Co-optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells: SnS absorber and Zn(O,S) buffer materials for improved solar cells

Park, Helen Hejin; Heasley, Rachel; Sun, Leizhi; Steinmann, Vera; Jaramillo, Rafael; Hartman, Katy; Chakraborty, Rupak; Sinsermsuksakul, Prasert; Chua, Danny; Buonassisi, Tonio; Gordon, Roy G.

doi:10.1002/pip.2504

Title: Co-optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells: SnS absorber and Zn(O,S) buffer materials for improved solar cells

Journal Article · Mon May 05 00:00:00 EDT 2014 · Progress in Photovoltaics

DOI:https://doi.org/10.1002/pip.2504· OSTI ID:1557830

Park, Helen Hejin ^[1]; Heasley, Rachel ^[1]; Sun, Leizhi ^[1]; Steinmann, Vera ^[2]; Jaramillo, Rafael ^[2]; Hartman, Katy ^[2]; Chakraborty, Rupak ^[2]; Sinsermsuksakul, Prasert ^[1]; Chua, Danny ^[1]; Buonassisi, Tonio ^[2]; Gordon, Roy G. ^[1]

Harvard Univ., Cambridge, MA (United States)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Thin-film solar cells consisting of earth-abundant and non-toxic materials were created from pulsed chemical vapor deposition (pulsed-CVD) of SnS as the p-type absorber layer and atomic layer deposition (ALD) of Zn(O,S) as the n-type buffer layer. The effects of deposition temperature and annealing conditions of the SnS absorber layer were investigated for solar cells with a structure of Mo/SnS/Zn(O,S)/ZnO/ITO. Solar cells were further optimized by varying the stoichiometry of Zn(O,S) and the annealing conditions of SnS. Post-deposition annealing in pure hydrogen sulfide improved crystallinity and increased the carrier mobility by one order of magnitude, and a power conversion efficiency up to 2.9% was achieved.

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Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office; National Science Foundation (NSF)

Grant/Contract Number:: EE0005329

OSTI ID:: 1557830

Journal Information:: Progress in Photovoltaics, Vol. 23, Issue 7; ISSN 1062-7995

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 118 works

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References (30)

