Materials Data on K2Sn(H2N)6 by Materials Project
K2Sn(NH2)6 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. K1+ is bonded in a 9-coordinate geometry to six equivalent N3- and three equivalent H1+ atoms. There are three shorter (2.87 Å) and three longer (2.99 Å) K–N bond lengths. All K–H bond lengths are 2.87 Å. Sn4+ is bonded in an octahedral geometry to six equivalent N3- atoms. All Sn–N bond lengths are 2.23 Å. N3- is bonded in a distorted water-like geometry to two equivalent K1+, one Sn4+, and two H1+ atoms. Both N–H bond lengths are 1.03 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one K1+ and one N3- atom.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Contributing Organization:
- MIT; UC Berkeley; Duke; U Louvain
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- OSTI ID:
- 1280300
- Report Number(s):
- mp-643371
- Resource Relation:
- Related Information: https://materialsproject.org/citing
- Country of Publication:
- United States
- Language:
- English
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