Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products

Michan, Alison L.; Leskes, Michal; Grey, Clare P.

doi:10.1021/acs.chemmater.5b04408

Title: Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products

Journal Article · Mon Dec 28 00:00:00 EST 2015 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.5b04408· OSTI ID:1234032

Michan, Alison L. ^[1]; Leskes, Michal ^[1]; Grey, Clare P. ^[1]

Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, United Kingdom

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1234032

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Vol. 28 Journal Issue: 1; ISSN 0897-4756

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 115 works

Citation information provided by
Web of Science

References (48)

Correlation between irreversible capacity and electrolyte solvents degradation probed by NMR in Si-based negative electrode of Li-ion cell Delpuech, N.; Dupré, N.; Mazouzi, D. Electrochemistry Communications, Vol. 33 https://doi.org/10.1016/j.elecom.2013.05.001	journal	August 2013
Reversible Cycling of Crystalline Silicon Powder Obrovac, M. N.; Krause, L. J. Journal of The Electrochemical Society, Vol. 154, Issue 2 https://doi.org/10.1149/1.2402112	journal	January 2007
Density‐functional thermochemistry. III. The role of exact exchange Becke, Axel D. The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652 https://doi.org/10.1063/1.464913	journal	April 1993
Direct Calculation of Li-Ion Transport in the Solid Electrolyte Interphase Shi, Siqi; Lu, Peng; Liu, Zhongyi Journal of the American Chemical Society, Vol. 134, Issue 37 https://doi.org/10.1021/ja305366r	journal	September 2012
Examining Solid Electrolyte Interphase Formation on Crystalline Silicon Electrodes: Influence of Electrochemical Preparation and Ambient Exposure Conditions Schroder, Kjell W.; Celio, Hugo; Webb, Lauren J. The Journal of Physical Chemistry C, Vol. 116, Issue 37 https://doi.org/10.1021/jp307372m	journal	September 2012
Role of the LiPF ₆ Salt for the Long-Term Stability of Silicon Electrodes in Li-Ion Batteries – A Photoelectron Spectroscopy Study Philippe, Bertrand; Dedryvère, Rémi; Gorgoi, Mihaela Chemistry of Materials, Vol. 25, Issue 3 https://doi.org/10.1021/cm303399v	journal	January 2013
A review on electrolyte additives for lithium-ion batteries Zhang, Sheng Shui Journal of Power Sources, Vol. 162, Issue 2, p. 1379-1394 https://doi.org/10.1016/j.jpowsour.2006.07.074	journal	November 2006
A new look at the solid electrolyte interphase on graphite anodes in Li-ion batteries Edström, Kristina; Herstedt, Marie; Abraham, Daniel P. Journal of Power Sources, Vol. 153, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.05.062	journal	February 2006
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density Lee, Chengteh; Yang, Weitao; Parr, Robert G. Physical Review B, Vol. 37, Issue 2 https://doi.org/10.1103/PhysRevB.37.785	journal	January 1988
An In Situ X-Ray Diffraction Study of the Reaction of Li with Crystalline Si Li, Jing; Dahn, J. R. Journal of The Electrochemical Society, Vol. 154, Issue 3 https://doi.org/10.1149/1.2409862	journal	January 2007
Hydrolysis in the system LiPF6—propylene carbonate—dimethyl carbonate—H2O Plakhotnyk, Andriy V.; Ernst, Ludger; Schmutzler, Reinhard Journal of Fluorine Chemistry, Vol. 126, Issue 1 https://doi.org/10.1016/j.jfluchem.2004.09.027	journal	January 2005
Modelling one- and two-dimensional solid-state NMR spectra: Modelling 1D and 2D solid-state NMR spectra Massiot, Dominique; Fayon, Franck; Capron, Mickael Magnetic Resonance in Chemistry, Vol. 40, Issue 1 https://doi.org/10.1002/mrc.984	journal	December 2001
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions Aurbach, D. Solid State Ionics, Vol. 148, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00080-2	journal	June 2002
Nanosilicon-Based Thick Negative Composite Electrodes for Lithium Batteries with Graphene as Conductive Additive Nguyen, Binh Phuong Nhan; Kumar, Nanjundan Ashok; Gaubicher, Joël Advanced Energy Materials, Vol. 3, Issue 10 https://doi.org/10.1002/aenm.201300330	journal	June 2013
High Field Multinuclear NMR Investigation of the SEI Layer in Lithium Rechargeable Batteries Meyer, Benjamin M.; Leifer, Nicole; Sakamoto, Sarah Electrochemical and Solid-State Letters, Vol. 8, Issue 3 https://doi.org/10.1149/1.1854117	journal	January 2005
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes Peled, E. Journal of The Electrochemical Society, Vol. 144, Issue 8 https://doi.org/10.1149/1.1837858	journal	January 1997
