Establishing Performance Baselines for the Oxygen Evolution Reaction in Alkaline Electrolytes

Anderson, Grace C.; Pivovar, Bryan S.; Alia, Shaun M.

doi:10.1149/1945-7111/ab7090

Title: Establishing Performance Baselines for the Oxygen Evolution Reaction in Alkaline Electrolytes

Journal Article · Fri Jan 03 00:00:00 EST 2020 · Journal of the Electrochemical Society (Online)

DOI:https://doi.org/10.1149/1945-7111/ab7090· OSTI ID:1598912

Anderson, Grace C.; Pivovar, Bryan S.; Alia, Shaun M.

This paper establishes baseline performance of several platinum group metal (PGM) and non-PGM catalysts in alkaline oxygen evolution (OER). As OER catalyst development efforts increase, there is a need to standardize testing and baseline performance to compare catalysts between different studies, better direct materials development, and understand how performance improvements translate to the device. Of the catalysts tested, metals tend to have higher half-cell activity than their fully oxidized counterparts. In single-cells, however, metal activities approach oxides, likely due to the elevated temperature, higher potential, and longer time needed to condition membrane electrode assemblies (MEAs) relative to rotating disk electrodes (RDEs). In RDEs, cobalt (Co) and ruthenium nanoparticles are the most OER active. Due to high ruthenium dissolution rates, however, iridium (Ir) is used as a PGM baseline. Activity differences between materials in RDE (Ir 320 A g^-1, Co 12 A g^-1 at 1.55 V) further appear to translate to MEAs (Ir 1370 A g^-1, Co 101 A g^-1 at 1.5 V), indicating that half-cell testing can be useful in the early stages of catalyst development to predict kinetics at the device-level.

View Journal Article

Cite

Export

Save

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1598912

Alternate ID(s):: OSTI ID: 1603263

Report Number(s):: NREL/JA-5900-75887

Journal Information:: Journal of the Electrochemical Society (Online), Journal Name: Journal of the Electrochemical Society (Online) Vol. 167 Journal Issue: 4; ISSN 1945-7111

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 24 works

Citation information provided by
Web of Science

References (120)

