A Highly Reversible Zn Anode with Intrinsically Safe Organic Electrolyte for Long-Cycle-Life Batteries

Naveed, Ahmad; Yang, Huijun; Shao, Yuyan; Yang, Jun; Yanna, Nuli; Liu, Jun; Shi, Siqi; Zhang, Liwen; Ye, Anjiang; He, Bing; Wang, Jiulin

doi:10.1002/adma.201900668

Title: A Highly Reversible Zn Anode with Intrinsically Safe Organic Electrolyte for Long-Cycle-Life Batteries

Journal Article · Fri Sep 06 00:00:00 EDT 2019 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201900668· OSTI ID:1571480

Naveed, Ahmad ^[1]; Yang, Huijun ^[1];

^[2]; Yang, Jun ^[1]; Yanna, Nuli ^[3]; Liu, Jun ^[4]; Shi, Siqi ^[5]; Zhang, Liwen ^[5]; Ye, Anjiang ^[5]; He, Bing ^[5]; Wang, Jiulin ^[6]

Shanghai Jiao Tong University
BATTELLE (PACIFIC NW LAB)
Beijing Jiaotong University
PNNL
Shanghai University
UNIVERSITY PROGRAMS

Dendrite has puzzled the metal anodes including Li and Zn for rechargeable batteries more than decades of years. Here we bypass this obstacle via adopting non-flammable Trimethyl Phosphate (TMP) safe organic electrolyte to build zinc ion batteries. The graphene-like form Zn deposit was gained via TMP surfactant and Zn3(PO4)2 molecular template. This novel morphology Zn anode demonstrates highly stable and reversible plating/stripping for more than 2000 hours without dendrite, and a remarkably high Coulombic efficiency (CE) of 99.57 %. Addition of Dimethyl Carbonate (DMC) to TMP enhanced the stability of Zn/Zn symmetric cells to over 5000 hours without sacrificing the CE (99.15 %) of Zn deposition/dissolution. Moreover, non-aqueous Zn-VS2 battery delivered a specific capacity of 146.6 mA h g-1 with a capacity retention of 94.38 % over 500 cycles. Excellent anodic stability, high CE and cycling stability of the full cell expands the scope for developing low cost, safe and high performance non-aqueous Zn batteries.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1571480

Report Number(s):: PNNL-SA-146185

Journal Information:: Advanced Materials, Vol. 31, Issue 36

Country of Publication:: United States

Language:: English

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