A water activity based model of heterogeneous ice nucleation kinetics for freezing of water and aqueous solution droplets

Knopf, Daniel A.; Alpert, Peter A.

doi:10.1039/C3FD00035D

Title: A water activity based model of heterogeneous ice nucleation kinetics for freezing of water and aqueous solution droplets

Journal Article · Wed Apr 24 00:00:00 EDT 2013 · Faraday Discussions

DOI:https://doi.org/10.1039/C3FD00035D· OSTI ID:1349435

Knopf, Daniel A. ^[1]; Alpert, Peter A. ^[1]

Stony Brook Univ., Stony Brook, NY (United States)

Immersion freezing of water and aqueous solutions by particles acting as ice nuclei (IN) is a common process of heterogeneous ice nucleation which occurs in many environments, especially in the atmosphere where it results in the glaciation of clouds. Here we experimentally show, using a variety of IN types suspended in various aqueous solutions, that immersion freezing temperatures and kinetics can be described solely by temperature, T, and solution water activity, a_w, which is the ratio of the vapour pressure of the solution and the saturation water vapour pressure under the same conditions and, in equilibrium, equivalent to relative humidity (RH). This allows the freezing point and corresponding heterogeneous ice nucleation rate coefficient, J_het, to be uniquely expressed by T and a_w, a result we term the aw based immersion freezing model (ABIFM). This method is independent of the nature of the solute and accounts for several varying parameters, including cooling rate and IN surface area, while providing a holistic description of immersion freezing and allowing prediction of freezing temperatures, J_het, frozen fractions, ice particle production rates and numbers. Our findings are based on experimental freezing data collected for various IN surface areas, A, and cooling rates, r, of droplets variously containing marine biogenic material, two soil humic acids, four mineral dusts, and one organic monolayer acting as IN. For all investigated IN types we demonstrate that droplet freezing temperatures increase as A increases. Similarly, droplet freezing temperatures increase as the cooling rate decreases. The log₁₀(J_het) values for the various IN types derived exclusively by T and a_w, provide a complete description of the heterogeneous ice nucleation kinetics. Thus, the ABIFM can be applied over the entire range of T, RH, total particulate surface area, and cloud activation timescales typical of atmospheric conditions. Finally, we demonstrate that ABIFM can be used to derive frozen fractions of droplets and ice particle production for atmospheric models of cirrus and mixed phase cloud conditions.

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Research Organization:: Stony Brook Univ., NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: SC0008613

