Surface and Structural Investigation of a MnO x Birnessite-Type Water Oxidation Catalyst Formed under Photocatalytic Conditions

Deibert, Benjamin J.; Zhang, Jingming; Smith, Paul F.; Chapman, Karena W.; Rangan, Sylvie; Banerjee, Debasis; Tan, Kui; Wang, Hao; Pasquale, Nicholas; Chen, Feng; Lee, Ki-Bum; Dismukes, G. Charles; Chabal, Yves J.; Li, Jing

doi:10.1002/chem.201501930

Title: Surface and Structural Investigation of a MnO _x Birnessite-Type Water Oxidation Catalyst Formed under Photocatalytic Conditions

Journal Article · Tue Aug 11 00:00:00 EDT 2015 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201501930· OSTI ID:1392563

Deibert, Benjamin J.; Zhang, Jingming; Smith, Paul F.; Chapman, Karena W.; Rangan, Sylvie; Banerjee, Debasis; Tan, Kui; Wang, Hao; Pasquale, Nicholas; Chen, Feng; Lee, Ki-Bum; Dismukes, G. Charles; Chabal, Yves J.; Li, Jing

Catalytically active MnOx species have been reported to form in situ from various Mn-complexes during electrocatalytic and solution-based water oxidation when employing cerium(IV) ammonium ammonium nitrate (CAN) oxidant as a sacrificial reagent. The full structural characterization of these oxides may be complicated by the presence of support material and lack of a pure bulk phase. For the first time, we show that highly active MnOx catalysts form without supports in situ under photocatalytic conditions. Our most active (MnOx)-Mn-4 catalyst (similar to 0.84 mmol O-2 mol Mn-1 s(-1)) forms from a Mn4O4 bearing a metal-organic framework. 4MnO(x) is characterized by pair distribution function analysis PDF), Raman spectroscopy, and HR-TEM as a disordered, layered Mn-oxide with high surface area (216 m(2)g(-1)) and small regions of crystallinity and layer flexibility. In contrast, the (MnOx)-Mn-S formed from Mn2+ salt gives an amorphous species of lower surface area (80 m(2)g(-1)) and lower activity (similar to 0.15 mmol O-2 mol Mn(-1)s(-1)). We compare these catalysts to crystalline hexagonal birnessite, which activates under the same conditions. Full deconvolution of the XPS Mn2p(3/2) core levels detects enriched Mn3+ and Mn2+ content on the surfaces, which indicates possible disproportionation/comproportionation surface equilibria.

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1392563

Journal Information:: Chemistry - A European Journal, Vol. 21, Issue 40; ISSN 0947-6539

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

References (83)

