A highly scalable spray coating technique for electrode infiltration: Barium carbonate infiltrated La0.6Sr0.4Co0.2Fe0.8O3-δ perovskite structured electrocatalyst with demonstrated long term durability

Hong, Tao; Lee, Shiwoo; Ohodnicki, Paul; Brinkman, Kyle

doi:10.1016/j.ijhydene.2017.08.091

Title: A highly scalable spray coating technique for electrode infiltration: Barium carbonate infiltrated La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ perovskite structured electrocatalyst with demonstrated long term durability

Journal Article · Fri Sep 08 00:00:00 EDT 2017 · International Journal of Hydrogen Energy

DOI:https://doi.org/10.1016/j.ijhydene.2017.08.091· OSTI ID:1482349

Hong, Tao ^[1]; Lee, Shiwoo ^[2]; Ohodnicki, Paul ^[3];

^[1]

Clemson Univ., SC (United States)
National Energy Technology Lab. (NETL), Morgantown, WV (United States); AECOM, Morgantown, WV (United States)
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Carnegie Mellon Univ., Pittsburgh, PA (United States)

Barium carbonate (BaCO₃) nanoparticles have demonstrated excellent catalytic activity for the oxygen reduction reaction by spray coating onto La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) and LSCF-SDC (Sm_0.2Ce_0.8O_2-δ) cathode materials. In this work, barium acetate solutions were modified by a surfactant to lower the surface tension and decrease the contact angle on LSCF which is a benefit for the infiltration process. In the LSCF electrode, BaCO₃ nano-particles exhibited significant interfacial contact with LSCF particles by the spray coating technique. As a result, the polarization resistance of BaCO₃ infiltrated LSCF was reduced from 2.5 to 1.2 Ωcm² at 700 °C. In addition, commercial full cell SOFCs with BaCO₃ infiltrated LSCF-SDC cathodes also demonstrated higher performance due to the reduced cathode resistance. At 750 °C, the electrode overpotential of the BaCO3 infiltrated cell was much lower than that of baseline cell during long term testing (500 hours). The polarization resistance of the BaCO₃ infiltrated LSCF-SDC electrode only increased by 1.6% after 500 hours. This work demonstrated a highly scalable spray coating process of a promising electrocatalyst (BaCO₃) with excellent long-term stability for the oxygen reduction reaction.

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Research Organization:: National Energy Technology Lab. (NETL), Morgantown, WV (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: 14-6357

OSTI ID:: 1482349

Alternate ID(s):: OSTI ID: 1549926

Journal Information:: International Journal of Hydrogen Energy, Vol. 42, Issue 39; ISSN 0360-3199

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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References (51)

