Materials Data on PtCl2 by Materials Project
PtCl2 is Hg_xSn-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two PtCl2 clusters. there are two inequivalent Pt2+ sites. In the first Pt2+ site, Pt2+ is bonded in a 2-coordinate geometry to one Pt2+ and three Cl1- atoms. The Pt–Pt bond length is 2.48 Å. There are two shorter (2.19 Å) and one longer (3.02 Å) Pt–Cl bond lengths. In the second Pt2+ site, Pt2+ is bonded in a distorted linear geometry to two Cl1- atoms. There are one shorter (2.20 Å) and one longer (2.34 Å) Pt–Cl bond lengths. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 7-coordinate geometry to three Pt2+ atoms. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt2+ and one Cl1- atom. The Cl–Cl bond length is 2.79 Å. In the third Cl1- site, Cl1- is bonded in a distorted L-shaped geometry to two equivalent Cl1- atoms. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt2+ atom.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1676010
- Report Number(s):
- mp-1179938
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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