Light-driven water oxidation for solar fuels Young, Karin J.; Martini, Lauren A.; Milot, Rebecca L. Coordination Chemistry Reviews, Vol. 256, Issue 21-22 https://doi.org/10.1016/j.ccr.2012.03.031	journal	November 2012
Synchrotron applications of an amorphous silicon flat-panel detector Lee, John H.; Aydıner, C. Can; Almer, Jonathan Journal of Synchrotron Radiation, Vol. 15, Issue 5 https://doi.org/10.1107/S090904950801755X	journal	July 2008
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E. Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454 https://doi.org/10.1021/ja203564w	journal	August 2011
Photochemical Water Oxidation by Crystalline Polymorphs of Manganese Oxides: Structural Requirements for Catalysis Robinson, David M.; Go, Yong Bok; Mui, Michelle Journal of the American Chemical Society, Vol. 135, Issue 9 https://doi.org/10.1021/ja310286h	journal	February 2013
Beyond crystallography: the study of disorder, nanocrystallinity and crystallographically challenged materials with pair distribution functions Billinge, Simon J. L.; Kanatzidis, M. G. Chemical Communications, Issue 7 https://doi.org/10.1039/b309577k	journal	January 2004
Electrosynthesis, functional, and structural characterization of a water-oxidizing manganese oxide Zaharieva, Ivelina; Chernev, Petko; Risch, Marcel Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21191b	journal	January 2012
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation Kärkäs, Markus D.; Verho, Oscar; Johnston, Eric V. Chemical Reviews, Vol. 114, Issue 24 https://doi.org/10.1021/cr400572f	journal	October 2014
Thin Films of Sodium Birnessite-Type MnO ₂ : Optical Properties, Electronic Band Structure, and Solar Photoelectrochemistry Pinaud, Blaise A.; Chen, Zhebo; Abram, David N. The Journal of Physical Chemistry C, Vol. 115, Issue 23 https://doi.org/10.1021/jp200015p	journal	May 2011
A new layered metal–organic framework as a promising heterogeneous catalyst for olefin epoxidation reactions Zhang, Jingming; Biradar, Ankush V.; Pramanik, Sanhita Chemical Communications, Vol. 48, Issue 52 https://doi.org/10.1039/c2cc18127d	journal	January 2012
Homogeneous Light-Driven Water Oxidation Catalyzed by a Tetraruthenium Complex with All Inorganic Ligands Geletii, Yurii V.; Huang, Zhuangqun; Hou, Yu Journal of the American Chemical Society, Vol. 131, Issue 22, p. 7522-7523 https://doi.org/10.1021/ja901373m	journal	June 2009
Manganese Oxides: Parallels between Abiotic and Biotic Structures Saratovsky, Ian; Wightman, Peter G.; Pastén, Pablo A. Journal of the American Chemical Society, Vol. 128, Issue 34 https://doi.org/10.1021/ja062097g	journal	August 2006
Synthesis, Structures, and Magnetic Properties of Three 3D Coordination Polymers Based on M ₄ O ₄ Cubanes (M = Mn ^II , Fe ^II , Co ^II ) Tian, Chong-Bin; Zhang, Hua-Bin; Peng, Yan European Journal of Inorganic Chemistry, Vol. 2012, Issue 25 https://doi.org/10.1002/ejic.201200353	journal	July 2012
Water-Splitting Chemistry of Photosystem II McEvoy, James P.; Brudvig, Gary W. Chemical Reviews, Vol. 106, Issue 11 https://doi.org/10.1021/cr0204294	journal	November 2006
A Functionally Stable Manganese Oxide Oxygen Evolution Catalyst in Acid Huynh, Michael; Bediako, D. Kwabena; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja413147e	journal	April 2014
Nanostructured cobalt and manganese oxide clusters as efficient water oxidation catalysts Jiao, Feng; Frei, Heinz Energy & Environmental Science, Vol. 3, Issue 8 https://doi.org/10.1039/c002074e	journal	January 2010
Water oxidation catalysts based on abundant 1st row transition metals Singh, Archana; Spiccia, Leone Coordination Chemistry Reviews, Vol. 257, Issue 17-18 https://doi.org/10.1016/j.ccr.2013.02.027	journal	September 2013
Visible Light-Driven Water Oxidation by Ir Oxide Clusters Coupled to Single Cr Centers in Mesoporous Silica Nakamura, Ryuhei; Frei, Heinz Journal of the American Chemical Society, Vol. 128, Issue 33 https://doi.org/10.1021/ja0625632	journal	August 2006