Direct oxidation of hydrocarbons in a solid-oxide fuel cell Park, Seungdoo; Vohs, John M.; Gorte, Raymond J. Nature, Vol. 404, Issue 6775 https://doi.org/10.1038/35005040	journal	March 2000
A novel microbial fuel cell stack for continuous production of clean energy Rahimnejad, M.; Ghoreyshi, A. A.; Najafpour, G. D. International Journal of Hydrogen Energy, Vol. 37, Issue 7 https://doi.org/10.1016/j.ijhydene.2011.12.154	journal	April 2012
Methylene blue as electron promoters in microbial fuel cell Rahimnejad, M.; Najafpour, G. D.; Ghoreyshi, A. A. International Journal of Hydrogen Energy, Vol. 36, Issue 20 https://doi.org/10.1016/j.ijhydene.2011.07.059	journal	October 2011
Visible light photocatalytic water splitting for hydrogen production from N-TiO2 rice grain shaped electrospun nanostructures Babu, Veluru Jagadeesh; Kumar, Manippady K.; Nair, Appukuttan Sreekumaran International Journal of Hydrogen Energy, Vol. 37, Issue 10 https://doi.org/10.1016/j.ijhydene.2011.12.015	journal	May 2012
Enhanced Oxygen Reduction Activity and Solid Oxide Fuel Cell Performance with a Nanoparticles-Loaded Cathode Zhang, Xiaomin; Liu, Li; Zhao, Zhe Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/nl5043566	journal	February 2015
Tailoring gadolinium-doped ceria-based solid oxide fuel cells to achieve 2 W cm−2 at 550 °C Lee, Jin Goo; Park, Jeong Ho; Shul, Yong Gun Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5045	journal	June 2014
Progress and perspectives in micro direct methanol fuel cell Sundarrajan, Subramanian; Allakhverdiev, Suleyman I.; Ramakrishna, Seeram International Journal of Hydrogen Energy, Vol. 37, Issue 10 https://doi.org/10.1016/j.ijhydene.2011.12.017	journal	May 2012
Three-Dimensional Nanostructured Bilayer Solid Oxide Fuel Cell with 1.3 W/cm ² at 450 °C An, Jihwan; Kim, Young-Beom; Park, Joonsuk Nano Letters, Vol. 13, Issue 9 https://doi.org/10.1021/nl402661p	journal	August 2013
Pd-YSZ composite cathodes for oxygen reduction reaction of intermediate-temperature solid oxide fuel cells Liang, Fengli; Zhou, Wei; Chi, Bo International Journal of Hydrogen Energy, Vol. 36, Issue 13 https://doi.org/10.1016/j.ijhydene.2011.03.132	journal	July 2011
Enhanced Oxygen Reduction Activity on Ruddlesden–Popper Phase Decorated La _0.8 Sr _0.2 FeO _3−δ 3D Heterostructured Cathode for Solid Oxide Fuel Cells Hong, Tao; Zhao, Mingyang; Brinkman, Kyle ACS Applied Materials & Interfaces, Vol. 9, Issue 10 https://doi.org/10.1021/acsami.6b14625	journal	March 2017
Efficient Electro-Catalysts for Enhancing Surface Activity and Stability of SOFC Cathodes Ding, Dong; Liu, Mingfei; Liu, Zhangbo Advanced Energy Materials, Vol. 3, Issue 9 https://doi.org/10.1002/aenm.201200984	journal	May 2013
Enhancing SOFC cathode performance by surface modification through infiltration Ding, Dong; Li, Xiaxi; Lai, Samson Yuxiu Energy & Environmental Science, Vol. 7, Issue 2 https://doi.org/10.1039/c3ee42926a	journal	January 2014
Nanoscale and nano-structured electrodes of solid oxide fuel cells by infiltration: Advances and challenges Jiang, San Ping International Journal of Hydrogen Energy, Vol. 37, Issue 1 https://doi.org/10.1016/j.ijhydene.2011.09.067	journal	January 2012
Nano-structured composite cathodes for intermediate-temperature solid oxide fuel cells via an infiltration/impregnation technique Jiang, Zhiyi; Xia, Changrong; Chen, Fanglin Electrochimica Acta, Vol. 55, Issue 11 https://doi.org/10.1016/j.electacta.2010.02.019	journal	April 2010
High-Performance composite cathodes for solid oxide fuel cells Park, Young Min; Kim, Ju Hee; Kim, Haekyoung International Journal of Hydrogen Energy, Vol. 36, Issue 15 https://doi.org/10.1016/j.ijhydene.2011.04.075	journal	July 2011
Electrochemical characteristics of solid oxide fuel cell cathodes prepared by infiltrating (La,Sr)MnO3 nanoparticles into yttria-stabilized bismuth oxide backbones Jiang, Zhiyi; Lei, Zhiwei; Ding, Bo International Journal of Hydrogen Energy, Vol. 35, Issue 15 https://doi.org/10.1016/j.ijhydene.2009.12.008	journal	August 2010
Technological development of hydrogen production by solid oxide electrolyzer cell (SOEC) Ni, M.; Leung, M.; Leung, D. International Journal of Hydrogen Energy, Vol. 33, Issue 9 https://doi.org/10.1016/j.ijhydene.2008.02.048	journal	May 2008
