Analysis of tars produced in biomass gasification
- Univ. of Hawaii, Honolulu, HI (United States)
Parametric tests on tar formation, varying temperature, equivalence ratio, and residence time, are performed on a bench-scale, indirectly-heated fluidized bed gasifier. Prepared tar samples are analyzed in a gas chromatograph (GC) with a flame ionization detector, using a capillary column. Standards containing dominant tar species have been prepared for GC calibration. The identified peaks include single-ring hydrocarbons, such as benzene, to five-ring hydrocarbons, such as perylene; depending on the gasification conditions, the identified species represent about 70 to 90% (mass basis) of the tar constituents. Under all conditions tested, benzene and naphthalene were the most dominant species. Temperature and equivalence ratio have significant effect on tar yield and tar composition. Tar yield decreases with increasing temperature or equivalence ratio. The test results suggest that lower temperature favors the formation of more aromatic tar species with diversified substituent groups, while higher temperature favors the formation of fewer aromatic tar species without substituent groups. Higher temperature or equivalence ratio favors the formation of polyaromatic compounds. Oxygen-containing compounds exist in significant quantities only at temperature below 800{degrees}C and decrease with increasing temperature, equivalence ratio, or residence time.
- Research Organization:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- OSTI ID:
- 140331
- Report Number(s):
- NREL/CP-200-5768-Vol.1; CONF-9308106-Vol.1; ON: DE93010050; TRN: 93:003926-0062
- Resource Relation:
- Conference: 1. biomass conference of the Americas: energy, environment, agriculture, and industry, Burlington, VT (United States), 30 Aug - 2 Sep 1993; Other Information: PBD: [1993]; Related Information: Is Part Of First Biomass Conference of the Americas: Energy, environment, agriculture, and industry; Proceedings, Volume 1; PB: 796 p.
- Country of Publication:
- United States
- Language:
- English
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