xu, Zhi-Yuan; Fan, Cheng-Jie Macromolecules, Vol. 51, Issue 3 https://doi.org/10.1021/acs.macromol.7b02641	journal	January 2018
Light-triggered self-healing and shape-memory polymers Habault, Damien; Zhang, Hongji; Zhao, Yue Chemical Society Reviews, Vol. 42, Issue 17 https://doi.org/10.1039/c3cs35489j	journal	January 2013
Photoresponsive Liquid Crystalline Epoxy Networks with Shape Memory Behavior and Dynamic Ester Bonds Li, Yuzhan; Rios, Orlando; Keum, Jong K. ACS Applied Materials & Interfaces, Vol. 8, Issue 24 https://doi.org/10.1021/acsami.6b04374	journal	June 2016
Electroactivate shape-memory polymer filled with nanocarbon particles and short carbon fibers Leng, Jinsong; Lv, Haibao; Liu, Yanju Applied Physics Letters, Vol. 91, Issue 14 https://doi.org/10.1063/1.2790497	journal	October 2007
Creating Poly(tetramethylene oxide) Glycol-Based Networks with Tunable Two-Way Shape Memory Effects via Temperature-Switched Netpoints Xie, Hui; Cheng, Chuan-Ying; Deng, Xiao-Ying Macromolecules, Vol. 50, Issue 13 https://doi.org/10.1021/acs.macromol.6b02773	journal	June 2017
Mechanically Robust and Recyclable Cross-Linked Fibers from Melt Blown Anthracene-Functionalized Commodity Polymers Jin, Kailong; Banerji, Aditya; Kitto, David ACS Applied Materials & Interfaces, Vol. 11, Issue 13 https://doi.org/10.1021/acsami.9b00209	journal	March 2019
Bioinspired Mechanically Adaptive Polymer Nanocomposites with Water-Activated Shape-Memory Effect Mendez, Julie; Annamalai, Pratheep K.; Eichhorn, Stephen J. Macromolecules, Vol. 44, Issue 17 https://doi.org/10.1021/ma201502k	journal	September 2011
Water-driven programmable polyurethane shape memory polymer: Demonstration and mechanism Huang, W. M.; Yang, B.; An, L. Applied Physics Letters, Vol. 86, Issue 11 https://doi.org/10.1063/1.1880448	journal	March 2005
Shape memory effect and mechanical properties of carbon nanotube/shape memory polymer nanocomposites Ni, Qing-Qing; Zhang, Chun-sheng; Fu, Yaqin Composite Structures, Vol. 81, Issue 2 https://doi.org/10.1016/j.compstruct.2006.08.017	journal	November 2007
Photo-cross-linking: A powerful and versatile strategy to develop shape-memory polymers Xie, Hui; Yang, Ke-Ke; Wang, Yu-Zhong Progress in Polymer Science, Vol. 95 https://doi.org/10.1016/j.progpolymsci.2019.05.001	journal	August 2019
Design of Poly( l -lactide)–Poly(ethylene glycol) Copolymer with Light-Induced Shape-Memory Effect Triggered by Pendant Anthracene Groups Xie, Hui; He, Man-jie; Deng, Xiao-Ying ACS Applied Materials & Interfaces, Vol. 8, Issue 14 https://doi.org/10.1021/acsami.6b00704	journal	March 2016
pH-Induced Shape-Memory Polymers Han, Xiao-Juan; Dong, Zhen-Qiang; Fan, Min-Min Macromolecular Rapid Communications, Vol. 33, Issue 12 https://doi.org/10.1002/marc.201200153	journal	April 2012
Controlled Shape Memory Behavior of a Smectic Main-Chain Liquid Crystalline Elastomer Li, Yuzhan; Pruitt, Cole; Rios, Orlando Macromolecules, Vol. 48, Issue 9 https://doi.org/10.1021/acs.macromol.5b00519	journal	April 2015
Electroactive shape memory polymer based on optimized multi-walled carbon nanotubes/polyvinyl alcohol nanocomposites Du, Fei-Peng; Ye, En-Zhou; Yang, Wen Composites Part B: Engineering, Vol. 68 https://doi.org/10.1016/j.compositesb.2014.08.043	journal	January 2015
Melt-Blown Cross-Linked Fibers from Thermally Reversible Diels–Alder Polymer Networks Jin, Kailong; Kim, Sung-soo; Xu, Jun ACS Macro Letters, Vol. 7, Issue 11 https://doi.org/10.1021/acsmacrolett.8b00685	journal	October 2018
PEG-Based Hydrogel Synthesis via the Photodimerization of Anthracene Groups Zheng, Yujun; Micic, Miodrag; Mello, Sarita V. Macromolecules, Vol. 35, Issue 13 https://doi.org/10.1021/ma012263z	journal	June 2002
Tunable Electromechanical Liquid Crystal Elastomer Actuators Guin, Tyler; Hinton, Holly E.; Burgeson, Eric Advanced Intelligent Systems, Vol. 2, Issue 7 https://doi.org/10.1002/aisy.202000022	journal	April 2020
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
