Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition

Benson, David M.; Tsang, Chu F.; Sugar, Joshua Daniel; Jagannathan, Kaushik; Robinson, David B.; El Gabaly, Farid; Cappillino, Patrick J.; Stickney, John L.

doi:10.1021/acsami.7b03005

Title: Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition

Journal Article · Fri Apr 28 00:00:00 EDT 2017 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.7b03005· OSTI ID:1360933

^[1]; Tsang, Chu F. ^[1]; Sugar, Joshua Daniel ^[2]; Jagannathan, Kaushik ^[1]; Robinson, David B. ^[2]; El Gabaly, Farid ^[2]; Cappillino, Patrick J. ^[3]; Stickney, John L. ^[1]

Univ. of Georgia, Athens, GA (United States). Dept. of Chemistry
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sandia National Lab. (SNL-CA), Livermore, CA (United States); Univ. of Massachusetts, North Dartmouth, MA (United States). Dept. of Chemistry and Biochemistry

One method for the formation of nanofilms of materials, is Electrochemical atomic layer deposition (E-ALD), one atomic layer at a time. It uses the galvanic exchange of a less noble metal, deposited using underpotential deposition (UPD), to produce an atomic layer of a more noble element by reduction of its ions. This process is referred to as surface limited redox replacement and can be repeated in a cycle to grow thicker deposits. Previously, we performed it on nanoparticles and planar substrates. In the present report, E-ALD is applied for coating a submicron-sized powder substrate, making use of a new flow cell design. E-ALD is used to coat a Pd powder substrate with different thicknesses of Rh by exchanging it for Cu UPD. Furthermore, cyclic voltammetry and X-ray photoelectron spectroscopy indicate an increasing Rh coverage with increasing numbers of deposition cycles performed, in a manner consistent with the atomic layer deposition (ALD) mechanism. Cyclic voltammetry also indicated increased kinetics of H sorption and desorption in and out of the Pd powder with Rh present, relative to unmodified Pd.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC04-94AL85000; NA0003525; AC02-05CH11231

OSTI ID:: 1360933

Report Number(s):: SAND-2017-5175J; 653340; TRN: US1701980

Journal Information:: ACS Applied Materials and Interfaces, Vol. 9, Issue 21; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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rhodium
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Title: Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition

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