NixCo3−xO4 Nanowire Arrays for Electrocatalytic Oxygen Evolution Li, Yanguang; Hasin, Panitat; Wu, Yiying Advanced Materials, Vol. 22, Issue 17 https://doi.org/10.1002/adma.200903896	journal	February 2010
Operando Analysis of NiFe and Fe Oxyhydroxide Electrocatalysts for Water Oxidation: Detection of Fe ⁴⁺ by Mössbauer Spectroscopy Chen, Jamie Y. C.; Dang, Lianna; Liang, Hanfeng Journal of the American Chemical Society, Vol. 137, Issue 48 https://doi.org/10.1021/jacs.5b10699	journal	November 2015
Electrochemical investigation of surface area effects on PVD Al-Ni as electrocatalyst for alkaline water electrolysis Kjartansdóttir, Cecilía; Caspersen, Michael; Egelund, Sune Electrochimica Acta, Vol. 142 https://doi.org/10.1016/j.electacta.2014.07.061	journal	October 2014
Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst Song, Fang; Hu, Xile Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja5096733	journal	November 2014
In situ Cobalt–Cobalt Oxide/N-Doped Carbon Hybrids As Superior Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution Jin, Haiyan; Wang, Jing; Su, Diefeng Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja5127165	journal	February 2015
A monolithic metal-free electrocatalyst for oxygen evolution reaction and overall water splitting Balogun, Muhammad-Sadeeq; Qiu, Weitao; Yang, Hao Energy & Environmental Science, Vol. 9, Issue 11 https://doi.org/10.1039/C6EE01930G	journal	January 2016
Three-Dimensional N-Doped Graphene Hydrogel/NiCo Double Hydroxide Electrocatalysts for Highly Efficient Oxygen Evolution Chen, Sheng; Duan, Jingjing; Jaroniec, Mietek Angewandte Chemie International Edition, Vol. 52, Issue 51 https://doi.org/10.1002/anie.201306166	journal	November 2013
Cobalt nanoparticles embedded in porous N-rich carbon as an efficient bifunctional electrocatalyst for water splitting Li, Xingyue; Niu, Zhiguo; Jiang, Jing Journal of Materials Chemistry A, Vol. 4, Issue 9 https://doi.org/10.1039/C6TA00223D	journal	January 2016
Monodisperse Ternary NiCoP Nanostructures as a Bifunctional Electrocatalyst for Both Hydrogen and Oxygen Evolution Reactions with Excellent Performance Wang, Chunde; Jiang, Jun; Ding, Tao Advanced Materials Interfaces, Vol. 3, Issue 4 https://doi.org/10.1002/admi.201500454	journal	December 2015
SrNb _0.1 Co _0.7 Fe _0.2 O _{3− δ} Perovskite as a Next-Generation Electrocatalyst for Oxygen Evolution in Alkaline Solution Zhu, Yinlong; Zhou, Wei; Chen, Zhi-Gang Angewandte Chemie International Edition, Vol. 54, Issue 13 https://doi.org/10.1002/anie.201408998	journal	February 2015
Pristine carbon nanotubes as non-metal electrocatalysts for oxygen evolution reaction of water splitting Cheng, Yi; Xu, Changwei; Jia, Lichao Applied Catalysis B: Environmental, Vol. 163 https://doi.org/10.1016/j.apcatb.2014.07.049	journal	February 2015
Hydrogen adsorption on platinum, iridium and rhodium electrodes at reduced temperatures and the determination of real surface area Woods, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 49, Issue 2 https://doi.org/10.1016/S0022-0728(74)80229-9	journal	January 1974
Co-Ni-Based Nanotubes/Nanosheets as Efficient Water Splitting Electrocatalysts Li, Siwen; Wang, Yongcheng; Peng, Sijia Advanced Energy Materials, Vol. 6, Issue 3 https://doi.org/10.1002/aenm.201501661	journal	November 2015
Nickel nitride as an efficient electrocatalyst for water splitting Shalom, Menny; Ressnig, Debora; Yang, Xiaofei Journal of Materials Chemistry A, Vol. 3, Issue 15 https://doi.org/10.1039/C5TA00078E	journal	January 2015
Synthesis of (La, Sr)CoO ₃ perovskite films via a sol–gel route and their physicochemical and electrochemical surface characterization for anode application in alkaline water electrolysis Singh, Ravidra N.; Tiwari, Shashi K.; Singh, Shri P. J. Chem. Soc., Faraday Trans., Vol. 92, Issue 14 https://doi.org/10.1039/FT9969202593	journal	January 1996
Amorphous Ni-B alloy nanoparticle film on Ni foam: rapid alternately dipping deposition for efficient overall water splitting Liang, Yanhui; Sun, Xuping; Asiri, Abdullah M. Nanotechnology, Vol. 27, Issue 12 https://doi.org/10.1088/0957-4484/27/12/12LT01	journal	February 2016
Evolution of physicochemical and electrocatalytic properties of NiCo2O4 (AB2O4) spinel oxide with the effect of Fe substitution at the A site leading to efficient anodic O2 evolution in an alkaline environment Chanda, Debabrata; Hnát, Jaromír; Paidar, Martin International Journal of Hydrogen Energy, Vol. 39, Issue 11 https://doi.org/10.1016/j.ijhydene.2014.01.141	journal	April 2014
Oxygen evolution electrocatalysis in alkaline medium at thin MnxCo3-xO4 (0 ≤ x ≤ 1) spinel films on glass / SnO2: F prepared by spray pyrolysis Rios, E.; Chartier, P.; Gautier, J. -L. Solid State Sciences, Vol. 1, Issue 5 https://doi.org/10.1016/S1293-2558(00)80081-3	journal	July 1999
Characterization of Conductive Polymeric Nickel(II) Tetrakis(3-methoxy-4-hydroxy-phenyl)Porphyrin as an Anodic Material for Electrocatalysis Malinski, Tadeusz Journal of The Electrochemical Society, Vol. 138, Issue 7 https://doi.org/10.1149/1.2085915	journal	January 1991
