Crystal structure of bis(1-mesityl-1 H -imidazole-κ N 3 )diphenylboron trifluoromethanesulfonate
Journal Article
·
· Acta Crystallographica. Section E, Crystallographic Communications
The solid-state structure of bis(1-mesityl-1 H -imidazole-κ N 3 )diphenylboron trifluoromethanesulfonate, C 36 H 38 BN 4 + ·CF 3 SO 3 − or ( Ph 2 B(MesIm) 2 OTf ), is reported. Bis(1-mesityl-1 H -imidazole-κ N 3 )diphenylboron ( Ph 2 B(MesIm) 2 + ) is a bulky ligand that crystallizes in the orthorhombic space group Pbcn . The asymmetric unit contains one Ph 2 B(MesIm) 2 + cationic ligand and one trifluoromethanesulfonate anion that balances the positive charge of the ligand. The tetrahedral geometry around the boron center is distorted as a result of the steric bulk of the phenyl groups. Weak interactions, such as π–π stacking are present in the crystal structure.
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- SC0019466
- OSTI ID:
- 1616623
- Journal Information:
- Acta Crystallographica. Section E, Crystallographic Communications, Journal Name: Acta Crystallographica. Section E, Crystallographic Communications Vol. 76 Journal Issue: 5; ISSN 2056-9890
- Publisher:
- International Union of Crystallography (IUCr)Copyright Statement
- Country of Publication:
- United Kingdom
- Language:
- English
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