Immobilization of highly active bimetallic PdAu nanoparticles onto nanocarbons for dehydrogenation of formic acid

Hong, Wei; Kitta, Mitsunori; Tsumori, Nobuko; Himeda, Yuichiro; Autrey, S Thomas; Xu, Qiang

doi:10.1039/c9ta06014f

Title: Immobilization of highly active bimetallic PdAu nanoparticles onto nanocarbons for dehydrogenation of formic acid

Journal Article · Wed Aug 28 00:00:00 EDT 2019 · Journal of Materials Chemistry A

DOI:https://doi.org/10.1039/c9ta06014f· OSTI ID:1645102

Hong, Wei ^[1]; Kitta, Mitsunori ^[1]; Tsumori, Nobuko ^[2]; Himeda, Yuichiro ^[3];

^[4]; Xu, Qiang ^[5]

National Institute of Advanced Industrial Science and Technology, Japan
Toyama National College of Technology
VISITORS
BATTELLE (PACIFIC NW LAB)
AIST

Highly active bimetallic PdAu nanoparticles (NPs) supported on commercial nanocarbons have been prepared through a simple Larginine- mediated synthetic approach. The as-synthesized catalysts have been used for the dehydrogenation of formic acid (FA). Remarkably, the resultant Pd1Au1 NPs immobilized onto MSC-30 carbon achieved a turnover frequency (TOF) value of 8355 h1 at 60 C in aqueous FA solution without addition of sodium formate, much higher than the results of heterogeneous catalysts reported thus far. The simple small-molecule-mediated synthetic methodology developed herein opens a new path for the practical and large-scale development of high-performance catalysts for a wide range of applications.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1645102

Report Number(s):: PNNL-SA-148310

Journal Information:: Journal of Materials Chemistry A, Vol. 7, Issue 32

Country of Publication:: United States

Language:: English

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