Iron–Nickel Nitride Nanostructures in Situ Grown on Surface-Redox-Etching Nickel Foam: Efficient and Ultrasustainable Electrocatalysts for Overall Water Splitting Zhang, Bo; Xiao, Chunhui; Xie, Sanmu Chemistry of Materials, Vol. 28, Issue 19 https://doi.org/10.1021/acs.chemmater.6b02610	journal	September 2016
Evaluation of electrocatalysts for water electrolysis in alkaline solutions Miles, Melvin H. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 60, Issue 1 https://doi.org/10.1016/S0022-0728(75)80205-1	journal	March 1975
Low-Overpotential High-Activity Mixed Manganese and Ruthenium Oxide Electrocatalysts for Oxygen Evolution Reaction in Alkaline Media Browne, Michelle P.; Nolan, Hugo; Duesberg, Georg S. ACS Catalysis, Vol. 6, Issue 4 https://doi.org/10.1021/acscatal.5b02069	journal	March 2016
Bifunctional non-noble metal oxide nanoparticle electrocatalysts through lithium-induced conversion for overall water splitting Wang, Haotian; Lee, Hyun-Wook; Deng, Yong Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8261	journal	June 2015
Structural basis for differing electrocatalytic water oxidation by the cubic, layered and spinel forms of lithium cobalt oxides Gardner, Graeme; Al-Sharab, Jafar; Danilovic, Nemanja Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02195B	journal	January 2016
The Synthesis of Nanostructured Ni ₅ P ₄ Films and their Use as a Non-Noble Bifunctional Electrocatalyst for Full Water Splitting Ledendecker, Marc; Krick Calderón, Sandra; Papp, Christian Angewandte Chemie, Vol. 127, Issue 42 https://doi.org/10.1002/ange.201502438	journal	June 2015
Pyrochlore electrocatalysts for efficient alkaline water electrolysis Parrondo, Javier; George, Morgan; Capuano, Christopher Journal of Materials Chemistry A, Vol. 3, Issue 20 https://doi.org/10.1039/C5TA01771H	journal	January 2015
Pt-Mn 3 O 4 /C as efficient electrocatalyst for oxygen evolution reaction in water electrolysis Li, Zhuo-ying; Shi, Shu-ting; Zhong, Qi-sui Electrochimica Acta, Vol. 146 https://doi.org/10.1016/j.electacta.2014.09.067	journal	November 2014
Hierarchically Porous Ni3S2 Nanorod Array Foam as Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction and Oxygen Evolution Reaction Ouyang, Canbin; Wang, Xin; Wang, Chen Electrochimica Acta, Vol. 174 https://doi.org/10.1016/j.electacta.2015.05.186	journal	August 2015
A Flexible Electrode Based on Iron Phosphide Nanotubes for Overall Water Splitting Yan, Ya; Xia, Bao Yu; Ge, Xiaoming Chemistry - A European Journal, Vol. 21, Issue 50 https://doi.org/10.1002/chem.201503777	journal	October 2015
Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas Alia, Shaun M.; Hurst, Katherine E.; Kocha, Shyam S. Journal of The Electrochemical Society, Vol. 163, Issue 11 https://doi.org/10.1149/2.0071611jes	journal	January 2016
Electrodeposition of nickel–phosphorus nanoparticles film as a Janus electrocatalyst for electro-splitting of water Liu, Qian; Gu, Shuang; Li, Chang Ming Journal of Power Sources, Vol. 299 https://doi.org/10.1016/j.jpowsour.2015.09.027	journal	December 2015
Self-supported NiMo hollow nanorod array: an efficient 3D bifunctional catalytic electrode for overall water splitting Tian, Jingqi; Cheng, Ningyan; Liu, Qian Journal of Materials Chemistry A, Vol. 3, Issue 40 https://doi.org/10.1039/C5TA04723D	journal	January 2015
Electrocatalysis by amorphous metals of hydrogen and oxygen evolution in alkaline solution Kreysa, G.; Håkansson, B. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 201, Issue 1 https://doi.org/10.1016/0022-0728(86)90088-4	journal	April 1986
Single layer graphene encapsulating non-precious metals as high-performance electrocatalysts for water oxidation Cui, Xiaoju; Ren, Pengju; Deng, Dehui Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE03316K	journal	January 2016
Hierarchical Zn _x Co _{3– x} O ₄ Nanoarrays with High Activity for Electrocatalytic Oxygen Evolution Liu, Xijun; Chang, Zheng; Luo, Liang Chemistry of Materials, Vol. 26, Issue 5 https://doi.org/10.1021/cm4040903	journal	February 2014
Porous MoO ₂ Nanosheets as Non-noble Bifunctional Electrocatalysts for Overall Water Splitting Jin, Yanshuo; Wang, Haotian; Li, Junjie Advanced Materials, Vol. 28, Issue 19 https://doi.org/10.1002/adma.201506314	journal	March 2016
Hydrogen at Scale (H ₂ @Scale): Key to a Clean, Economic, and Sustainable Energy System Pivovar, Bryan; Rustagi, Neha; Satyapal, Sunita The Electrochemical Society Interface, Vol. 27, Issue 1 https://doi.org/10.1149/2.F04181if	journal	January 2018
Insight the effect of surface Co cations on the electrocatalytic oxygen evolution properties of cobaltite spinels Tan, Yuan; Wu, Congcong; Lin, Hong Electrochimica Acta, Vol. 121 https://doi.org/10.1016/j.electacta.2013.12.128	journal	March 2014
Cobalt nanoparticles encapsulated in nitrogen-doped carbon as a bifunctional catalyst for water electrolysis Wang, Jing; Gao, Dunfeng; Wang, Guoxiong J. Mater. Chem. A, Vol. 2, Issue 47 https://doi.org/10.1039/C4TA04337E	journal	January 2014