Calcium-Mangan(III)-Oxide (CaMn ₂ O ₄ ⋅ x H ₂ O) als biomimetische Katalysatoren für die Sauerstoffbildung Najafpour, Mohammad Mahdi; Ehrenberg, Till; Wiechen, Mathias Angewandte Chemie, Vol. 122, Issue 12 https://doi.org/10.1002/ange.200906745	journal	March 2010
New Synthetic Route, Characterization, and Electrocatalytic Activity of Nanosized Manganite Crisostomo, Vincent Mark B.; Ngala, J. Katana; Alia, Shaun Chemistry of Materials, Vol. 19, Issue 7 https://doi.org/10.1021/cm062871z	journal	March 2007
Uncovering Structure-Activity Relationships in Manganese-Oxide-Based Heterogeneous Catalysts for Efficient Water Oxidation Indra, Arindam; Menezes, Prashanth W.; Driess, Matthias ChemSusChem, Vol. 8, Issue 5 https://doi.org/10.1002/cssc.201402812	journal	January 2015
Luminescent Functional Metal–Organic Frameworks Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200101d	journal	June 2011
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å Umena, Yasufumi; Kawakami, Keisuke; Shen, Jian-Ren Nature, Vol. 473, Issue 7345 https://doi.org/10.1038/nature09913	journal	April 2011
Fragments of Layered Manganese Oxide Are the Real Water Oxidation Catalyst after Transformation of Molecular Precursor on Clay Najafpour, M. M.; Moghaddam, Atefeh N.; Dau, Holger Journal of the American Chemical Society, Vol. 136, Issue 20 https://doi.org/10.1021/ja5028716	journal	May 2014
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
Development of Bioinspired Mn ₄ O ₄ −Cubane Water Oxidation Catalysts: Lessons from Photosynthesis Dismukes, G. Charles; Brimblecombe, Robin; Felton, Greg A. N. Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar900249x	journal	December 2009
Active Mixed-Valent MnO _x Water Oxidation Catalysts through Partial Oxidation (Corrosion) of Nanostructured MnO Particles Indra, Arindam; Menezes, Prashanth W.; Zaharieva, Ivelina Angewandte Chemie International Edition, Vol. 52, Issue 50 https://doi.org/10.1002/anie.201307543	journal	October 2013
Artificial photosynthesis for solar water-splitting Tachibana, Yasuhiro; Vayssieres, Lionel; Durrant, James R. Nature Photonics, Vol. 6, Issue 8 https://doi.org/10.1038/nphoton.2012.175	journal	July 2012
Calcium Manganese(III) Oxides (CaMn ₂ O ₄ ⋅ x H ₂ O) as Biomimetic Oxygen-Evolving Catalysts Najafpour, Mohammad Mahdi; Ehrenberg, Till; Wiechen, Mathias Angewandte Chemie International Edition, Vol. 49, Issue 12 https://doi.org/10.1002/anie.200906745	journal	March 2010
Structural study of biotic and abiotic poorly-crystalline manganese oxides using atomic pair distribution function analysis Zhu, Mengqiang; Farrow, Christopher L.; Post, Jeffrey E. Geochimica et Cosmochimica Acta, Vol. 81 https://doi.org/10.1016/j.gca.2011.12.006	journal	March 2012
Sol-gel synthesis of birnessite from KMnO4 and simple sugars Ching, Stanton; Landrigan, Jennifer A.; Jorgensen, Matthew L. Chemistry of Materials, Vol. 7, Issue 9 https://doi.org/10.1021/cm00057a003	journal	September 1995
Metal oxides as heterogeneous catalysts for oxygen evolution under photochemical conditions Harriman, Anthony; Pickering, Ingrid J.; Thomas, John M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 84, Issue 8 https://doi.org/10.1039/f19888402795	journal	January 1988
Water Oxidation Catalysis using Amorphous Manganese Oxides, Octahedral Molecular Sieves (OMS-2), and Octahedral Layered (OL-1) Manganese Oxide Structures Iyer, Aparna; Del-Pilar, Joselyn; King’ondu, Cecil K. The Journal of Physical Chemistry C, Vol. 116, Issue 10 https://doi.org/10.1021/jp2120737	journal	February 2012
Rate and mechanism of the photoreduction of birnessite (MnO ₂ ) nanosheets Marafatto, Francesco Femi; Strader, Matthew L.; Gonzalez-Holguera, Julia Proceedings of the National Academy of Sciences, Vol. 112, Issue 15 https://doi.org/10.1073/pnas.1421018112	journal	March 2015
