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Title: Low cost rechargeable battery and the method for making the same

Patent ·
OSTI ID:1568725

Low-cost electrochemical energy storage devices having electrochemical cells containing zinc electrodes in aqueous electrolytes, which exhibit superior cycle performance, preferably comprise the following elements: (a) a cathode formed of manganese dioxide particles, preferably doped with at least one of magnesium, strontium, barium, calcium, and lanthanum, wherein the manganese dioxide particles preferably form at least one of (1) a delta manganese dioxide structure and (2) a todokorite manganese dioxide structure; (b) an anode formed of particles comprising zinc, wherein the particles are preferably treated with at least one of bismuth, indium, gallium, antimony, and tin; (c) a mixed ion electrolyte solution with a pH greater than or equal to three and less than or equal to seven, wherein the solution preferably comprises at least one monovalent salt and at least one divalent salt; and (d) a mesh as cathode current collector comprising at least one of titanium, stainless steel, tantalum, and niobium, wherein the mesh is preferably coated by an electrically conductive and yet oxidation resistant material comprising but not limited to carbon.

Research Organization:
Bettergy Corp., Peekskill, NY (United States)
Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
DOE Contract Number:
AR0000382
Assignee:
Bettergy Corp. (Peekskill, NY)
Patent Number(s):
10,381,645
Application Number:
15/378,200
OSTI ID:
1568725
Resource Relation:
Patent File Date: 12/14/2016
Country of Publication:
United States
Language:
English

References (12)

Rechargeable Zinc Ion Battery patent-application February 2012
Non-Aqueous Secondary Battery patent-application September 2014
Method of making a rechargable modified manganese dioxide material and related compound and electrode material patent October 1992
Rechargeable alkaline manganese dioxide-zinc cell with low internal resistance and improved cycle life patent May 1990
Mixed Metal Cathode for Secondary Alkaline Batteries patent-application July 2017
Flexible thin printed battery and device and method of manufacturing same patent-application September 2003
Rechargeable zinc/manganese dioxide cell patent May 1984
Electrochemical Cell with Divalent Cation Electrolyte and at Least One Intercalation Electrode patent-application August 2015
Aqueous zinc sulfate (II) rechargeable cell containing manganese (II) salt and carbon powder patent February 2001
Method of making a compound patent May 1985
Electrostatic Image Developing Toner patent-application January 2011
Electrode-Supported Tubular Solid-Oxide Electrochemical Cell patent-application April 2017

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