Frequency-domain coherent multidimensional spectroscopy when dephasing rivals pulsewidth: Disentangling material and instrument response

Kohler, Daniel D.; Thompson, Blaise J.; Wright, John C.

doi:10.1063/1.4986069

Title: Frequency-domain coherent multidimensional spectroscopy when dephasing rivals pulsewidth: Disentangling material and instrument response

Journal Article · Thu Aug 31 00:00:00 EDT 2017 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4986069· OSTI ID:1393442

^[1];

^[1]; Wright, John C. ^[1]

Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry

Ultrafast spectroscopy is often collected in the mixed frequency/time domain, where pulse durations are similar to system dephasing times. In these experiments, expectations derived from the familiar driven and impulsive limits are not valid. This work simulates the mixed-domain four-wave mixing response of a model system to develop expectations for this more complex field-matter interaction. We also explore frequency and delay axes. We show that these line shapes are exquisitely sensitive to excitation pulse widths and delays. Near pulse overlap, the excitation pulses induce correlations that resemble signatures of dynamic inhomogeneity. We describe these line shapes using an intuitive picture that connects to familiar field-matter expressions. We develop strategies for distinguishing pulse-induced correlations from true system inhomogeneity. Our simulations provide a foundation for interpretation of ultrafast experiments in the mixed domain.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0002162; FG02-09ER46664

OSTI ID:: 1393442

Alternate ID(s):: OSTI ID: 1377970

Journal Information:: Journal of Chemical Physics, Vol. 147, Issue 8; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 7 works

Citation information provided by
Web of Science

References (70)