Efficient Light-Driven Carbon-Free Cobalt-Based Molecular Catalyst for Water Oxidation Huang, Zhuangqun; Luo, Zhen; Geletii, Yurii V. Journal of the American Chemical Society, Vol. 133, Issue 7, p. 2068-2071 https://doi.org/10.1021/ja109681d	journal	February 2011
Calculation of multiplet structure of core $p$ -vacancy levels Gupta, R. P.; Sen, S. K. Physical Review B, Vol. 10, Issue 1 https://doi.org/10.1103/PhysRevB.10.71	journal	July 1974
Applications of an amorphous silicon-based area detector for high-resolution, high-sensitivity and fast time-resolved pair distribution function measurements Chupas, Peter J.; Chapman, Karena W.; Lee, Peter L. Journal of Applied Crystallography, Vol. 40, Issue 3 https://doi.org/10.1107/S0021889807007856	journal	May 2007
Dissolution of β-MnOOH particles by ligands: pyrophosphate, ethylenediaminetetraacetate, and citrate Klewicki, J. K.; Morgan, J. J. Geochimica et Cosmochimica Acta, Vol. 63, Issue 19-20 https://doi.org/10.1016/S0016-7037(99)00229-X	journal	October 1999
Formation of a Nanoparticulate Birnessite-Like Phase in Purported Molecular Water Oxidation Catalyst Systems Hocking, Rosalie K.; Malaeb, Rafah; Gates, Will P. ChemCatChem, Vol. 6, Issue 7 https://doi.org/10.1002/cctc.201400066	journal	June 2014
Water-oxidation catalysis by synthetic manganese oxides – systematic variations of the calcium birnessite theme Frey, Carolin E.; Wiechen, Mathias; Kurz, Philipp Dalton Trans., Vol. 43, Issue 11 https://doi.org/10.1039/C3DT52604F	journal	January 2014
What Determines Catalyst Functionality in Molecular Water Oxidation? Dependence on Ligands and Metal Nuclearity in Cobalt Clusters Smith, Paul F.; Kaplan, Christopher; Sheats, John E. Inorganic Chemistry, Vol. 53, Issue 4 https://doi.org/10.1021/ic402720p	journal	December 2013
Vibrational analysis of nicotinic acid species based on ab initio molecular orbital calculations Sala, O.; Gonçalves, N. S.; Noda, L. K. Journal of Molecular Structure, Vol. 565-566 https://doi.org/10.1016/S0022-2860(00)00936-4	journal	May 2001
Structure of Synthetic K-rich Birnessite Obtained by High-Temperature Decomposition of KMnO ₄ . I. Two-Layer Polytype from 800 °C Experiment Gaillot, Anne-Claire; Flot, David; Drits, Victor A. Chemistry of Materials, Vol. 15, Issue 24 https://doi.org/10.1021/cm021733g	journal	December 2003
Luminescent metal–organic frameworks for chemical sensing and explosive detection Hu, Zhichao; Deibert, Benjamin J.; Li, Jing Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00010B	journal	January 2014
Rapid-acquisition pair distribution function (RA-PDF) analysis Chupas, Peter J.; Qiu, Xiangyun; Hanson, Jonathan C. Journal of Applied Crystallography, Vol. 36, Issue 6, p. 1342-1347 https://doi.org/10.1107/S0021889803017564	journal	November 2003
Kinetic Behavior of Mn(III) Complexes of Pyrophosphate, EDTA, and Citrate Klewicki, J. Kenneth; Morgan, James J. Environmental Science & Technology, Vol. 32, Issue 19 https://doi.org/10.1021/es980308e	journal	October 1998
Water oxidation catalysis by manganese oxides: learning from evolution Wiechen, M.; Najafpour, M. M.; Allakhverdiev, S. I. Energy & Environmental Science, Vol. 7, Issue 7 https://doi.org/10.1039/c4ee00681j	journal	January 2014
Synthetic manganese–calcium oxides mimic the water-oxidizing complex of photosynthesis functionally and structurally Zaharieva, Ivelina; Najafpour, M. Mahdi; Wiechen, Mathias Energy & Environmental Science, Vol. 4, Issue 7 https://doi.org/10.1039/c0ee00815j	journal	January 2011
Kinetics of Electron Transfer and Oxygen Evolution in the Reaction of [Ru(bpy) ₃ ] ³⁺ with Colloidal Iridium Oxide Morris, Natalie D.; Suzuki, Masahiro; Mallouk, Thomas E. The Journal of Physical Chemistry A, Vol. 108, Issue 42 https://doi.org/10.1021/jp0480145	journal	October 2004
Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks Wu, Haohan; Gong, Qihan; Olson, David H. Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200216x	journal	September 2011