Tunable polymer multi-shape memory effect Xie, Tao Nature, Vol. 464, Issue 7286 https://doi.org/10.1038/nature08863	journal	March 2010
Light-induced shape-memory polymers Lendlein, Andreas; Jiang, Hongyan; Jünger, Oliver Nature, Vol. 434, Issue 7035 https://doi.org/10.1038/nature03496	journal	April 2005
Optically triggered and spatially controllable shape-memory polymer–gold nanoparticle composite materials Zhang, Hongji; Xia, Hesheng; Zhao, Yue J. Mater. Chem., Vol. 22, Issue 3 https://doi.org/10.1039/C1JM14615G	journal	January 2012
A Facile Strategy To Construct PDLLA-PTMEG Network with Triple-Shape Effect via Photo-Cross-Linking of Anthracene Groups Xie, Hui; Cheng, Chuan-Ying; Du, Lan Macromolecules, Vol. 49, Issue 10 https://doi.org/10.1021/acs.macromol.6b00382	journal	May 2016
Photo-responsive liquid crystalline epoxy networks with exchangeable disulfide bonds Li, Yuzhan; Zhang, Yuehong; Rios, Orlando RSC Advances, Vol. 7, Issue 59 https://doi.org/10.1039/C7RA06343A	journal	January 2017
Reversible switching transitions of stimuli-responsive shape changing polymers Meng, Harper; Li, Guoqiang Journal of Materials Chemistry A, Vol. 1, Issue 27 https://doi.org/10.1039/c3ta10716g	journal	January 2013
Anthracene-Based Thiol–Ene Networks with Thermo-Degradable and Photo-Reversible Properties Van Damme, Jonas; van den Berg, Otto; Brancart, Joost Macromolecules, Vol. 50, Issue 5 https://doi.org/10.1021/acs.macromol.6b02400	journal	February 2017
Thermally and Optically Fixable Shape Memory in Azobenzene-Functionalized Glassy Liquid Crystalline Polymer Networks Wie, Jeong Jae; Lee, Kyung Min; White, Timothy J. Molecular Crystals and Liquid Crystals, Vol. 596, Issue 1 https://doi.org/10.1080/15421406.2014.918336	journal	June 2014
Polymers with Dual Light-Triggered Functions of Shape Memory and Healing Using Gold Nanoparticles Zhang, Hongji; Zhao, Yue ACS Applied Materials & Interfaces, Vol. 5, Issue 24 https://doi.org/10.1021/am404087q	journal	December 2013
Biodegradable, Elastic Shape-Memory Polymers for Potential Biomedical Applications Lendlein, Andreas; Langer, Robert Science, Vol. 296, Issue 5573, p. 1673-1676 https://doi.org/10.1126/science.1066102	journal	April 2002
Photodecomposition of anthracene on dry surfaces: products and mechanism Debestani, Reza; Ellis, Keith J.; Sigman, Michael E. Journal of Photochemistry and Photobiology A: Chemistry, Vol. 86, Issue 1-3 https://doi.org/10.1016/1010-6030(94)03945-Q	journal	February 1995
Dynamics of entangled linear polymer melts: A molecular‐dynamics simulation Kremer, Kurt; Grest, Gary S. The Journal of Chemical Physics, Vol. 92, Issue 8 https://doi.org/10.1063/1.458541	journal	April 1990
Thermo-, Photo-, and Chemo-Responsive Shape-Memory Properties from Photo-Cross-Linked Metallo-Supramolecular Polymers Kumpfer, Justin R.; Rowan, Stuart J. Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja205332w	journal	August 2011
New strategies towards reversible and mendable epoxy based materials employing [4πs+4πs] photocycloaddition and thermal cycloreversion of pendant anthracene groups Radl, Simone; Kreimer, Manuel; Griesser, Thomas Polymer, Vol. 80 https://doi.org/10.1016/j.polymer.2015.10.043	journal	December 2015
Liquid crystalline networks based on photo-initiated thiol–ene click chemistry Li, Yuzhan; Zhang, Yuehong; Goswami, Monojoy Soft Matter, Vol. 16, Issue 7 https://doi.org/10.1039/C9SM01818B	journal	January 2020
Electromagnetic Activation of Shape Memory Polymer Networks Containing Magnetic Nanoparticles Schmidt, Annette M. Macromolecular Rapid Communications, Vol. 27, Issue 14 https://doi.org/10.1002/marc.200600225	journal	July 2006
Light-Healable Epoxy Polymer Networks via Anthracene Dimer Scission of Diamine Crosslinker Hughes, Timothy; Simon, George P.; Saito, Kei ACS Applied Materials & Interfaces, Vol. 11, Issue 21 https://doi.org/10.1021/acsami.9b02521	journal	May 2019

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