The two-dimensional IR nonlinear spectroscopy of a cyclic penta-peptide in relation to its three-dimensional structure Hamm, P.; Lim, M.; DeGrado, W. F. Proceedings of the National Academy of Sciences, Vol. 96, Issue 5 https://doi.org/10.1073/pnas.96.5.2036	journal	March 1999
The grating decomposition method: A new approach for understanding polarization‐selective transient grating experiments. II. Applications Fourkas, John T.; Trebino, Rick; Fayer, M. D. The Journal of Chemical Physics, Vol. 97, Issue 1 https://doi.org/10.1063/1.463525	journal	July 1992
Infrared Photon Echo Experiments: Exploring Vibrational Dynamics in Liquids and Glasses Tokmakoff, A.; Fayer, M. D. Accounts of Chemical Research, Vol. 28, Issue 11 https://doi.org/10.1021/ar00059a001	journal	November 1995
Dynamics of spectral hole burning Brito Cruz, C. H.; Gordon, J. P.; Becker, P. C. IEEE Journal of Quantum Electronics, Vol. 24, Issue 2 https://doi.org/10.1109/3.122	journal	February 1988
Spectral Simplification in Vibrational Spectroscopy Using Doubly Vibrationally Enhanced Infrared Four Wave Mixing Zhao, Wei; Wright, John C. Journal of the American Chemical Society, Vol. 121, Issue 47 https://doi.org/10.1021/ja9926414	journal	December 1999
The grating decomposition method: A new approach for understanding polarization‐selective transient grating experiments. I. Theory Fourkas, John T.; Trebino, Rick; Fayer, M. D. The Journal of Chemical Physics, Vol. 97, Issue 1 https://doi.org/10.1063/1.463565	journal	July 1992
Picosecond coherence coupling in the pump and probe technique Vardeny, Z.; Tauc, J. Optics Communications, Vol. 39, Issue 6 https://doi.org/10.1016/0030-4018(81)90231-5	journal	November 1981
Mixed Frequency-/Time-Domain Coherent Multidimensional Spectroscopy: Research Tool or Potential Analytical Method? Pakoulev, Andrei V.; Rickard, Mark A.; Kornau, Kathryn M. Accounts of Chemical Research, Vol. 42, Issue 9 https://doi.org/10.1021/ar900032g	journal	September 2009
On the nature of “coherent artifact” Lebedev, M. V.; Misochko, O. V.; Dekorsy, T. Journal of Experimental and Theoretical Physics, Vol. 100, Issue 2 https://doi.org/10.1134/1.1884668	journal	February 2005
Spectral Quantum Beating in Mixed Frequency/Time-Domain Coherent Multidimensional Spectroscopy Pakoulev, Andrei V.; Rickard, Mark A.; Mathew, Nathan A. The Journal of Physical Chemistry A, Vol. 111, Issue 30 https://doi.org/10.1021/jp071929+	journal	July 2007
Ultrafast Dynamics within the 1S Exciton Band of Colloidal PbSe Quantum Dots Using Multiresonant Coherent Multidimensional Spectroscopy Kohler, Daniel D.; Block, Stephen B.; Kain, Schuyler The Journal of Physical Chemistry C, Vol. 118, Issue 9 https://doi.org/10.1021/jp412058u	journal	February 2014
Two-color three pulse photon echo peak shift spectroscopy Agarwal, Ritesh; Prall, Bradley S.; Rizvi, Abbas H. The Journal of Chemical Physics, Vol. 116, Issue 14 https://doi.org/10.1063/1.1459414	journal	April 2002
Femtosecond Stimulated Raman Study of Excited-State Evolution in Bacteriorhodopsin McCamant, David W.; Kukura, Philipp; Mathies, Richard A. The Journal of Physical Chemistry B, Vol. 109, Issue 20 https://doi.org/10.1021/jp050095x	journal	May 2005
Direct identification and decongestion of Fermi resonances by control of pulse time ordering in two-dimensional IR spectroscopy Donaldson, Paul M.; Guo, Rui; Fournier, Frederic The Journal of Chemical Physics, Vol. 127, Issue 11 https://doi.org/10.1063/1.2771176	journal	September 2007
Triply Resonant Sum Frequency Spectroscopy: Combining Advantages of Resonance Raman and 2D-IR Boyle, Erin S.; Neff-Mallon, Nathan A.; Wright, John C. The Journal of Physical Chemistry A, Vol. 117, Issue 47 https://doi.org/10.1021/jp409377a	journal	November 2013
Exciton–bath coupling and inhomogeneous broadening in the optical spectroscopy of semiconductor quantum dots Salvador, Mayrose R.; Hines, Margaret A.; Scholes, Gregory D. The Journal of Chemical Physics, Vol. 118, Issue 20 https://doi.org/10.1063/1.1568733	journal	May 2003
Two-dimensional line-shape analysis of photon-echo signal Okumura, Ko; Tokmakoff, Andrei; Tanimura, Yoshitaka Chemical Physics Letters, Vol. 314, Issue 5-6 https://doi.org/10.1016/s0009-2614(99)01173-2	journal	December 1999