Oxygen Reduction Reaction Measurements on Platinum Electrocatalysts Utilizing Rotating Disk Electrode Technique: I. Impact of Impurities, Measurement Protocols and Applied Corrections Shinozaki, Kazuma; Zack, Jason W.; Richards, Ryan M. Journal of The Electrochemical Society, Vol. 162, Issue 10 https://doi.org/10.1149/2.1071509jes	journal	January 2015
Highly efficient and robust oxygen evolution catalysts achieved by anchoring nanocrystalline cobalt oxides onto mildly oxidized multiwalled carbon nanotubes Lu, Xunyu; Zhao, Chuan Journal of Materials Chemistry A, Vol. 1, Issue 39 https://doi.org/10.1039/c3ta12912h	journal	January 2013
CoP ₂ nanoparticles on reduced graphene oxide sheets as a super-efficient bifunctional electrocatalyst for full water splitting Wang, Jianmei; Yang, Wenrong; Liu, Jingquan Journal of Materials Chemistry A, Vol. 4, Issue 13 https://doi.org/10.1039/C6TA00596A	journal	January 2016
High activity and durability of novel perovskite electrocatalysts for water oxidation Zhou, Wei; Zhao, Mingwen; Liang, Fengli Materials Horizons, Vol. 2, Issue 5 https://doi.org/10.1039/C5MH00096C	journal	January 2015
Cobalt phosphide-based nanoparticles as bifunctional electrocatalysts for alkaline water splitting Vigil, Julian A.; Lambert, Timothy N.; Christensen, Benjamin T. Journal of Materials Chemistry A, Vol. 4, Issue 20 https://doi.org/10.1039/C6TA00637J	journal	January 2016
Ni ₃ Se ₂ film as a non-precious metal bifunctional electrocatalyst for efficient water splitting Shi, Jinle; Hu, Jianming; Luo, Yonglan Catalysis Science & Technology, Vol. 5, Issue 11 https://doi.org/10.1039/C5CY01121C	journal	January 2015
Synthesis and Activities of Rutile IrO ₂ and RuO ₂ Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions Lee, Youngmin; Suntivich, Jin; May, Kevin J. The Journal of Physical Chemistry Letters, Vol. 3, Issue 3 https://doi.org/10.1021/jz2016507	journal	January 2012
Metal–organic framework-based CoP/reduced graphene oxide: high-performance bifunctional electrocatalyst for overall water splitting Jiao, Long; Zhou, Yu-Xiao; Jiang, Hai-Long Chemical Science, Vol. 7, Issue 3 https://doi.org/10.1039/C5SC04425A	journal	January 2016
Graphene-Co3O4 nanocomposite as electrocatalyst with high performance for oxygen evolution reaction Zhao, Yufei; Chen, Shuangqiang; Sun, Bing Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep07629	journal	January 2015
Strong-Coupled Cobalt Borate Nanosheets/Graphene Hybrid as Electrocatalyst for Water Oxidation Under Both Alkaline and Neutral Conditions Chen, Pengzuo; Xu, Kun; Zhou, Tianpei Angewandte Chemie International Edition, Vol. 55, Issue 7 https://doi.org/10.1002/anie.201511032	journal	January 2016
Electrocatalytic Oxygen Evolution over Supported Small Amorphous Ni–Fe Nanoparticles in Alkaline Electrolyte Qiu, Yang; Xin, Le; Li, Wenzhen Langmuir, Vol. 30, Issue 26 https://doi.org/10.1021/la501246e	journal	June 2014
Mechanisms of pH-Dependent Activity for Water Oxidation to Molecular Oxygen by MnO ₂ Electrocatalysts Takashima, Toshihiro; Hashimoto, Kazuhito; Nakamura, Ryuhei Journal of the American Chemical Society, Vol. 134, Issue 3 https://doi.org/10.1021/ja206511w	journal	January 2012
Mechanistic insight into oxygen evolution electrocatalysis of surface phosphate modified cobalt phosphide nanorod bundles and their superior performance for overall water splitting Ai, Lunhong; Niu, Zhiguo; Jiang, Jing Electrochimica Acta, Vol. 242 https://doi.org/10.1016/j.electacta.2017.05.032	journal	July 2017
Nickel–cobalt layered double hydroxide nanosheets as high-performance electrocatalyst for oxygen evolution reaction Jiang, Jing; Zhang, Ailing; Li, Lili Journal of Power Sources, Vol. 278 https://doi.org/10.1016/j.jpowsour.2014.12.085	journal	March 2015
Iridium–nickel composite oxide catalysts for oxygen evolution reaction in acidic water electrolysis Xu, Shuai; Liu, Yuan; Tong, Jinlin Russian Journal of Electrochemistry, Vol. 52, Issue 11 https://doi.org/10.1134/S1023193516110124	journal	November 2016
Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities Lu, Xunyu; Zhao, Chuan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7616	journal	March 2015
Zn0.76Co0.24S/CoS2 nanowires array for efficient electrochemical splitting of water Liang, Yanhui; Liu, Qian; Luo, Yonglan Electrochimica Acta, Vol. 190 https://doi.org/10.1016/j.electacta.2015.12.153	journal	February 2016
Enhanced water electrolysis: Electrocatalytic generation of oxygen gas at manganese oxide nanorods modified electrodes El-Deab, Mohamed S.; Awad, Mohamed I.; Mohammad, Ahmad M. Electrochemistry Communications, Vol. 9, Issue 8 https://doi.org/10.1016/j.elecom.2007.06.011	journal	August 2007
Efficient and Stable Bifunctional Electrocatalysts Ni/Ni _x M _y (M = P, S) for Overall Water Splitting Chen, Gao-Feng; Ma, Tian Yi; Liu, Zhao-Qing Advanced Functional Materials, Vol. 26, Issue 19 https://doi.org/10.1002/adfm.201505626	journal	March 2016
Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction Grimaud, Alexis; Demortière, Arnaud; Saubanère, Matthieu Nature Energy, Vol. 2, Issue 1 https://doi.org/10.1038/nenergy.2016.189	journal	December 2016
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407115p	journal	October 2013
High-Index Faceted Ni ₃ S ₂ Nanosheet Arrays as Highly Active and Ultrastable Electrocatalysts for Water Splitting Feng, Liang-Liang; Yu, Guangtao; Wu, Yuanyuan Journal of the American Chemical Society, Vol. 137, Issue 44 https://doi.org/10.1021/jacs.5b08186	journal	September 2015
Efficient Water Oxidation Using CoMnP Nanoparticles Li, Da; Baydoun, Habib; Verani, Cláudio N. Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.6b01543	journal	March 2016
Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0–14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity Gerken, James B.; McAlpin, J. Gregory; Chen, Jamie Y. C. Journal of the American Chemical Society, Vol. 133, Issue 36 https://doi.org/10.1021/ja205647m	journal	August 2011
Nanoparticle-Stacked Porous Nickel–Iron Nitride Nanosheet: A Highly Efficient Bifunctional Electrocatalyst for Overall Water Splitting Wang, Yanyong; Xie, Chao; Liu, Dongdong ACS Applied Materials & Interfaces, Vol. 8, Issue 29 https://doi.org/10.1021/acsami.6b05811	journal	July 2016
Electrochemical Analysis of Synthetized Iridium Nanoparticles for Oxygen Evolution Reaction in Acid Medium Lettenmeier, P.; Majchel, J.; Wang, L. ECS Transactions, Vol. 72, Issue 23 https://doi.org/10.1149/07223.0001ecst	journal	August 2016
Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation Trotochaud, Lena; Young, Samantha L.; Ranney, James K. Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja502379c	journal	April 2014
Selenide-Based Electrocatalysts and Scaffolds for Water Oxidation Applications Xia, Chuan; Jiang, Qiu; Zhao, Chao Advanced Materials, Vol. 28, Issue 1 https://doi.org/10.1002/adma.201503906	journal	November 2015
A Heterostructure Coupling of Exfoliated Ni-Fe Hydroxide Nanosheet and Defective Graphene as a Bifunctional Electrocatalyst for Overall Water Splitting Jia, Yi; Zhang, Longzhou; Gao, Guoping Advanced Materials, Vol. 29, Issue 17 https://doi.org/10.1002/adma.201700017	journal	March 2017
Activity and Durability of Iridium Nanoparticles in the Oxygen Evolution Reaction Alia, Shaun M.; Rasimick, Brian; Ngo, Chilan Journal of The Electrochemical Society, Vol. 163, Issue 11 https://doi.org/10.1149/2.0151611jes	journal	January 2016
Development of Cobalt Hydroxide as a Bifunctional Catalyst for Oxygen Electrocatalysis in Alkaline Solution Zhan, Yi; Du, Guojun; Yang, Shiliu ACS Applied Materials & Interfaces, Vol. 7, Issue 23 https://doi.org/10.1021/acsami.5b02670	journal	March 2015
An efficient bifunctional electrocatalyst for water splitting based on cobalt phosphide Yang, Libin; Qi, Honglan; Zhang, Chengxiao Nanotechnology, Vol. 27, Issue 23 https://doi.org/10.1088/0957-4484/27/23/23LT01	journal	May 2016
Highly defective CeO ₂ as a promoter for efficient and stable water oxidation Liang, Fengli; Yu, Ying; Zhou, Wei Journal of Materials Chemistry A, Vol. 3, Issue 2 https://doi.org/10.1039/C4TA05770H	journal	January 2015
Co3O4 nanocrystals on single-walled carbon nanotubes as a highly efficient oxygen-evolving catalyst Wu, Jian; Xue, Yan; Yan, Xin Nano Research, Vol. 5, Issue 8 https://doi.org/10.1007/s12274-012-0237-y	journal	July 2012
Three-dimensional coral-like cobalt selenide as an advanced electrocatalyst for highly efficient oxygen evolution reaction Liao, Mei; Zeng, Guangfeng; Luo, Tingting Electrochimica Acta, Vol. 194 https://doi.org/10.1016/j.electacta.2016.02.046	journal	March 2016
Surface engineering by a novel electrochemical activation method for the synthesis of Co3+ enriched Co(OH)2/CoOOH heterostructure for water oxidation Liu, Lu; Ou, Yingqing; Gao, Di Journal of Power Sources, Vol. 396 https://doi.org/10.1016/j.jpowsour.2018.06.030	journal	August 2018
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation Gorlin, Yelena; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614 https://doi.org/10.1021/ja104587v	journal	October 2010
Ni Inverse Opals for Water Electrolysis in an Alkaline Electrolyte Huang, Yi-Jui; Lai, Chun-Han; Wu, Pu-Wei Journal of The Electrochemical Society, Vol. 157, Issue 3 https://doi.org/10.1149/1.3281332	journal	January 2010
CuxCo3−xO4 (0 ≤x < 1) nanoparticles for oxygen evolution in high performance alkaline exchange membrane water electrolysers Wu, Xu; Scott, Keith Journal of Materials Chemistry, Vol. 21, Issue 33 https://doi.org/10.1039/c1jm11312g	journal	January 2011
Inexpensive electrochemical synthesis of nickel iron sulphides on nickel foam: super active and ultra-durable electrocatalysts for alkaline electrolyte membrane water electrolysis Ganesan, Pandian; Sivanantham, Arumugam; Shanmugam, Sangaraju Journal of Materials Chemistry A, Vol. 4, Issue 42 https://doi.org/10.1039/C6TA04499A	journal	January 2016