Characterization of infiltrated (La0.75Sr0.25)0.95MnO3 as oxygen electrode for solid oxide electrolysis cells Yang, Chenghao; Jin, Chao; Coffin, Adam International Journal of Hydrogen Energy, Vol. 35, Issue 11 https://doi.org/10.1016/j.ijhydene.2010.03.049	journal	June 2010
Synthesis of supported catalysts by impregnation and drying using aqueous chelated metal complexes van Dillen, A. Jos; Terörde, Robert J. A. M.; Lensveld, Dennis J. Journal of Catalysis, Vol. 216, Issue 1-2 https://doi.org/10.1016/S0021-9517(02)00130-6	journal	May 2003
Eggshell catalysts for Fischer–Tropsch synthesis Galarraga, C.; Peluso, E.; de Lasa, H. Chemical Engineering Journal, Vol. 82, Issue 1-3 https://doi.org/10.1016/S1385-8947(00)00352-1	journal	March 2001
Electrochemical performance of (La,Sr)(Co,Fe)O3–(Ce,Gd)O3 composite cathodes Perry Murray, E. Solid State Ionics, Vol. 148, Issue 1-2 https://doi.org/10.1016/S0167-2738(02)00102-9	journal	May 2002
Ferrite-based perovskites as cathode materials for anode-supported solid oxide fuel cells Mai, Andreas; Haanappel, Vincent A. C.; Uhlenbruck, Sven Solid State Ionics, Vol. 176, Issue 15-16 https://doi.org/10.1016/j.ssi.2005.03.009	journal	May 2005
The effect of thermal treatment on the resistance of LSCF electrodes on gadolinia doped ceria electrolytes Waller, D. Solid State Ionics, Vol. 86-88 https://doi.org/10.1016/0167-2738(96)00362-1	journal	July 1996
Palladium and ceria infiltrated La0.8Sr0.2Co0.5Fe0.5O3−δ cathodes of solid oxide fuel cells Chen, Jing; Liang, Fengli; Chi, Bo Journal of Power Sources, Vol. 194, Issue 1 https://doi.org/10.1016/j.jpowsour.2009.04.041	journal	October 2009
Enhancement of La0.6Sr0.4Co0.2Fe0.8O3-δ durability and surface electrocatalytic activity by La0.85Sr0.15MnO3±δ investigated using a new test electrode platform Lynch, Matthew E.; Yang, Lei; Qin, Wentao Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01188j	journal	January 2011
Barium carbonate nanoparticle to enhance oxygen reduction activity of strontium doped lanthanum ferrite for solid oxide fuel cell Hong, Tao; Chen, Fanglin; Xia, Changrong Journal of Power Sources, Vol. 278 https://doi.org/10.1016/j.jpowsour.2014.12.137	journal	March 2015
Barium Carbonate Nanoparticles as Synergistic Catalysts for the Oxygen Reduction Reaction on La_0.6Sr_0.4Co_0.2Fe_0.8O_3−δ Solid-Oxide Fuel Cell Cathodes Hong, Tao; Brinkman, Kyle S.; Xia, Changrong ChemElectroChem, Vol. 3, Issue 5, p. 805-813 https://doi.org/10.1002/celc.201500529	journal	February 2016
Barium carbonate nanoparticle as high temperature oxygen reduction catalyst for solid oxide fuel cell Hong, Tao; Chen, Fanglin; Xia, Changrong Electrochemistry Communications, Vol. 51, p. 93-97 https://doi.org/10.1016/j.elecom.2014.12.017	journal	February 2015
Mechanism for the enhanced oxygen reduction reaction of La _0.6 Sr _0.4 Co _0.2 Fe _0.8 O _3−δ by strontium carbonate Li, Mei; Sun, Zhongti; Yang, Wenqiang Physical Chemistry Chemical Physics, Vol. 19, Issue 1 https://doi.org/10.1039/C6CP06204K	journal	January 2017
Dopants to enhance SOFC cathodes based on Sr-doped LaFeO3 and LaMnO3 Bidrawn, F.; Kim, G.; Aramrueang, N. Journal of Power Sources, Vol. 195, Issue 3 https://doi.org/10.1016/j.jpowsour.2009.08.034	journal	February 2010
Improving electrochemical performance of lanthanum strontium ferrite by decorating instead of doping cobaltite Li, Mei; Zheng, Minghao; Hu, Bobing Electrochimica Acta, Vol. 230 https://doi.org/10.1016/j.electacta.2017.02.014	journal	March 2017
Thin film SOFCs with cobalt-infiltrated cathodes Yamahara, K.; Jacobson, C.; Visco, S. Solid State Ionics, Vol. 176, Issue 3-4 https://doi.org/10.1016/j.ssi.2004.08.017	journal	January 2005
Reversible Decomposition of Secondary Phases in BaO Infiltrated LSM Electrodes-Polarization Effects Traulsen, Marie L.; McIntyre, Melissa D.; Norrman, Kion Advanced Materials Interfaces, Vol. 3, Issue 24 https://doi.org/10.1002/admi.201600750	journal	November 2016
Degradation of La0.6Sr0.4CoO3-based cathode performance in solid oxide fuel cells due to the presence of aluminum oxide deposited through atomic layer deposition Kim, Eui-Hyun; Jung, Hyo-Jun; An, Ki-Seok Ceramics International, Vol. 40, Issue 6 https://doi.org/10.1016/j.ceramint.2013.12.125	journal	July 2014
Vacuum-assisted electroless copper plating on Ni/(Sm,Ce)O2 anodes for intermediate temperature solid oxide fuel cells Ai, Na; Chen, Kongfa; Jiang, San Ping International Journal of Hydrogen Energy, Vol. 36, Issue 13 https://doi.org/10.1016/j.ijhydene.2011.03.131	journal	July 2011
