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Title: A flexible thioether-based MOF as a crystalline sponge for structural characterization of liquid organic molecules

Journal Article · · Materials Chemistry Frontiers
DOI:https://doi.org/10.1039/c7qm00152e· OSTI ID:1469991
 [1];  [1];  [1]; ORCiD logo [1];  [2]; ORCiD logo [3]
  1. Department of Chemistry; Texas A&M University; College Station; USA
  2. Chemistry Department; College of Science; King Saud University; Riyadh 11451; Saudi Arabia
  3. Department of Chemistry; Texas A&M University; College Station; USA; Chemistry Department
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Herein, we present a flexible MOF (PCN-41) composed of a thioether-based linker. By the virtue of the low symmetry, structural flexibility, and the electron-rich cavity environment, PCN-41 exhibits crystalline sponge behavior toward a series of electron-deficient liquid molecules.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
DOE Contract Number:
SC0001015
OSTI ID:
1469991
Journal Information:
Materials Chemistry Frontiers, Vol. 1, Issue 9; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 2052-1537
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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Where is the Oxygen? Structural Analysis of α-Humulene Oxidation Products by the Crystalline Sponge Method journal June 2015
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Structural Reevaluation of the Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation Supported by the Crystalline Sponge Method for X-ray Analysis journal February 2014
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A saccharide-based crystalline sponge for hydrophilic guests journal January 2016
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Sponge-like molecular cage for purification of fullerenes journal November 2014
Preparation and guest-uptake protocol for a porous complex useful for 'crystal-free' crystallography journal January 2014
Thermodynamically Guided Synthesis of Mixed-Linker Zr-MOFs with Enhanced Tunability journal May 2016
In Situ Observation of Thiol Michael Addition to a Reversible Covalent Drug in a Crystalline Sponge journal March 2016
Networked molecular cages as crystalline sponges for fullerenes and other guests journal July 2010

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Related Subjects

membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)