Nonresonant Background Suppression in Broadband Vibrational Sum-Frequency Generation Spectroscopy Lagutchev, Alexei; Hambir, Selezion A.; Dlott, Dana D. The Journal of Physical Chemistry C, Vol. 111, Issue 37 https://doi.org/10.1021/jp075391j	journal	August 2007
Fully Coherent Triple Sum Frequency Spectroscopy of a Benzene Fermi Resonance Boyle, Erin S.; Pakoulev, Andrei V.; Wright, John C. The Journal of Physical Chemistry A, Vol. 117, Issue 27 https://doi.org/10.1021/jp404713x	journal	July 2013
Pump/probe self heterodyned 2D spectroscopy of vibrational transitions of a small globular peptide Hamm, Peter; Lim, Manho; DeGrado, William F. The Journal of Chemical Physics, Vol. 112, Issue 4 https://doi.org/10.1063/1.480772	journal	January 2000
Ultrafast Processes Rentzepis, P. M. Science, Vol. 169, Issue 3942 https://doi.org/10.1126/science.169.3942.239	journal	July 1970
Phase-locked heterodyne-detected stimulated photon echo. A unique tool to study solute—solvent interactions de Boeij, Wim P.; Pshenichnikov, Maxim S.; Wiersma, Douwe A. Chemical Physics Letters, Vol. 238, Issue 1-3 https://doi.org/10.1016/0009-2614(95)00452-1	journal	May 1995
Spectroscopic Characteristics of Triply Vibrationally Enhanced Four-Wave Mixing Spectroscopy ^† Besemann, Daniel M.; Meyer, Kent A.; Wright, John C. The Journal of Physical Chemistry B, Vol. 108, Issue 29 https://doi.org/10.1021/jp049597l	journal	July 2004
On the relation between the echo-peak shift and Brownian-oscillator correlation function de Boeij, Wim P.; Pshenichnikov, Maxim S.; Wiersma, Douwe A. Chemical Physics Letters, Vol. 253, Issue 1-2 https://doi.org/10.1016/0009-2614(96)00207-2	journal	April 1996
Photon echoes and related four‐wave‐mixing spectroscopies using phase‐locked pulses Cho, Minhaeng; Scherer, Norbert F.; Fleming, Graham R. The Journal of Chemical Physics, Vol. 96, Issue 8 https://doi.org/10.1063/1.462686	journal	April 1992
Three-Pulse Echo Peak Shift Studies of Polar Solvation Dynamics Passino, Sean A.; Nagasawa, Yutaka; Joo, Taiha The Journal of Physical Chemistry A, Vol. 101, Issue 4 https://doi.org/10.1021/jp9621383	journal	January 1997
Generation of Simplified Protein Raman Spectra Using Three-Color Picosecond Coherent Anti-Stokes Raman Spectroscopy Donaldson, Paul M.; Willison, Keith R.; Klug, David R. The Journal of Physical Chemistry B, Vol. 114, Issue 37 https://doi.org/10.1021/jp1061607	journal	September 2010
Molecular, multiresonant coherent four-wave mixing spectroscopy Wright, John C.; Carlson, Roger J.; Hurst, Gregory B. International Reviews in Physical Chemistry, Vol. 10, Issue 4 https://doi.org/10.1080/01442359109353262	journal	October 1991
Phase-stabilized two-dimensional electronic spectroscopy Brixner, Tobias; Mančal, Tomáš; Stiopkin, Igor V. The Journal of Chemical Physics, Vol. 121, Issue 9 https://doi.org/10.1063/1.1776112	journal	September 2004
Two-Color Pump−Probe Spectroscopies of Two- and Three-Level Systems: 2-Dimensional Line Shapes and Solvation Dynamics Kwac, Kijeong; Cho, Minhaeng The Journal of Physical Chemistry A, Vol. 107, Issue 31 https://doi.org/10.1021/jp034727w	journal	August 2003
Transient absorption of vibrationally excited water Bakker, H. J.; Nienhuys, H. -K.; Gallot, G. The Journal of Chemical Physics, Vol. 116, Issue 6 https://doi.org/10.1063/1.1432687	journal	February 2002
Intersystem crossing from singlet states of molecular dimers and monomers in mixed molecular crystals: picosecond stimulated photon echo experiments Patterson, F. G.; Lee, H. W. H.; Wilson, William L. Chemical Physics, Vol. 84, Issue 1 https://doi.org/10.1016/0301-0104(84)80005-1	journal	February 1984
Photon-echo relaxation in molecular mixed crystals Aartsma, Thijs J.; Wiersma, Douwe A. Chemical Physics Letters, Vol. 42, Issue 3 https://doi.org/10.1016/0009-2614(76)80667-7	journal	September 1976
The interaction of solutes with their environments Fleming, G. R.; Passino, S. A.; Nagasawa, Y. Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 356, Issue 1736 https://doi.org/10.1098/rsta.1998.0172	journal	February 1998
Ultrafast Librational Dynamics of the Hydrated Electron Emde, Michel F.; Baltus̆ka, Andrius; Kummrow, Andreas Physical Review Letters, Vol. 80, Issue 21 https://doi.org/10.1103/physrevlett.80.4645	journal	May 1998