Thin film solar cell with 8.4% power conversion efficiency using an earth-abundant Cu ₂ ZnSnS ₄ absorber : Cu Shin, Byungha; Gunawan, Oki; Zhu, Yu Progress in Photovoltaics: Research and Applications, Vol. 21, Issue 1 https://doi.org/10.1002/pip.1174	journal	November 2011
Atomic layer deposition of Zn(O,S) thin films with tunable electrical properties by oxygen annealing Hejin Park, Helen; Heasley, Rachel; Gordon, Roy G. Applied Physics Letters, Vol. 102, Issue 13 https://doi.org/10.1063/1.4800928	journal	April 2013
Theoretical analysis of the effect of conduction band offset of window/CIS layers on performance of CIS solar cells using device simulation Minemoto, Takashi; Matsui, Takuya; Takakura, Hideyuki Solar Energy Materials and Solar Cells, Vol. 67, Issue 1-4 https://doi.org/10.1016/S0927-0248(00)00266-X	journal	March 2001
Sublimation study of the tin sulphides SnS2, Sn2S3 and SnS Piacente, V.; Foglia, S.; Scardala, P. Journal of Alloys and Compounds, Vol. 177, Issue 1 https://doi.org/10.1016/0925-8388(91)90053-X	journal	December 1991
Photovoltaic properties of SnS based solar cells Ramakrishna Reddy, K. T.; Koteswara Reddy, N.; Miles, R. W. Solar Energy Materials and Solar Cells, Vol. 90, Issue 18-19, p. 3041-3046 https://doi.org/10.1016/j.solmat.2006.06.012	journal	November 2006
SnS thin film solar cells with Zn1−xMgxO buffer layers Ikuno, Takashi; Suzuki, Ryo; Kitazumi, Kosuke Applied Physics Letters, Vol. 102, Issue 19 https://doi.org/10.1063/1.4804603	journal	May 2013
Growth characteristics, material properties, and optical properties of zinc oxysulfide films deposited by atomic layer deposition Bakke, Jonathan R.; Tanskanen, Jukka T.; Hägglund, Carl Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 30, Issue 1 https://doi.org/10.1116/1.3664758	journal	January 2012
Quasiparticle band structures and interface physics of SnS and GeS Malone, Brad D.; Kaxiras, Efthimios Physical Review B, Vol. 87, Issue 24 https://doi.org/10.1103/PhysRevB.87.245312	journal	June 2013
Structural and band alignment properties of Al ₂ O ₃ on epitaxial Ge grown on (100), (110), and (111)A GaAs substrates by molecular beam epitaxy Hudait, M. K.; Zhu, Y.; Maurya, D. Journal of Applied Physics, Vol. 113, Issue 13 https://doi.org/10.1063/1.4799367	journal	April 2013
Optical and electronic properties of post-annealed ZnO:Al thin films Kim, Yumin; Lee, Woojin; Jung, Dae-Ryong Applied Physics Letters, Vol. 96, Issue 17 https://doi.org/10.1063/1.3419859	journal	April 2010
Characterization of vacuum-evaporated tin sulfide film for solar cell materials Noguchi, Hidenori; Setiyadi, Agus; Tanamura, Hiromasa Solar Energy Materials and Solar Cells, Vol. 35, p. 325-331 https://doi.org/10.1016/0927-0248(94)90158-9	journal	September 1994
High-Efficiency Solar Cell with Earth-Abundant Liquid-Processed Absorber Todorov, Teodor K.; Reuter, Kathleen B.; Mitzi, David B. Advanced Materials, Vol. 22, Issue 20, p. E156-E159 https://doi.org/10.1002/adma.200904155	journal	May 2010
Enhancing the efficiency of SnS solar cells via band-offset engineering with a zinc oxysulfide buffer layer Sinsermsuksakul, Prasert; Hartman, Katy; Bok Kim, Sang Applied Physics Letters, Vol. 102, Issue 5 https://doi.org/10.1063/1.4789855	journal	February 2013
The role of ZnO-coating-layer thickness on the recombination in CdS quantum-dot-sensitized solar cells Choi, Hongsik; Kim, Jongmin; Nahm, Changwoo Nano Energy, Vol. 2, Issue 6 https://doi.org/10.1016/j.nanoen.2013.05.007	journal	November 2013
Tetrahedral Zinc Blende Tin Sulfide Nano- and Microcrystals Greyson, Eric C.; Barton, Jeremy E.; Odom, Teri W. Small, Vol. 2, Issue 3 https://doi.org/10.1002/smll.200500460	journal	March 2006
Zinc oxysulfide thin films grown by atomic layer deposition Sanders, B. W.; Kitai, A. Chemistry of Materials, Vol. 4, Issue 5 https://doi.org/10.1021/cm00023a015	journal	September 1992
Band-structure, optical properties, and defect physics of the photovoltaic semiconductor SnS Vidal, Julien; Lany, Stephan; d’Avezac, Mayeul Applied Physics Letters, Vol. 100, Issue 3 https://doi.org/10.1063/1.3675880	journal	January 2012
Optimization of photoconductivity in vacuum-evaporated tin sulfide thin films Johnson, J. B.; Jones, H.; Latham, B. S. Semiconductor Science and Technology, Vol. 14, Issue 6 https://doi.org/10.1088/0268-1242/14/6/303	journal	January 1999
The effect of a blocking layer on the photovoltaic performance in CdS quantum-dot-sensitized solar cells Kim, Jongmin; Choi, Hongsik; Nahm, Changwoo Journal of Power Sources, Vol. 196, Issue 23 https://doi.org/10.1016/j.jpowsour.2011.08.052	journal	December 2011
SnS thin-films by RF sputtering at room temperature Hartman, Katy; Johnson, J. L.; Bertoni, Mariana I. Thin Solid Films, Vol. 519, Issue 21, p. 7421-7424 https://doi.org/10.1016/j.tsf.2010.12.186	journal	August 2011
On the CdS/CuInSe ₂ conduction band discontinuity Niemegeers, Alex; Burgelman, Marc; De Vos, Alexis Applied Physics Letters, Vol. 67, Issue 6 https://doi.org/10.1063/1.115523	journal	August 1995
Recombination mechanisms in highly efficient thin film Zn(S,O)/Cu(In,Ga)S2 based solar cells Merdes, S.; Sáez-Araoz, R.; Ennaoui, A. Applied Physics Letters, Vol. 95, Issue 21 https://doi.org/10.1063/1.3266829	journal	November 2009
Strong Valence-Band Offset Bowing of ${ZnO}_{1 - x} S_{x}$ Enhances $p$ -Type Nitrogen Doping of ZnO-like Alloys Persson, Clas; Platzer-Björkman, Charlotte; Malmström, Jonas Physical Review Letters, Vol. 97, Issue 14 https://doi.org/10.1103/PhysRevLett.97.146403	journal	October 2006
Polymorphic Tin Sulfide Thin Films of Zinc Blende and Orthorhombic Structures by Chemical Deposition Avellaneda, David; Nair, M. T. S.; Nair, P. K. Journal of The Electrochemical Society, Vol. 155, Issue 7 https://doi.org/10.1149/1.2917198	journal	January 2008
Zn(O,S) buffer layers by atomic layer deposition in Cu(In,Ga)Se2 based thin film solar cells: Band alignment and sulfur gradient Platzer-Björkman, C.; Törndahl, T.; Abou-Ras, D. Journal of Applied Physics, Vol. 100, Issue 4 https://doi.org/10.1063/1.2222067	journal	August 2006
Band alignment of SnS/Zn(O,S) heterojunctions in SnS thin film solar cells Sun, Leizhi; Haight, Richard; Sinsermsuksakul, Prasert Applied Physics Letters, Vol. 103, Issue 18 https://doi.org/10.1063/1.4821433	journal	October 2013
Sputtered molybdenum bilayer back contact for copper indium diselenide-based polycrystalline thin-film solar cells Scofield, John H.; Duda, A.; Albin, D. Thin Solid Films, Vol. 260, Issue 1, p. 26-31 https://doi.org/10.1016/0040-6090(94)06462-8	journal	May 1995
First-Principles Study on Influences of Crystal Structure and Orientation on Band Offsets at the CdS/Cu ₂ ZnSnS ₄ Interface Bao, Wujisiguleng; Ichimura, Masaya International Journal of Photoenergy, Vol. 2012 https://doi.org/10.1155/2012/619812	journal	January 2012
Temperature-dependent structural and optical properties of SnS films Koteeswara Reddy, N.; Hahn, Y. B.; Devika, M. Journal of Applied Physics, Vol. 101, Issue 9 https://doi.org/10.1063/1.2729450	journal	May 2007
Low Temperature Atomic Layer Deposition of Tin Oxide Heo, Jaeyeong; Hock, Adam S.; Gordon, Roy G. Chemistry of Materials, Vol. 22, Issue 17 https://doi.org/10.1021/cm1011108	journal	September 2010

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Title: Co-optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells: SnS absorber and Zn(O,S) buffer materials for improved solar cells

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