The mineralogy and chemistry of manganese in some Australian soils Taylor, Rm; McKenzie, Rm; Norrish, K. Soil Research, Vol. 2, Issue 2 https://doi.org/10.1071/SR9640235	journal	January 1964
Reversible phase transformation of MnO ₂ nanosheets in an electrochemical capacitor investigated by in situRaman spectroscopy Hsu, Yu-Kuei; Chen, Ying-Chu; Lin, Yan-Gu Chem. Commun., Vol. 47, Issue 4 https://doi.org/10.1039/C0CC03902K	journal	January 2011
Mechanisms of pH-Dependent Activity for Water Oxidation to Molecular Oxygen by MnO ₂ Electrocatalysts Takashima, Toshihiro; Hashimoto, Kazuhito; Nakamura, Ryuhei Journal of the American Chemical Society, Vol. 134, Issue 3 https://doi.org/10.1021/ja206511w	journal	January 2012
An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction Fu, Yanghe; Sun, Dengrong; Chen, Yongjuan Angewandte Chemie International Edition, Vol. 51, Issue 14 https://doi.org/10.1002/anie.201108357	journal	February 2012
Structure–Property Relationship of Bifunctional MnO ₂ Nanostructures: Highly Efficient, Ultra-Stable Electrochemical Water Oxidation and Oxygen Reduction Reaction Catalysts Identified in Alkaline Media Meng, Yongtao; Song, Wenqiao; Huang, Hui Journal of the American Chemical Society, Vol. 136, Issue 32 https://doi.org/10.1021/ja505186m	journal	August 2014
Molecular artificial photosynthesis Berardi, Serena; Drouet, Samuel; Francàs, Laia Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60405E	journal	January 2014
Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell Youngblood, W. Justin; Lee, Seung-Hyun Anna; Kobayashi, Yoji Journal of the American Chemical Society, Vol. 131, Issue 3, p. 926-927 https://doi.org/10.1021/ja809108y	journal	January 2009
Structure of H-exchanged hexagonal birnessite and its mechanism of formation from Na-rich monoclinic buserite at low pH Lanson, Bruno; Drits, Victor A.; Silvester, Ewen American Mineralogist, Vol. 85, Issue 5-6 https://doi.org/10.2138/am-2000-5-625	journal	May 2000
Structure of synthetic Na-birnessite: Evidence for a triclinic one-layer unit cell Lanson, Bruno; Drits, Victor A.; Feng, Qi American Mineralogist, Vol. 87, Issue 11-12 https://doi.org/10.2138/am-2002-11-1215	journal	November 2002
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
Manganese Clusters with Relevance to Photosystem II Mukhopadhyay, Sumitra; Mandal, Sanjay K.; Bhaduri, Sumit Chemical Reviews, Vol. 104, Issue 9 https://doi.org/10.1021/cr0206014	journal	September 2004
Interpretation of XPS Mn(2p) spectra of Mn oxyhydroxides and constraints on the mechanism of MnO ₂ precipitation Nesbitt, H. W.; Banerjee, D. American Mineralogist, Vol. 83, Issue 3-4 https://doi.org/10.2138/am-1998-3-414	journal	April 1998
Molecular models of birnessite and related hydrated layered minerals Cygan, R. T.; Post, J. E.; Heaney, P. J. American Mineralogist, Vol. 97, Issue 8-9 https://doi.org/10.2138/am.2012.3957	journal	August 2012
Making Oxygen with Ruthenium Complexes Concepcion, Javier J.; Jurss, Jonah W.; Brennaman, M. Kyle Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9001526	journal	December 2009
Characterization of the manganese oxide produced by pseudomonas putida strain MnB1 Villalobos, Mario; Toner, Brandy; Bargar, John Geochimica et Cosmochimica Acta, Vol. 67, Issue 14 https://doi.org/10.1016/S0016-7037(03)00217-5	journal	July 2003
Investigation of Surface Oxidation Processes on Manganese Oxide Electrocatalysts Using Electrochemical Methods and Ex Situ X-ray Photoelectron Spectroscopy Gorlin, Yelena; Jaramillo, Thomas F. Journal of The Electrochemical Society, Vol. 159, Issue 10 https://doi.org/10.1149/2.017210jes	journal	January 2012
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Structural model for the biogenic Mn oxide produced by Pseudomonas putida Villalobos, M.; Lanson, B.; Manceau, A. American Mineralogist, Vol. 91, Issue 4 https://doi.org/10.2138/am.2006.1925	journal	April 2006