Anodically electrodeposited Co+Ni mixed oxide electrode: preparation and electrocatalytic activity for oxygen evolution in alkaline media Wu, Gang; Li, Ning; Zhou, De-Rui Journal of Solid State Chemistry, Vol. 177, Issue 10, p. 3682-3692 https://doi.org/10.1016/j.jssc.2004.06.027	journal	October 2004
Efficient Electrocatalytic Oxygen Evolution on Amorphous Nickel–Cobalt Binary Oxide Nanoporous Layers Yang, Yang; Fei, Huilong; Ruan, Gedeng ACS Nano, Vol. 8, Issue 9 https://doi.org/10.1021/nn503760c	journal	August 2014
In Situ Derived CoB Nanoarray: A High-Efficiency and Durable 3D Bifunctional Electrocatalyst for Overall Alkaline Water Splitting Lu, Wenbo; Liu, Tingting; Xie, Lisi Small, Vol. 13, Issue 32 https://doi.org/10.1002/smll.201700805	journal	June 2017
Nitrogen-doped carbon nanomaterials as non-metal electrocatalysts for water oxidation Zhao, Yong; Nakamura, Ryuhei; Kamiya, Kazuhide Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3390	journal	August 2013
Evaluating Hydrogen Evolution and Oxidation in Alkaline Media to Establish Baselines Alia, Shaun M.; Pivovar, Bryan S. Journal of The Electrochemical Society, Vol. 165, Issue 7 https://doi.org/10.1149/2.0361807jes	journal	January 2018
An Advanced Ni–Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation Gong, Ming; Li, Yanguang; Wang, Hailiang Journal of the American Chemical Society, Vol. 135, Issue 23 https://doi.org/10.1021/ja4027715	journal	May 2013
An electrodeposited cobalt–selenide-based film as an efficient bifunctional electrocatalyst for full water splitting Xu, Xiujuan; Du, Puyu; Chen, Zongkun Journal of Materials Chemistry A, Vol. 4, Issue 28 https://doi.org/10.1039/C6TA03788G	journal	January 2016
Co/Co9S8@S,N-doped porous graphene sheets derived from S, N dual organic ligands assembled Co-MOFs as superior electrocatalysts for full water splitting in alkaline media Zhang, Xian; Liu, Shengwen; Zang, Yipeng Nano Energy, Vol. 30 https://doi.org/10.1016/j.nanoen.2016.09.040	journal	December 2016
An Alkaline Water Electrolyzer with Sustainion™ Membranes: 1 A/cm² at 1.9V with Base Metal Catalysts Liu, Zengcai; Sajjad, Syed D.; Gao, Yan ECS Transactions, Vol. 77, Issue 9 https://doi.org/10.1149/07709.0071ecst	journal	May 2017
Iridium Oxygen Evolution Activity and Durability Baselines in Rotating Disk Electrode Half-Cells Alia, Shaun M.; Anderson, Grace C. Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.0731904jes	journal	January 2019
Ni ₂ P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni ₂ P nanoparticles Stern, Lucas-Alexandre; Feng, Ligang; Song, Fang Energy & Environmental Science, Vol. 8, Issue 8 https://doi.org/10.1039/C5EE01155H	journal	January 2015
Porous Cobalt-Based Thin Film as a Bifunctional Catalyst for Hydrogen Generation and Oxygen Generation Yang, Yang; Fei, Huilong; Ruan, Gedeng Advanced Materials, Vol. 27, Issue 20 https://doi.org/10.1002/adma.201500894	journal	April 2015
Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution Trotochaud, Lena; Ranney, James K.; Williams, Kerisha N. Journal of the American Chemical Society, Vol. 134, Issue 41 https://doi.org/10.1021/ja307507a	journal	October 2012
Ternary NiCoP nanosheet arrays: An excellent bifunctional catalyst for alkaline overall water splitting Li, Yingjie; Zhang, Haichuan; Jiang, Ming Nano Research, Vol. 9, Issue 8 https://doi.org/10.1007/s12274-016-1112-z	journal	June 2016
Electrolyzer Durability at Low Catalyst Loading and with Dynamic Operation Alia, Shaun M.; Stariha, Sarah; Borup, Rod L. Journal of The Electrochemical Society, Vol. 166, Issue 15 https://doi.org/10.1149/2.0231915jes	journal	January 2019
Electrodeposited Ni-P Alloy Nanoparticle Films for Efficiently Catalyzing Hydrogen- and Oxygen-Evolution Reactions Tang, Chun; Asiri, Abdullah M.; Luo, Yonglan ChemNanoMat, Vol. 1, Issue 8 https://doi.org/10.1002/cnma.201500163	journal	November 2015
Electrodeposited Co-doped NiSe ₂ nanoparticles film: a good electrocatalyst for efficient water splitting Liu, Tingting; Asiri, Abdullah M.; Sun, Xuping Nanoscale, Vol. 8, Issue 7 https://doi.org/10.1039/C5NR07170D	journal	January 2016
Core-Ring Structured NiCo2O4 Nanoplatelets: Synthesis, Characterization, and Electrocatalytic Applications Cui, Bai; Lin, Hong; Li, Jian-Bao Advanced Functional Materials, Vol. 18, Issue 9 https://doi.org/10.1002/adfm.200700982	journal	April 2008
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces Man, Isabela C.; Su, Hai‐Yan; Calle‐Vallejo, Federico ChemCatChem, Vol. 3, Issue 7 https://doi.org/10.1002/cctc.201000397	journal	March 2011
Overall Water Splitting Catalyzed Efficiently by an Ultrathin Nanosheet-Built, Hollow Ni ₃ S ₂ -Based Electrocatalyst Wu, Yuanyuan; Li, Guo-Dong; Liu, Yipu Advanced Functional Materials, Vol. 26, Issue 27 https://doi.org/10.1002/adfm.201601315	journal	May 2016
Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions Maiyalagan, Thandavarayan; Jarvis, Karalee A.; Therese, Soosairaj Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4949	journal	May 2014
