Iridium complexes bearing a PNP ligand, favoring facile C(sp3)–H bond cleavage

Lokare, Kapil S.; Nielsen, Robert J.; Yousufuddin, Muhammed; Goddard III, William A.; Periana, Roy A.

doi:10.1039/c1dt10577a

Title: Iridium complexes bearing a PNP ligand, favoring facile C(sp3)–H bond cleavage

Journal Article · Sat Jan 01 00:00:00 EST 2011 · Dalton Transactions

DOI:https://doi.org/10.1039/c1dt10577a· OSTI ID:1380919

Lokare, Kapil S.; Nielsen, Robert J.; Yousufuddin, Muhammed; Goddard III, William A.; Periana, Roy A.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Catalytic Hydrocarbon Functionalization (CCHF)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001298

OSTI ID:: 1380919

Journal Information:: Dalton Transactions, Vol. 40, Issue 36; Related Information: CCHF partners with University of Virginia (lead); Brigham Young University; California Institute of Technology; Colorado School of Mines; University of Maryland; University of North Carolina, Chapel Hill; University of North Texas; Princeton University; The Scripps Research Institute; Yale University; ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (13)

Selective Ortho C−H Activation of Haloarenes by an Ir(I) System Ben-Ari, Eyal; Gandelman, Mark; Rozenberg, Haim Journal of the American Chemical Society, Vol. 125, Issue 16 https://doi.org/10.1021/ja028362p	journal	April 2003
Transition Metal-Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines Kawatsura, Motoi; Hartwig, John F. Organometallics, Vol. 20, Issue 10 https://doi.org/10.1021/om0009987	journal	May 2001
Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents Hashiguchi, Brian G.; Young, Kenneth J. H.; Yousufuddin, Muhammed Journal of the American Chemical Society, Vol. 132, Issue 36 https://doi.org/10.1021/ja102518m	journal	September 2010
Electron-Rich, Bulky Ruthenium PNP-Type Complexes. Acceptorless Catalytic Alcohol Dehydrogenation Zhang, Jing; Gandelman, Mark; Shimon, Linda J. W. Organometallics, Vol. 23, Issue 17 https://doi.org/10.1021/om049716j	journal	July 2004
Facile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes Zhang, Jing; Leitus, Gregory; Ben-David, Yehoshoa Journal of the American Chemical Society, Vol. 127, Issue 31 https://doi.org/10.1021/ja052862b	journal	August 2005
A Mercury-Catalyzed, High-Yield System for the Oxidation of Methane to Methanol Periana, R. A.; Taube, D. J.; Evitt, E. R. Science, Vol. 259, Issue 5093 https://doi.org/10.1126/science.259.5093.340	journal	January 1993
Synthesis, Structure, and Reactivity of New Rhodium and Iridium Complexes, Bearing a Highly Electron-Donating PNP System. Iridium-Mediated Vinylic C−H Bond Activation Hermann, Dominik; Gandelman, Mark; Rozenberg, Haim Organometallics, Vol. 21, Issue 5 https://doi.org/10.1021/om010719v	journal	March 2002
ortho C−H Activation of Haloarenes and Anisole by an Electron-Rich Iridium(I) Complex: Mechanism and Origin of Regio- and Chemoselectivity. An Experimental and Theoretical Study Ben-Ari, Eyal; Cohen, Revital; Gandelman, Mark Organometallics, Vol. 25, Issue 13 https://doi.org/10.1021/om060078+	journal	May 2006
Metal−Ligand Cooperation in C−H and H ₂ Activation by an Electron-Rich PNP Ir(I) System: Facile Ligand Dearomatization−Aromatization as Key Steps Ben-Ari, Eyal; Leitus, Gregory; Shimon, Linda J. W. Journal of the American Chemical Society, Vol. 128, Issue 48 https://doi.org/10.1021/ja066411i	journal	December 2006
Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes Tanaka, Ryo; Yamashita, Makoto; Nozaki, Kyoko Journal of the American Chemical Society, Vol. 131, Issue 40 https://doi.org/10.1021/ja903574e	journal	October 2009
CH Bond Activation by Rhodium(I) Hydroxide and Phenoxide Complexes Kloek, Susan M.; Heinekey, D. Michael; Goldberg, Karen I. Angewandte Chemie International Edition, Vol. 46, Issue 25 https://doi.org/10.1002/anie.200700270	journal	June 2007
Experimental realization of catalytic CH4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability Young, Kenneth J. H.; Oxgaard, Jonas; Ess, Daniel H. Chemical Communications, Issue 22 https://doi.org/10.1039/b823303a	journal	January 2009
Metal–ligand cooperation in the trans addition of dihydrogen to a pincer Ir(i) complex: a DFT study Iron, Mark A.; Ben-Ari, Eyal; Cohen, Revital Dalton Transactions, Issue 43 https://doi.org/10.1039/b909852f	journal	January 2009

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Title: Iridium complexes bearing a PNP ligand, favoring facile C(sp3)–H bond cleavage

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