Analysis of vibrational correlations and couplings in the lowest two singlet states of pentacene by high resolution, fully resonant, coherent four‐wave mixing spectroscopy Carlson, Roger J.; Wright, John C. The Journal of Chemical Physics, Vol. 92, Issue 9 https://doi.org/10.1063/1.458553	journal	May 1990
Enhanced selectivity for spectrochemical measurement by mode selection in fully resonant nonlinear mixing Carlson, Roger J.; Wright, John C. Analytical Chemistry, Vol. 63, Issue 14 https://doi.org/10.1021/ac00014a019	journal	July 1991
Frequency and Time-Resolved Triply Vibrationally Enhanced Four-Wave Mixing Spectroscopy Meyer, Kent A.; Wright, John C.; Thompson, David E. The Journal of Physical Chemistry A, Vol. 108, Issue 52 https://doi.org/10.1021/jp046137j	journal	December 2004
Line shape and Doppler broadening in resonant CARS and related nonlinear processes through a diagrammatic approach Druet, S. A. J.; Taran, J. -P. E.; Bordé, Ch. J. Journal de Physique, Vol. 40, Issue 9 https://doi.org/10.1051/jphys:01979004009081900	journal	January 1979
Resonance IR: A Coherent Multidimensional Analogue of Resonance Raman Boyle, Erin S.; Neff-Mallon, Nathan A.; Handali, Jonathan D. The Journal of Physical Chemistry A, Vol. 118, Issue 17 https://doi.org/10.1021/jp5018554	journal	April 2014
Simulating multidimensional optical wave-mixing signals with finite-pulse envelopes Schweigert, Igor V.; Mukamel, Shaul Physical Review A, Vol. 77, Issue 3 https://doi.org/10.1103/physreva.77.033802	journal	March 2008
Analysis of Femtosecond Dynamic Absorption Spectra of Nonstationary States Pollard, W. Annual Review of Physical Chemistry, Vol. 43, Issue 1 https://doi.org/10.1146/annurev.physchem.43.1.497	journal	January 1992
Measurement of $χ^{(3)}$ for Doubly Vibrationally Enhanced Four Wave Mixing Spectroscopy Zhao, Wei; Wright, John C. Physical Review Letters, Vol. 83, Issue 10 https://doi.org/10.1103/physrevlett.83.1950	journal	September 1999
Dependence of line shapes in femtosecond broadband stimulated Raman spectroscopy on pump-probe time delay Yoon, Sangwoon; McCamant, David W.; Kukura, Philipp The Journal of Chemical Physics, Vol. 122, Issue 2 https://doi.org/10.1063/1.1828044	journal	January 2005
Decongestion of methylene spectra in biological and non-biological systems using picosecond 2DIR spectroscopy measuring electron-vibration–vibration coupling Donaldson, Paul M.; Guo, Rui; Fournier, Frederic Chemical Physics, Vol. 350, Issue 1-3 https://doi.org/10.1016/j.chemphys.2008.02.050	journal	June 2008
Two-dimensional infrared spectroscopy of peptides by phase-controlled femtosecond vibrational photon echoes Asplund, M. C.; Zanni, M. T.; Hochstrasser, R. M. Proceedings of the National Academy of Sciences, Vol. 97, Issue 15 https://doi.org/10.1073/pnas.140227997	journal	July 2000
Optical fingerprinting of peptides using two-dimensional infrared spectroscopy: Proof of principle Fournier, Frédéric; Gardner, Elizabeth M.; Guo, Rui Analytical Biochemistry, Vol. 374, Issue 2 https://doi.org/10.1016/j.ab.2007.11.009	journal	March 2008
Spectral line‐narrowing and saturation effects in fully resonant nondegenerate four wave mixing Riebe, Michael T.; Wright, John C. The Journal of Chemical Physics, Vol. 88, Issue 5 https://doi.org/10.1063/1.453939	journal	March 1988
Measurement of Ultrafast Excitonic Dynamics of Few-Layer MoS ₂ Using State-Selective Coherent Multidimensional Spectroscopy Czech, Kyle J.; Thompson, Blaise J.; Kain, Schuyler ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b05198	journal	October 2015
Time- and frequency-resolved coherent two-dimensional IR spectroscopy: Its complementary relationship with the coherent two-dimensional Raman scattering spectroscopy Park, Kisam; Cho, Minhaeng The Journal of Chemical Physics, Vol. 109, Issue 24 https://doi.org/10.1063/1.477756	journal	December 1998
Finite pulse effects in single and double quantum spectroscopies Perlík, Václav; Hauer, Jürgen; Šanda, František Journal of the Optical Society of America B, Vol. 34, Issue 2 https://doi.org/10.1364/josab.34.000430	journal	January 2017
Multiresonant Coherent Multidimensional Electronic Spectroscopy of Colloidal PbSe Quantum Dots Yurs, Lena A.; Block, Stephen B.; Pakoulev, Andrei V. The Journal of Physical Chemistry C, Vol. 115, Issue 46 https://doi.org/10.1021/jp207273x	journal	October 2011