Structure–Property Relationship of Bifunctional MnO ₂ Nanostructures: Highly Efficient, Ultra-Stable Electrochemical Water Oxidation and Oxygen Reduction Reaction Catalysts Identified in Alkaline Media Meng, Yongtao; Song, Wenqiao; Huang, Hui Journal of the American Chemical Society, Vol. 136, Issue 32 https://doi.org/10.1021/ja505186m	journal	August 2014
Hierarchically Porous Nickel Sulfide Multifunctional Superstructures You, Bo; Sun, Yujie Advanced Energy Materials, Vol. 6, Issue 7 https://doi.org/10.1002/aenm.201502333	journal	January 2016
The Roles of Oxide Growth and Sub-Surface Facets in Oxygen Evolution Activity of Iridium and Its Impact on Electrolysis Alia, Shaun M.; Ha, Mai-Anh; Anderson, Grace C. Journal of The Electrochemical Society, Vol. 166, Issue 15 https://doi.org/10.1149/2.0771915jes	journal	January 2019
Rational composition and structural design of in situ grown nickel-based electrocatalysts for efficient water electrolysis Liu, Xiangye; Wang, Xin; Yuan, Xiaotao Journal of Materials Chemistry A, Vol. 4, Issue 1 https://doi.org/10.1039/C5TA07047C	journal	January 2016
Nitrogen-Doped Graphene Supported CoSe ₂ Nanobelt Composite Catalyst for Efficient Water Oxidation Gao, Min-Rui; Cao, Xuan; Gao, Qiang ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn500880v	journal	March 2014
Nickel promoted cobalt disulfide nanowire array supported on carbon cloth: An efficient and stable bifunctional electrocatalyst for full water splitting Fang, Weizhen; Liu, Danni; Lu, Qun Electrochemistry Communications, Vol. 63 https://doi.org/10.1016/j.elecom.2015.10.010	journal	February 2016
Lanthanum Phosphate-Bonded Composite Nickel-Rhodium Electrodes for Alkaline Water Electrolysis Dumont, H. Journal of The Electrochemical Society, Vol. 139, Issue 8 https://doi.org/10.1149/1.2221192	journal	January 1992
Nickel sulfide microsphere film on Ni foam as an efficient bifunctional electrocatalyst for overall water splitting Zhu, Wenxin; Yue, Xiaoyue; Zhang, Wentao Chemical Communications, Vol. 52, Issue 7 https://doi.org/10.1039/C5CC08064A	journal	January 2016
The Catalysis of the Oxygen Evolution Reaction by Iron Impurities in Thin Film Nickel Oxide Electrodes Corrigan, Dennis A. Journal of The Electrochemical Society, Vol. 134, Issue 2 https://doi.org/10.1149/1.2100463	journal	January 1987
One-step electrodeposition of Ni–Co–S nanosheets film as a bifunctional electrocatalyst for efficient water splitting Liu, Tingting; Sun, Xuping; Asiri, Abdullah M. International Journal of Hydrogen Energy, Vol. 41, Issue 18 https://doi.org/10.1016/j.ijhydene.2016.03.111	journal	May 2016
Hydrogen Production From Water Electrolysis: Current Status and Future Trends Ursua, Alfredo; Gandia, Luis M.; Sanchis, Pablo Proceedings of the IEEE, Vol. 100, Issue 2 https://doi.org/10.1109/JPROC.2011.2156750	journal	February 2012
Surface Oxidized Cobalt-Phosphide Nanorods As an Advanced Oxygen Evolution Catalyst in Alkaline Solution Chang, Jinfa; Xiao, Yao; Xiao, Meiling ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b02076	journal	October 2015
Novel electrocatalysts for generating oxygen from alkaline water electrolysis Singh, R. N.; Mishra, D. Electrochemistry Communications, Vol. 9, Issue 6 https://doi.org/10.1016/j.elecom.2007.01.044	journal	June 2007
Ultrathin Laminar Ir Superstructure as Highly Efficient Oxygen Evolution Electrocatalyst in Broad pH Range Pi, Yecan; Zhang, Nan; Guo, Shaojun Nano Letters, Vol. 16, Issue 7 https://doi.org/10.1021/acs.nanolett.6b01554	journal	June 2016
Electrodeposited Cobalt-Phosphorous-Derived Films as Competent Bifunctional Catalysts for Overall Water Splitting Jiang, Nan; You, Bo; Sheng, Meili Angewandte Chemie, Vol. 127, Issue 21 https://doi.org/10.1002/ange.201501616	journal	April 2015
An amorphous CoSe film behaves as an active and stable full water-splitting electrocatalyst under strongly alkaline conditions Liu, Tingting; Liu, Qian; Asiri, Abdullah M. Chemical Communications, Vol. 51, Issue 93 https://doi.org/10.1039/C5CC06892D	journal	January 2015
Electrolytic Oxygen Evolution in Alkaline Medium on La[sub 1−x]Sr[sub x]FeO[sub 3−y] Perovskite-Related Ferrites Wattiaux, A. Journal of The Electrochemical Society, Vol. 134, Issue 7 https://doi.org/10.1149/1.2100741	journal	January 1987
Metallic Co ₂ P ultrathin nanowires distinguished from CoP as robust electrocatalysts for overall water-splitting Jin, Zhaoyu; Li, Panpan; Xiao, Dan Green Chemistry, Vol. 18, Issue 6 https://doi.org/10.1039/C5GC02462E	journal	January 2016
Low-temperature synthesis of perovskite-type oxides of lanthanum and cobalt and their electrocatalytic properties for oxygen evolution in alkaline solutions Jain, Amar N.; Tiwari, Shashi K.; Singh, Ravindra N. Journal of the Chemical Society, Faraday Transactions, Vol. 91, Issue 12 https://doi.org/10.1039/ft9959101871	journal	January 1995
Co/CoO nanoparticles immobilized on Co–N-doped carbon as trifunctional electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions Zhang, Xian; Liu, Rongrong; Zang, Yipeng Chemical Communications, Vol. 52, Issue 35 https://doi.org/10.1039/C6CC02513G	journal	January 2016