Evaluation of MnO _x , Mn ₂ O ₃ , and Mn ₃ O ₄ Electrodeposited Films for the Oxygen Evolution Reaction of Water Ramírez, Alejandra; Hillebrand, Philipp; Stellmach, Diana The Journal of Physical Chemistry C, Vol. 118, Issue 26 https://doi.org/10.1021/jp500939d	journal	June 2014
Vibrational study of nicotinic acid complexes with different central ions Lewandowski, Włodzimierz; Barańska, Halina; Mościbroda, Piotr Journal of Raman Spectroscopy, Vol. 24, Issue 12 https://doi.org/10.1002/jrs.1250241202	journal	December 1993
Inhibition of Charge Disproportionation of MnO ₂ Electrocatalysts for Efficient Water Oxidation under Neutral Conditions Takashima, Toshihiro; Hashimoto, Kazuhito; Nakamura, Ryuhei Journal of the American Chemical Society, Vol. 134, Issue 44 https://doi.org/10.1021/ja306499n	journal	October 2012
Elucidating the Domain Structure of the Cobalt Oxide Water Splitting Catalyst by X-ray Pair Distribution Function Analysis Du, Pingwu; Kokhan, Oleksandr; Chapman, Karena W. Journal of the American Chemical Society, Vol. 134, Issue 27 https://doi.org/10.1021/ja303826a	journal	June 2012
Layered manganese oxides for water-oxidation: alkaline earth cations influence catalytic activity in a photosystem II-like fashion Wiechen, Mathias; Zaharieva, Ivelina; Dau, Holger Chemical Science, Vol. 3, Issue 7 https://doi.org/10.1039/c2sc20226c	journal	January 2012
Nonequilibrium models for predicting forms of precipitated manganese oxides Hem, John D.; Lind, Carol J. Geochimica et Cosmochimica Acta, Vol. 47, Issue 11 https://doi.org/10.1016/0016-7037(83)90219-3	journal	November 1983
Using nickel manganese oxide catalysts for efficient water oxidation Menezes, Prashanth W.; Indra, Arindam; Levy, Ophir Chemical Communications, Vol. 51, Issue 24 https://doi.org/10.1039/C4CC09671A	journal	January 2015
An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO₂ Reduction Fu, Yanghe; Sun, Dengrong; Chen, Yongjuan Angewandte Chemie, Vol. 124, Issue 14, p. 3420-3423 https://doi.org/10.1002/ange.201108357	journal	February 2012
Water Oxidation by λ-MnO ₂ : Catalysis by the Cubical Mn ₄ O ₄ Subcluster Obtained by Delithiation of Spinel LiMn ₂ O ₄ Robinson, David M.; Go, Yong Bok; Greenblatt, Martha Journal of the American Chemical Society, Vol. 132, Issue 33 https://doi.org/10.1021/ja1055615	journal	August 2010
Water Oxidation Catalysis by Nanoparticulate Manganese Oxide Thin Films: Probing the Effect of the Manganese Precursors Singh, Archana; Hocking, Rosalie K.; Chang, Shery L. -Y. Chemistry of Materials, Vol. 25, Issue 7 https://doi.org/10.1021/cm3041345	journal	March 2013
Manganese Dioxide as Specific Redox Catalyst in the Photosensitized Oxygen Generation from Water Okuno, Yohmei; Yonemitsu, Osamu; Chiba, Yukihiro Chemistry Letters, Vol. 12, Issue 6 https://doi.org/10.1246/cl.1983.815	journal	June 1983
Nanostructured Manganese Oxides as Highly Active Water Oxidation Catalysts: A Boost from Manganese Precursor Chemistry Menezes, Prashanth W.; Indra, Arindam; Littlewood, Patrick ChemSusChem, Vol. 7, Issue 8 https://doi.org/10.1002/cssc.201402169	journal	July 2014
Electrochemical water splitting by layered and 3D cross-linked manganese oxides: correlating structural motifs and catalytic activity Bergmann, Arno; Zaharieva, Ivelina; Dau, Holger Energy & Environmental Science, Vol. 6, Issue 9 https://doi.org/10.1039/c3ee41194j	journal	January 2013
Fityk : a general-purpose peak fitting program Wojdyr, Marcin Journal of Applied Crystallography, Vol. 43, Issue 5 https://doi.org/10.1107/S0021889810030499	journal	September 2010
Raman spectra of birnessite manganese dioxides Julien, C. Solid State Ionics, Vol. 159, Issue 3-4 https://doi.org/10.1016/S0167-2738(03)00035-3	journal	April 2003
A distinct reversible colorimetric and fluorescent low pH response on a water-stable zirconium–porphyrin metal–organic framework Deibert, Benjamin J.; Li, Jing Chem. Commun., Vol. 50, Issue 68 https://doi.org/10.1039/C4CC01938E	journal	January 2014