Nonlinear Two-Dimensional Vibrational Spectroscopy Zhao, Wei; Murdoch, Keith M.; Besemann, Daniel M. Applied Spectroscopy, Vol. 54, Issue 7 https://doi.org/10.1366/0003702001950481	journal	July 2000
Interference, Dephasing, and Coherent Control in Time-Resolved Frequency Domain Two-Dimensional Vibrational Spectra Meyer, Kent A.; Wright, John C. The Journal of Physical Chemistry A, Vol. 107, Issue 41 https://doi.org/10.1021/jp035146+	journal	September 2003
Mixed Frequency/Time Domain Optical Analogues of Heteronuclear Multidimensional NMR Pakoulev, Andrei V.; Rickard, Mark A.; Meyer, Kent A. The Journal of Physical Chemistry A, Vol. 110, Issue 10 https://doi.org/10.1021/jp057339y	journal	March 2006
Two-dimensional heterodyned and stimulated infrared photon echoes of N-methylacetamide-D Zanni, Martin T.; Asplund, Matthew C.; Hochstrasser, Robin M. The Journal of Chemical Physics, Vol. 114, Issue 10 https://doi.org/10.1063/1.1346647	journal	January 2001
Parametric and nonparametric four‐wave mixing in pentacene: p ‐terphenyl Steehler, J. K.; Wright, J. C. The Journal of Chemical Physics, Vol. 83, Issue 7 https://doi.org/10.1063/1.449177	journal	October 1985
Ultrafast Solvation Dynamics Explored by Femtosecond Photon echo Spectroscopies de Boeij, Wim P.; Pshenichnikov, Maxim S.; Wiersma, Douwe A. Annual Review of Physical Chemistry, Vol. 49, Issue 1 https://doi.org/10.1146/annurev.physchem.49.1.99	journal	October 1998
Line narrowing in multiresonant third order molecular spectroscopies Carlson, Roger J.; Wright, John C. Journal of Molecular Spectroscopy, Vol. 143, Issue 1 https://doi.org/10.1016/0022-2852(90)90256-p	journal	September 1990
Theoretical Foundations for a New Family of Infrared Four-Wave Mixing Spectroscopies Wright, John C.; Chen, Peter C.; Hamilton, James P. Applied Spectroscopy, Vol. 51, Issue 7 https://doi.org/10.1366/0003702971941601	journal	July 1997
Peak shapes in femtosecond 2D correlation spectroscopy Hybl, John D.; Christophe, Yannick; Jonas, David M. Chemical Physics, Vol. 266, Issue 2-3 https://doi.org/10.1016/s0301-0104(01)00233-6	journal	May 2001
Quantitative Modeling of Nonlinear Processes in Coherent Two-Dimensional Vibrational Spectroscopy ^† Wright, John C.; Condon, Nicholas J.; Murdoch, Keith M. The Journal of Physical Chemistry A, Vol. 107, Issue 40 https://doi.org/10.1021/jp034018i	journal	October 2003
M ULTIDIMENSIONAL F EMTOSECOND C ORRELATION S PECTROSCOPIES OF E LECTRONIC AND V IBRATIONAL E XCITATIONS Mukamel, Shaul Annual Review of Physical Chemistry, Vol. 51, Issue 1 https://doi.org/10.1146/annurev.physchem.51.1.691	journal	October 2000
Resonant non-linear spectroscopy in strong fields Dick, Bernhard; Hochstrasser, R. M. Chemical Physics, Vol. 75, Issue 2 https://doi.org/10.1016/0301-0104(83)85015-0	journal	March 1983
Coherent interactions in pump–probe absorption measurements: the effect of phase gratings Palfrey, S. L.; Heinz, T. F. Journal of the Optical Society of America B, Vol. 2, Issue 4 https://doi.org/10.1364/josab.2.000674	journal	January 1985
Efficient Calculation of Time- and Frequency-Resolved Four-Wave-Mixing Signals Gelin, Maxim F.; Egorova, Dassia; Domcke, Wolfgang Accounts of Chemical Research, Vol. 42, Issue 9 https://doi.org/10.1021/ar900045d	journal	September 2009
Efficient method for the calculation of time- and frequency-resolved four-wave mixing signals and its application to photon-echo spectroscopy Gelin, Maxim F.; Egorova, Dassia; Domcke, Wolfgang The Journal of Chemical Physics, Vol. 123, Issue 16 https://doi.org/10.1063/1.2062188	journal	October 2005
Analysis of vibronic mode coupling in pentacene by fully resonant coherent four‐wave mixing Carlson, Roger J.; Nguyen, Dinh C.; Wright, John C. The Journal of Chemical Physics, Vol. 92, Issue 3 https://doi.org/10.1063/1.458084	journal	February 1990
Compact broadband vibrational sum-frequency generation spectrometer with nonresonant suppression Lagutchev, Alexei; Lozano, Aaron; Mukherjee, Prabuddha Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 75, Issue 4 https://doi.org/10.1016/j.saa.2009.12.066	journal	April 2010
Analytical chemistry, multidimensional spectral signatures, and the future of coherent multidimensional spectroscopy Wright, John C. Chemical Physics Letters, Vol. 662 https://doi.org/10.1016/j.cplett.2016.07.045	journal	October 2016

