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Title: Miniature all-solid-state heterostructure nanowire Li-ion batteries as a tool for engineering and structural diagnostics of nanoscale electrochemical processes

Journal Article · · Nanoscale
DOI:https://doi.org/10.1039/C4NR01666A· OSTI ID:1384684
 [1];  [2];  [3];  [2];  [2];  [4];  [5];  [6];  [7]
  1. Material Measurement Laboratory; National Institute of Standards and Technology; Gaithersburg, USA; Department of Materials Science and Engineering; University of Maryland
  2. Center for Nanoscale Science and Technology; National Institute of Standards and Technology; Gaithersburg, USA
  3. Center for Nanoscale Science and Technology; National Institute of Standards and Technology; Gaithersburg, USA; Institute for Research in Electronics and Applied Physics; University of Maryland
  4. Material Measurement Laboratory; National Institute of Standards and Technology; Gaithersburg, USA
  5. Material Measurement Laboratory; National Institute of Standards and Technology; Gaithersburg, USA; Institute for Research in Electronics and Applied Physics; University of Maryland
  6. Department of Materials Science and Engineering; University of Maryland; College Park, USA
  7. Center for Nanoscale Science and Technology; National Institute of Standards and Technology; Gaithersburg, USA; Sandia National Laboratories; Livermore, USA

We have revealed the 3D structure of Li-ion batteries composed of LiCoO2cathode, LiPON electrolyte and Si anode deposited around Si nanowires as a scaffolding core.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001160
OSTI ID:
1384684
Journal Information:
Nanoscale, Vol. 6, Issue 20; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University; ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (41)

In Situ Transmission Electron Microscopy Observation of Pulverization of Aluminum Nanowires and Evolution of the Thin Surface Al 2 O 3 Layers during Lithiation–Delithiation Cycles journal October 2011
Atomic-Scale Imaging and Spectroscopy for In Situ Liquid Scanning Transmission Electron Microscopy journal May 2012
Micropower energy harvesting journal July 2009
In Situ Analytical Electron Microscopy for Probing Nanoscale Electrochemistry journal January 2011
Point defect characterization in HAADF-STEM images using multivariate statistical analysis journal February 2011
High-performance lithium battery anodes using silicon nanowires journal December 2007
Modeling All-Solid-State Li-Ion Batteries journal January 2011
Lithium fiber growth on the anode in a nanowire lithium ion battery during charging journal May 2011
Mapping of Heterogeneous Chemical States of Lithium in a LiNiO[sub 2]-Based Active Material by Electron Energy-Loss Spectroscopy journal January 2010
Electrochemical energy storage to power the 21st century journal July 2011
In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode journal December 2010
Solution-Grown Silicon Nanowires for Lithium-Ion Battery Anodes journal March 2010
All-Solid-State Lithium-Ion Microbatteries: A Review of Various Three-Dimensional Concepts journal November 2010
Phase transitions in LiCoO2 thin films prepared by pulsed laser deposition journal April 2012
A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorus Oxynitride journal January 1997
High voltage stability of LiCoO2 particles with a nano-scale Lipon coating journal July 2011
Dynamic Visualization of the Electric Potential in an All-Solid-State Rechargeable Lithium Battery journal June 2010
Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in LixCoO2 journal January 1992
Fabrication of Si core/C shell nanofibers and their electrochemical performances as a lithium-ion battery anode journal May 2012
In situ transmission electron microscopy and spectroscopy studies of interfaces in Li ion batteries: Challenges and opportunities journal August 2010
Preferred Orientation of Polycrystalline LiCoO[sub 2] Films journal January 2000
Single Nanowire Electrochemical Devices journal October 2010
Quantitative chemical phase analysis of EFTEM elemental maps using scatter diagrams journal February 1998
Fe valence determination and Li elemental distribution in lithiated FeO0.7F1.3/C nanocomposite battery materials by electron energy loss spectroscopy (EELS) journal January 2012
Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation journal August 2011
Kinetics investigation of a preferential (104) plane oriented LiCoO2 thin film prepared by RF magnetron sputtering journal July 2007
Nanostructured electrodes for lithium-ion and lithium-air batteries: the latest developments, challenges, and perspectives journal November 2011
Annular dark field imaging in a TEM journal June 2004
In Situ TEM Investigation of Congruent Phase Transition and Structural Evolution of Nanostructured Silicon/Carbon Anode for Lithium Ion Batteries journal February 2012
First Cross-Section Observation of an All Solid-State Lithium-Ion “Nanobattery” by Transmission Electron Microscopy journal March 2008
Fracture of crystalline silicon nanopillars during electrochemical lithium insertion journal February 2012
Lithium-Assisted Electrochemical Welding in Silicon Nanowire Battery Electrodes journal February 2012
Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries journal December 2011
Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution journal August 2011
Li–O2 and Li–S batteries with high energy storage journal January 2012
Atomic resolution of lithium ions in LiCoO2 journal June 2003
Crystalline-Amorphous Core−Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes journal January 2009
Determination of Activation Energy for Li Ion Diffusion in Electrodes journal March 2009
TEM Study of Electrochemical Cycling-Induced Damage and Disorder in LiCoO[sub 2] Cathodes for Rechargeable Lithium Batteries journal January 1999
Relativistic effects in electron-energy-loss-spectroscopy observations of the S i / S i O 2 interface plasmon peak journal September 1997
Thin-film lithium and lithium-ion batteries journal November 2000