Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability

Zhao, Jie; Liao, Lei; Shi, Feifei; Lei, Ting; Chen, Guangxu; Pei, Allen; Sun, Jie; Yan, Kai; Zhou, Guangmin; Xie, Jin; Liu, Chong; Li, Yuzhang; Liang, Zheng; Bao, Zhenan; Cui, Yi

doi:10.1021/jacs.7b05251

Title: Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability

Journal Article · Wed Jul 26 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b05251· OSTI ID:1394068

^[1]; Liao, Lei ^[1];

^[1];

^[1]; Chen, Guangxu ^[1];

^[1]; Sun, Jie ^[1]; Yan, Kai ^[1]; Zhou, Guangmin ^[1];

^[1]; Liu, Chong ^[1];

^[1]; Liang, Zheng ^[1];

^[1]; Cui, Yi ^[2]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Significant increases in the energy density of batteries must be achieved by exploring new materials and cell configurations. Lithium metal and lithiated silicon are two promising high-capacity anode materials. Unfortunately, both of these anodes require a reliable passivating layer to survive the serious environmental corrosion during handling and cycling. Here we developed a surface fluorination process to form a homogeneous and dense LiF coating on reactive anode materials, with in situ generated fluorine gas, by using a fluoropolymer, CYTOP, as the precursor. The process is effectively a “reaction in the beaker”, avoiding direct handling of highly toxic fluorine gas. For lithium metal, this LiF coating serves as a chemically stable and mechanically strong interphase, which minimizes the corrosion reaction with carbonate electrolytes and suppresses dendrite formation, enabling dendrite-free and stable cycling over 300 cycles with current densities up to 5 mA/cm². Lithiated silicon can serve as either a pre-lithiation additive for existing lithium-ion batteries or a replacement for lithium metal in Li–O₂ and Li–S batteries. However, lithiated silicon reacts vigorously with the standard slurry solvent N-methyl-2-pyrrolidinone (NMP), indicating it is not compatible with the real battery fabrication process. With the protection of crystalline and dense LiF coating, Li_xSi can be processed in anhydrous NMP with a high capacity of 2504 mAh/g. With low solubility of LiF in water, this protection layer also allows Li_xSi to be stable in humid air (~40% relative humidity). Furthermore, this facile surface fluorination process brings huge benefit to both the existing lithium-ion batteries and next-generation lithium metal batteries.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1394068

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 33; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 305 works

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