Modification of the surface cellulose fibres in autoclaved cellulose cement-quartz composites
- Univ. of Technology, Sydney, NSW (Australia). Dept. Materials Science
- Australian Nuclear Science and Technology Organization, Menai, NSW (Australia)
The interfacial bond between fiber and matrix is one of the most important factors influencing fiber-reinforced composites. This is particularly apparent in cellulose wood pulp reinforced cement/quartz composites cured by autoclaving under saturated steam at 180 C. Scanning electron microscopy (SEM) studies have shown that there is little modification of the surface of the hydrated calcium silicate matrix immediately adjacent to the cellulose fiber surface, provided the cellulose fiber is relatively free from lignin, hemicelluloses, or chemicals from the pulping process. Coutts & Campbell (1979) in their investigation of water cured cement composites, applied several commercial coupling agents to cellulose fibres and established that two of these agents significantly increased the strength of the interfacial bond. In this paper, the surface of cellulose fibres was modified by sodium silicate, CTBN [carboxy terminated butadiene nitrile] and ATBN [amino terminated butadiene nitrile] in order to enhance the interfacial bond, and also to increase the resistance of the cellulose to oxidation, alkaline or thermal degradation, and algal attack. Algal attack can occur as the calcium silicate matrix is neutralized by atmospheric carbonation, especially in external wall board applications of the sheet composite. In addition, suitable coatings will protect the cellulose fiber from degradation arising from the presence of elevated temperature and alkaline solutions during the autoclaving process. Cellulose reinforced composites with substandard strengths, due to inhibited autoclave reactions, cannot be reautoclaved as the resultant material is too brittle due, in part, to the degradation of the cellulose fiber.
- OSTI ID:
- 143718
- Report Number(s):
- CONF-930246-; ISBN 0-87339-251-5; TRN: IM9413%%228
- Resource Relation:
- Conference: Advanced composites `93: international conference on advanced composite materials (ICACM), Wollongong (Australia), 15-19 Feb 1993; Other Information: PBD: 1993; Related Information: Is Part Of Advanced composites 1993; Chandra, T. [ed.] [Univ. of Wollongong (Australia)]; Dhingra, A.K. [ed.] [DuPont, Wilmington, DE (United States)]; PB: 1464 p.
- Country of Publication:
- United States
- Language:
- English
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