Similar Records

Catalytic Activity and Stability of Non-Platinum Group Metal Oxides for the Oxygen Evolution Reaction in Anion Exchange Membrane Electrolyzers

Journal Article · Fri Jun 16 00:00:00 EDT 2023 · Journal of the Electrochemical Society · OSTI ID:1598912

Volk, Emily K.; Kwon, Stephanie; Alia, Shaun M.

Effects of Ink Formulation on the Structure and Performance of PGM-Free Catalyst Layer in PEMFCs

Journal Article · Fri Oct 01 00:00:00 EDT 2021 · ECS Transactions · OSTI ID:1598912

Li, Chenzhao; Liu, Shengwen; Zeng, Yachao; +4 more

Synthesis and Characterization of Mixed-Conducting Corrosion Resistant Oxide Supports

Technical Report · Sat Jan 31 00:00:00 EST 2015 · OSTI ID:1598912

Ramani, Vijay K.

Related Subjects

36 MATERIALS SCIENCE
77 NANOSCIENCE AND NANOTECHNOLOGY
nanomaterials
oxygen evolution
electrolysis
electrochemistry

Title: Establishing Performance Baselines for the Oxygen Evolution Reaction in Alkaline Electrolytes

Citation Formats

References (120)

Similar Records

Related Subjects