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Title: Vapor space characterization of waste Tank 241-C-104: Results from samples collected on 2/17/94 and 3/3/94

Technical Report ·
DOI:https://doi.org/10.2172/124981· OSTI ID:124981

This report describes inorganic and organic analyses results from samples obtained from the headspace of the Hanford waste storage Tank 241-C-104 (referred to as Tank C-104). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Summary Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH{sub 3}), nitrogen dioxide (NO{sub 2}), nitric oxide (NO), sulfur oxides (SO{sub x}), and water vapor (H{sub 2}O). Organic compounds were also quantitatively determined. Occupational Safety and Health Administration (OSHA) versatile sampler (OVS) tubes were analyzed for tributyl phosphate. Twenty-four organic tentatively identified compounds (TICs) were observed above the detection limit of (ca.) 10 ppbv, but standards for most of these were not available at the time of analysis, and the reported concentrations are semiquantitative estimates. In addition, the authors looked for the 40 standard TO-14 analytes. Of these, two were observed above the 2-ppbv calibrated instrument detection limit. The 10 organic analytes with the highest estimated concentrations are listed in Summary Table 1. These 10 analytes account for approximately 88% of the total organic components in Tank C 104. Tank C-104 is not on any of the Watch Lists.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Environmental Restoration and Waste Management, Washington, DC (United States)
DOE Contract Number:
AC06-87RL10930; AC06-76RL01830
OSTI ID:
124981
Report Number(s):
PNL-10499; ON: DE96001898; TRN: AHC29528%%15
Resource Relation:
Other Information: PBD: Oct 1995
Country of Publication:
United States
Language:
English