Coaxial Carbon Nanotube Supported TiO2@MoO2@Carbon Core–Shell Anode for Ultrafast and High-Capacity Sodium Ion Storage

Ma, Chunrong; Li, Xiang; Deng, Changjian; Hu, Yan -Yan; Lee, Sungsik; Liao, Xiao -Zhen; He, Yu -Shi; Ma, Zi -Feng; Xiong, Hui

doi:10.1021/acsnano.8b07811

Title: Coaxial Carbon Nanotube Supported TiO₂@MoO₂@Carbon Core–Shell Anode for Ultrafast and High-Capacity Sodium Ion Storage

Journal Article · Fri Dec 28 00:00:00 EST 2018 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.8b07811· OSTI ID:1513760

Ma, Chunrong ^[1]; Li, Xiang ^[2]; Deng, Changjian ^[3];

^[2]; Lee, Sungsik ^[4]; Liao, Xiao -Zhen ^[5]; He, Yu -Shi ^[5]; Ma, Zi -Feng ^[6];

^[3]

Shanghai Jiao Tong Univ., Shanghai (China); Boise State Univ., Boise, ID (United States)
Florida State Univ., Tallahassee, FL (United States)
Boise State Univ., Boise, ID (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Shanghai Jiao Tong Univ., Shanghai (China)
Shanghai Jiao Tong Univ., Shanghai (China); Zhejiang Natrium Energy Inc., Shaoxing (China)

The sluggish kinetic in electrode materials is one of the critical challenges in achieving high-power sodium ion storage. We report a coaxial core-shell nanostructure composed of carbon nanotube (CNT) as the core and TiO₂@MoO₂@C as shells for a hierarchically nanoarchitectured anode for improved electrode kinetics. The 1D tubular nanostructure can effectively reduce ion diffusion path, increase electrical conductivity, accommodate the stress due to volume change upon cycling, and provide additional interfacial active sites for enhanced charge storage and transport properties. Significantly, a synergistic effect between TiO₂ and MoO₂ nanostructures is investigated through ex-situ solid state nuclear magnetic resonance. Furthermore, the electrode exhibits a good rate capability (150 mAh g^–1 at 20 A g^–1) and superior cycling stability with a reversibly capacity of 175 mAh g^–1 at 10 A g^–1 for over 8000 cycles.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Basic Research Program of China; National Science Foundation (NSF); National Natural Science Foundation of China (NSFC); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1513760

Journal Information:: ACS Nano, Vol. 13, Issue 1; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 30 works

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Title: Coaxial Carbon Nanotube Supported TiO2@MoO2@Carbon Core–Shell Anode for Ultrafast and High-Capacity Sodium Ion Storage

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