OSTI ID:: 1349435

Journal Information:: Faraday Discussions, Vol. 165; ISSN 1359-6640

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 77 works

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A comprehensive laboratory study on the immersion freezing behavior of illite NX particles: a comparison of 17 ice nucleation measurement techniques Hiranuma, N.; Augustin-Bauditz, S.; Bingemer, H. Atmospheric Chemistry and Physics, Vol. 15, Issue 5 https://doi.org/10.5194/acp-15-2489-2015	journal	January 2015
Integrating laboratory and field data to quantify the immersion freezing ice nucleation activity of mineral dust particles DeMott, P. J.; Prenni, A. J.; McMeeking, G. R. Atmospheric Chemistry and Physics, Vol. 15, Issue 1 https://doi.org/10.5194/acp-15-393-2015	journal	January 2015
A laboratory investigation of the ice nucleation efficiency of three types of mineral and soil dust Paramonov, Mikhail; David, Robert O.; Kretzschmar, Ruben Atmospheric Chemistry and Physics, Vol. 18, Issue 22 https://doi.org/10.5194/acp-18-16515-2018	journal	January 2018
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 1: The K-feldspar microcline Kumar, Anand; Marcolli, Claudia; Luo, Beiping Atmospheric Chemistry and Physics, Vol. 18, Issue 10 https://doi.org/10.5194/acp-18-7057-2018	journal	January 2018
Mixed-phase orographic cloud microphysics during StormVEx and IFRACS Lowenthal, Douglas H.; Hallar, A. Gannet; David, Robert O. Atmospheric Chemistry and Physics, Vol. 19, Issue 8 https://doi.org/10.5194/acp-19-5387-2019	journal	January 2019
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 2: Quartz and amorphous silica Kumar, Anand; Marcolli, Claudia; Peter, Thomas Atmospheric Chemistry and Physics, Vol. 19, Issue 9 https://doi.org/10.5194/acp-19-6035-2019	journal	January 2019
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 3: Aluminosilicates Kumar, Anand; Marcolli, Claudia; Peter, Thomas Atmospheric Chemistry and Physics, Vol. 19, Issue 9 https://doi.org/10.5194/acp-19-6059-2019	journal	January 2019
An instrument for quantifying heterogeneous ice nucleation in multiwell plates using infrared emissions to detect freezing Harrison, Alexander D.; Whale, Thomas F.; Rutledge, Rupert Atmospheric Measurement Techniques, Vol. 11, Issue 10 https://doi.org/10.5194/amt-11-5629-2018	journal	January 2018
A technique for quantifying heterogeneous ice nucleation in microlitre supercooled water droplets Whale, T. F.; Murray, B. J.; O'Sullivan, D. Atmospheric Measurement Techniques, Vol. 8, Issue 6 https://doi.org/10.5194/amt-8-2437-2015	journal	January 2015
BINARY: an optical freezing array for assessing temperature and time dependence of heterogeneous ice nucleation Budke, C.; Koop, T. Atmospheric Measurement Techniques Discussions, Vol. 7, Issue 9 https://doi.org/10.5194/amtd-7-9137-2014	journal	January 2014
Contact freezing: a review of experimental studies A., Ladino Moreno, Luis; Olaf, Stetzer,; Ulrike, Lohmann, ETH Zurich https://doi.org/10.3929/ethz-b-000073893	text	January 2013
A comprehensive laboratory study on the immersion freezing behavior of illite NX particles: A comparison of 17 ice nucleation measurement techniques Hiranuma, Naruki; Augustin-Bauditz, Stefanie; Bingemer, Heinz ETH Zurich https://doi.org/10.3929/ethz-b-000099687	text	January 2015
Perspectives on the Future of Ice Nucleation Research: Research Needs and Unanswered Questions Identified from Two International Workshops Coluzza, Ivan; Creamean, Jessie; Rossi, Michel J. ETH Zurich https://doi.org/10.3929/ethz-b-000191806	text	January 2017
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions - Part 1: The K-feldspar microcline Kumar, Anand; Marcolli, Claudia; Luo, Beiping ETH Zurich https://doi.org/10.3929/ethz-b-000267937	text	January 2018
A laboratory investigation of the ice nucleation efficiency of three types of mineral and soil dust Mikhail, Paramonov,; O., David, Robert; Ruben, Kretzschmar, ETH Zurich https://doi.org/10.3929/ethz-b-000303568	text	January 2018
Mixed-phase orographic cloud microphysics during StormVEx and IFRACS Lowenthal, Douglas H.; Hallar, A. Gannet; David, Robert O. ETH Zurich https://doi.org/10.3929/ethz-b-000341184	text	January 2019
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions – Part 2: Quartz and amorphous silica Kumar, Anand; Marcolli, Claudia; Peter, Thomas ETH Zurich https://doi.org/10.3929/ethz-b-000342178	text	January 2019
Ice nucleation activity of silicates and aluminosilicates in pure water and aqueous solutions - Part 3: Aluminosilicates Anand, Kumar,; Claudia, Marcolli,; Thomas, Peter, ETH Zurich https://doi.org/10.3929/ethz-b-000343155	text	January 2019
Laboratory studies of immersion and deposition mode ice nucleation of ozone aged mineral dust particles Kanji, Zamin A.; Welti, André; Chou, Cédric ETH Zurich https://doi.org/10.3929/ethz-b-000071931	text	January 2013
BINARY: an optical freezing array for assessing temperature and time dependence of heterogeneous ice nucleation Budke, C.; Koop, T. Atmospheric Measurement Techniques, Vol. 8, Issue 2 https://doi.org/10.5194/amt-8-689-2015	journal	January 2015
A technique for quantifying heterogeneous ice nucleation in microlitre supercooled water droplets Whale, Thomas F.; Murray, Benjamin J.; O'Sullivan, Daniel ETH Zurich https://doi.org/10.3929/ethz-b-000109446	text	January 2015

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