Cited By (3)

Diagonal slice four-wave mixing: natural separation of coherent broadening mechanisms Diederich, Geoffrey M.; Autry, Travis M.; Siemens, Mark E. Optics Letters, Vol. 43, Issue 24 https://doi.org/10.1364/ol.43.006061	journal	January 2018
WrightTools: a Python package for multidimensional spectroscopy Thompson, Blaise; Sunden, Kyle; Morrow, Darien Journal of Open Source Software, Vol. 4, Issue 33 https://doi.org/10.21105/joss.01141	journal	January 2019
Diagonal Slice Four-Wave Mixing: Natural Separation of Coherent Broadening Mechanisms Diederich, Geoffrey M.; Autry, Travis M.; Siemens, Mark E. arXiv https://doi.org/10.48550/arxiv.1810.09255	text	January 2018

Similar Records

Theory for selective-vibrational-dephasing experiments with the use of transient stimulated Raman scattering in high laser depletion

Journal Article · Mon Aug 01 00:00:00 EDT 1983 · Phys. Rev. A; (United States) · OSTI ID:1393442

George, S M; Harris, C B

Time-resolved THz studies of carrier dynamics in semiconductors, superconductors, and strongly-correlated electron materials

Book · Tue Nov 14 00:00:00 EST 2006 · OSTI ID:1393442

Kaindl, Robert A; Averitt, Richard D

Exceptionally slow rise in differential reflectivity spectra of excitons in GaN : effect of excitation-induced dephasing.

Journal Article · Tue Jun 01 00:00:00 EDT 2004 · Proposed for publication in Physical Review B. · OSTI ID:1393442

Stanton, C J; Kenrow, J; El Sayed, K; +4 more

Related Subjects

14 SOLAR ENERGY
36 MATERIALS SCIENCE

Title: Frequency-domain coherent multidimensional spectroscopy when dephasing rivals pulsewidth: Disentangling material and instrument response

Citation Formats

References (70)

Cited By (3)

Similar Records

Related Subjects