Similar Records

Surface and Structural Investigation of a MnO _x Birnessite‐Type Water Oxidation Catalyst Formed under Photocatalytic Conditions

Journal Article · Tue Aug 11 00:00:00 EDT 2015 · Chemistry - A European Journal · OSTI ID:1392563

Deibert, Benjamin J.; Zhang, Jingming; Smith, Paul F.; +11 more

XPS determination of Mn oxidation states in Mn (hydr)oxides

Journal Article · Tue Mar 01 00:00:00 EST 2016 · Applied Surface Science · OSTI ID:1392563

Ilton, Eugene S.; Post, Jeffrey E.; Heaney, Peter J.; +2 more

Effective Zinc Adsorption Driven by Electrochemical Redox Reactions of Birnessite Nanosheets Generated by Solar Photochemistry

Journal Article · Mon Oct 08 00:00:00 EDT 2018 · ACS Sustainable Chemistry & Engineering · OSTI ID:1392563

Liu, Lihu; Tan, Wenfeng; Suib, Steven L.; +4 more

Related Subjects

birnessite structure
manganese oxide
metal-organic frameworks
water oxidation catalyst
water splitting

Title: Surface and Structural Investigation of a MnO x Birnessite-Type Water Oxidation Catalyst Formed under Photocatalytic Conditions

Citation Formats

References (83)

Similar Records

Related Subjects

Title: Surface and Structural Investigation of a MnO _x Birnessite-Type Water Oxidation Catalyst Formed under Photocatalytic Conditions