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Title: Ionic Liquid Gating Control of Spin Reorientation Transition and Switching of Perpendicular Magnetic Anisotropy

Journal Article · · Advanced Materials
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [1];  [3];  [4];  [2];  [2];  [1]
  1. Xi'an Jiaotong Univ., Xi'an (China)
  2. Tsinghua Univ., Beijing (China)
  3. Xi'an Jiaotong Univ., Xi'an (China); Simon Fraser Univ., Burnaby, BC (Canada)
  4. Argonne National Lab. (ANL), Lemont, IL (United States); The Univ. of Chicago, Chicago, IL (United States)

Abstract Electric field (E‐field) modulation of perpendicular magnetic anisotropy (PMA) switching, in an energy‐efficient manner, is of great potential to realize magnetoelectric (ME) memories and other ME devices. Voltage control of the spin‐reorientation transition (SRT) that allows the magnetic moment rotating between the out‐of‐plane and the in‐plane direction is thereby crucial. In this work, a remarkable magnetic anisotropy field change up to 1572 Oe is achieved under a small operation voltage of 4 V through ionic liquid (IL) gating control of SRT in Au/[DEME] + [TFSI] /Pt/(Co/Pt) 2 /Ta capacitor heterostructures at room temperature, corresponding to a large ME coefficient of 378 Oe V −1 . As revealed by both ferromagnetic resonance measurements and magnetic domain evolution observation, the magnetization can be switched stably and reversibly between the out‐of‐plane and in‐plane directions via IL gating. The key mechanism, revealed by the first‐principles calculation, is that the IL gating process influences the interfacial spin–orbital coupling as well as net Rashba magnetic field between the Co and Pt layers, resulting in the modulation of the SRT and in‐plane/out‐of‐plane magnetization switching. This work demonstrates a unique IL‐gated PMA with large ME tunability and paves a way toward IL gating spintronic/electronic devices such as voltage tunable PMA memories.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC); Natural Science and Engineering Research Council of Canada; USDOE
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1467107
Alternate ID(s):
OSTI ID: 1439400
Journal Information:
Advanced Materials, Vol. 30, Issue 30; ISSN 0935-9648
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 43 works
Citation information provided by
Web of Science

References (36)

X-Ray Absorption Near Edge Structure in Metals: Relativistic Effects and Core-Hole Screening journal June 1995
Probing electric field control of magnetism using ferromagnetic resonance journal January 2015
Giant Electric Field Tuning of Magnetism in Novel Multiferroic FeGaB/Lead Zinc Niobate-Lead Titanate (PZN-PT) Heterostructures journal August 2009
Multiferroic Heterostructures Integrating Ferroelectric and Magnetic Materials journal November 2015
Quantitative Determination on Ionic-Liquid-Gating Control of Interfacial Magnetism journal March 2017
Electrostatic versus Electrochemical Doping and Control of Ferromagnetism in Ion-Gel-Gated Ultrathin La 0.5 Sr 0.5 CoO 3−δ journal July 2016
Ionic-liquid gating of perpendicularly magnetised CoFeB/MgO thin films journal July 2016
E-Field Control of Exchange Bias and Deterministic Magnetization Switching in AFM/FM/FE Multiferroic Heterostructures journal May 2011
Large voltage-induced magnetic anisotropy change in a few atomic layers of iron journal January 2009
Reversible Control of Co Magnetism by Voltage-Induced Oxidation journal December 2014
Formation of a Stable pn Junction in a Liquid-Gated MoS 2 Ambipolar Transistor journal June 2013
Voltage Tuning of Ferromagnetic Resonance with Bistable Magnetization Switching in Energy-Efficient Magnetoelectric Composites journal January 2013
Strong Electrical Manipulation of Spin-Orbit Torque in Ferromagnetic Heterostructures journal September 2016
Electrical Manipulation of Orbital Occupancy and Magnetic Anisotropy in Manganites journal December 2014
Electric-field control of ferromagnetism journal December 2000
Electric Field-Induced Modification of Magnetism in Thin-Film Ferromagnets journal January 2007
Superconducting Dome in a Gate-Tuned Band Insulator journal November 2012
Voltage-Impulse-Induced Non-Volatile Ferroelastic Switching of Ferromagnetic Resonance for Reconfigurable Magnetoelectric Microwave Devices journal July 2013
Magneto-ionic control of interfacial magnetism journal November 2014
The Rashba-effect at metallic surfaces journal September 2006
Electric-field-control of magnetic anisotropy of Co 0.6 Fe 0.2 B 0.2 /oxide stacks using reduced voltage journal August 2012
Electrically Induced Ferromagnetism at Room Temperature in Cobalt-Doped Titanium Dioxide journal May 2011
Electrical control of Curie temperature in cobalt using an ionic liquid film journal March 2012
Metal-Insulator Transition Induced by Oxygen Vacancies from Electrochemical Reaction in Ionic Liquid-Gated Manganite Films journal September 2015
Reversible Ferromagnetic Phase Transition in Electrode-Gated Manganites journal September 2014
Perpendicular Magnetic Anisotropy Caused by Interfacial Hybridization via Enhanced Orbital Moment in Co / Pt Multilayers: Magnetic Circular X-Ray Dichroism Study journal December 1998
Electrochemical properties of novel ionic liquids for electric double layer capacitor applications journal September 2004
Giant Electric Field Tuning of Magnetic Properties in Multiferroic Ferrite/Ferroelectric Heterostructures journal June 2009
Deterministic Switching of Perpendicular Magnetic Anisotropy by Voltage Control of Spin Reorientation Transition in (Co/Pt) 3 /Pb(Mg 1/3 Nb 2/3 )O 3 –PbTiO 3 Multiferroic Heterostructures journal April 2017
Electric-double-layer field-effect transistors with ionic liquids journal January 2013
Electric double-layer transistors: a review of recent progress journal June 2015
Magnetoelectric Charge Trap Memory journal February 2012
Detection of Rashba field using a rotational applied field journal April 2011
Electrical control of the ferromagnetic phase transition in cobalt at room temperature journal October 2011
Electric-field control of tri-state phase transformation with a selective dual-ion switch journal May 2017
Magnetoelectric Coupling in Well-Ordered Epitaxial BiFeO 3 /CoFe 2 O 4 /SrRuO 3 Heterostructured Nanodot Array journal December 2015

Cited By (8)

Sunlight Control of Interfacial Magnetism for Solar Driven Spintronic Applications journal October 2019
Voltage Control of Perpendicular Exchange Bias in Multiferroic Heterostructures journal May 2019
Room‐Temperature Reversible and Nonvolatile Tunability of Electrical Properties of Cr‐Doped In 2 O 3 Semiconductor Thin Films Gated by Ferroelectric Single Crystal and Ionic Liquid journal May 2019
Ionic Liquid Gating Control of Spin Wave Resonance in La 0.7 Sr 0.3 MnO 3 Thin Film journal November 2019
Low voltage induced reversible magnetoelectric coupling in Fe 3 O 4 thin films for voltage tunable spintronic devices journal January 2018
Tunable magnetic ground states of iron monolayer on nonmagnetic metallic substrates by small in-plane strains journal January 2019
Dynamic study of phase transition in Bi 2 O 3 epitaxial film induced by electrolyte gating journal December 2019
Simultaneous Optical and Electrical Spin-Torque Magnetometry with Phase-Sensitive Detection of Spin Precession journal March 2019

Figures / Tables (16)