Preparation of SOFC Anodes by Electrodeposition Jung, S. -W.; Vohs, J. M.; Gorte, R. J. Journal of The Electrochemical Society, Vol. 154, Issue 12 https://doi.org/10.1149/1.2790280	journal	January 2007
Engineering the solid oxide fuel cell electrocatalyst infiltration technique for industrial use Dowd, Regis P.; Lee, Shiwoo; Fan, Yueying International Journal of Hydrogen Energy, Vol. 41, Issue 33 https://doi.org/10.1016/j.ijhydene.2016.06.015	journal	September 2016
LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P. Journal of The Electrochemical Society, Vol. 153, Issue 6, p. A1115-A1119 https://doi.org/10.1149/1.2192733	journal	January 2006
LSM-Infiltrated Solid Oxide Fuel Cell Cathodes Sholklapper, Tal Z.; Lu, Chun; Jacobson, Craig P. Electrochemical and Solid-State Letters, Vol. 9, Issue 8 https://doi.org/10.1149/1.2206011	journal	January 2006
Enhancement in Three-Phase Boundary of SOFC Electrodes by an Ion Impregnation Method: A Modeling Comparison Zhu, Wei; Ding, Dong; Xia, Changrong Electrochemical and Solid-State Letters, Vol. 11, Issue 6, p. B83-B86 https://doi.org/10.1149/1.2895009	journal	January 2008
Finite-Element Modeling of Idealized Infiltrated Composite Solid Oxide Fuel Cell Cathodes Nicholas, Jason D.; Barnett, Scott A. Journal of The Electrochemical Society, Vol. 156, Issue 4 https://doi.org/10.1149/1.3076133	journal	January 2009
Prediction of infiltrated solid oxide fuel cell cathode polarization resistance Shah, Megna; Nicholas, Jason D.; Barnett, Scott A. Electrochemistry Communications, Vol. 11, Issue 1 https://doi.org/10.1016/j.elecom.2008.10.006	journal	January 2009
Modeling Impedance Response of SOFC Cathodes Prepared by Infiltration Bidrawn, F.; Küngas, R.; Vohs, J. M. Journal of The Electrochemical Society, Vol. 158, Issue 5 https://doi.org/10.1149/1.3565174	journal	January 2011
A durability model for solid oxide fuel cell electrodes in thermal cycle processes Zhang, Yanxiang; Xia, Changrong Journal of Power Sources, Vol. 195, Issue 19 https://doi.org/10.1016/j.jpowsour.2010.04.051	journal	October 2010
La0.6Sr0.4Co0.2Fe0.8O3−δ cathodes infiltrated with samarium-doped cerium oxide for solid oxide fuel cells Nie, Lifang; Liu, Mingfei; Zhang, Yujun Journal of Power Sources, Vol. 195, Issue 15 https://doi.org/10.1016/j.jpowsour.2010.02.049	journal	August 2010
Pd-promoted La0.6Sr0.4Co0.2Fe0.8O3 cathodes Sahibzada, M. Solid State Ionics, Vol. 113-115, Issue 1-2 https://doi.org/10.1016/S0167-2738(98)00294-X	journal	December 1998
Geometric Properties of Nanostructured Solid Oxide Fuel Cell Electrodes Zhang, Yanxiang; Sun, Qiong; Xia, Changrong Journal of The Electrochemical Society, Vol. 160, Issue 3 https://doi.org/10.1149/2.057303jes	journal	January 2013
Microstructural Insights into Dual-Phase Infiltrated Solid Oxide Fuel Cell Electrodes Zhang, Yanxiang; Ni, Meng; Xia, Changrong Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.092308jes	journal	January 2013
Time-Dependent Electrode Performance Changes in Intermediate Temperature Solid Oxide Fuel Cells Endler, C.; Leonide, A.; Weber, A. Journal of The Electrochemical Society, Vol. 157, Issue 2 https://doi.org/10.1149/1.3270047	journal	January 2010
Long-Term Stability of SOFC Composite Cathode Activated by Electrocatalyst Infiltration Lee, Shiwoo; Miller, Nicholas; Gerdes, Kirk Journal of The Electrochemical Society, Vol. 159, Issue 7 https://doi.org/10.1149/2.067207jes	journal	January 2012
A perspective on low-temperature solid oxide fuel cells Gao, Zhan; Mogni, Liliana V.; Miller, Elizabeth C. Energy & Environmental Science, Vol. 9, Issue 5 https://doi.org/10.1039/C5EE03858H	journal	January 2016

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Title: A highly scalable spray coating technique for electrode infiltration: Barium carbonate infiltrated La0.6Sr0.4Co0.2Fe0.8O3-δ perovskite structured electrocatalyst with demonstrated long term durability

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Title: A highly scalable spray coating technique for electrode infiltration: Barium carbonate infiltrated La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ perovskite structured electrocatalyst with demonstrated long term durability