Lithium transport within the solid electrolyte interphase Lu, Peng; Harris, Stephen J. Electrochemistry Communications, Vol. 13, Issue 10 https://doi.org/10.1016/j.elecom.2011.06.026	journal	October 2011
Consequences of air exposure on the lithiated graphite SEI Malmgren, Sara; Ciosek, Katarzyna; Lindblad, Rebecka Electrochimica Acta, Vol. 105 https://doi.org/10.1016/j.electacta.2013.04.118	journal	August 2013
The Effect of Vinylene Carbonate Additive on Surface Film Formation on Both Electrodes in Li-Ion Batteries El Ouatani, L.; Dedryvère, R.; Siret, C. Journal of The Electrochemical Society, Vol. 156, Issue 2 https://doi.org/10.1149/1.3029674	journal	January 2009
Silicon Composite Electrode with High Capacity and Long Cycle Life Mazouzi, D.; Lestriez, B.; Roué, L. Electrochemical and Solid-State Letters, Vol. 12, Issue 11 https://doi.org/10.1149/1.3212894	journal	January 2009
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries Aurbach, Doron Journal of Power Sources, Vol. 89, Issue 2 https://doi.org/10.1016/S0378-7753(00)00431-6	journal	August 2000
Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid Magasinski, Alexandre; Zdyrko, Bogdan; Kovalenko, Igor ACS Applied Materials & Interfaces, Vol. 2, Issue 11 https://doi.org/10.1021/am100871y	journal	October 2010
Interfacing electrolytes with electrodes in Li ion batteries Xu, Kang; von Cresce, Arthur Journal of Materials Chemistry, Vol. 21, Issue 27 https://doi.org/10.1039/c0jm04309e	journal	January 2011
XPS analysis for the lithium surface immersed in γ-butyrolactone containing various salts Kanamura, Kiyoshi; Tamura, Hiroshi; Shiraishi, Soshi Electrochimica Acta, Vol. 40, Issue 7 https://doi.org/10.1016/0013-4686(93)E0020-M	journal	May 1995
Effects of lithium salts on thermal stabilities of lithium alkyl carbonates in SEI layer Ryou, Myung-Hyun; Lee, Je-Nam; Lee, Dong Jin Electrochimica Acta, Vol. 83 https://doi.org/10.1016/j.electacta.2012.08.012	journal	November 2012
Syntheses and Characterization of Lithium Alkyl Mono- and Dicarbonates as Components of Surface Films in Li-Ion Batteries Xu, Kang; Zhuang, Guorong V.; Allen, Jan L. The Journal of Physical Chemistry B, Vol. 110, Issue 15 https://doi.org/10.1021/jp0601522	journal	March 2006
Investigation on the part played by the solid electrolyte interphase on the electrochemical performances of the silicon electrode for lithium-ion batteries Ulldemolins, M.; Le Cras, F.; Pecquenard, B. Journal of Power Sources, Vol. 206 https://doi.org/10.1016/j.jpowsour.2012.01.095	journal	May 2012
XPS Identification of the Organic and Inorganic Components of the Electrode/Electrolyte Interface Formed on a Metallic Cathode Dedryvère, R.; Laruelle, S.; Grugeon, S. Journal of The Electrochemical Society, Vol. 152, Issue 4 https://doi.org/10.1149/1.1861994	journal	January 2005
Si Electrodes for Li-Ion Batteries—A New Way to Look at an Old Problem Beattie, S. D.; Larcher, D.; Morcrette, M. Journal of The Electrochemical Society, Vol. 155, Issue 2 https://doi.org/10.1149/1.2817828	journal	January 2008
An Investigation of Weak CH···O Hydrogen Bonds in Maltose Anomers by a Combination of Calculation and Experimental Solid-State NMR Spectroscopy Yates, Jonathan R.; Pham, Tran N.; Pickard, Chris J. Journal of the American Chemical Society, Vol. 127, Issue 29 https://doi.org/10.1021/ja051019a	journal	July 2005
The Solid Electrolyte Interphase – The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries Winter, Martin Zeitschrift für Physikalische Chemie, Vol. 223, Issue 10-11 https://doi.org/10.1524/zpch.2009.6086	journal	December 2009
Self‐consistent molecular orbital methods. XX. A basis set for correlated wave functions Krishnan, R.; Binkley, J. S.; Seeger, R. The Journal of Chemical Physics, Vol. 72, Issue 1 https://doi.org/10.1063/1.438955	journal	January 1980
Effect of Heat Treatment on Si Electrodes Using Polyvinylidene Fluoride Binder Li, Jing; Christensen, L.; Obrovac, M. N. Journal of The Electrochemical Society, Vol. 155, Issue 3 https://doi.org/10.1149/1.2830545	journal	January 2008
Swept-frequency two-pulse phase modulation for heteronuclear dipolar decoupling in solid-state NMR Thakur, Rajendra Singh; Kurur, Narayanan D.; Madhu, P. K. Chemical Physics Letters, Vol. 426, Issue 4-6 https://doi.org/10.1016/j.cplett.2006.06.007	journal	August 2006
Chemical shift correlation spectroscopy in rotating solids: Radio frequency‐driven dipolar recoupling and longitudinal exchange Bennett, A. E.; Griffin, R. G.; Ok, J. H. The Journal of Chemical Physics, Vol. 96, Issue 11 https://doi.org/10.1063/1.462267	journal	June 1992
On the use of vinylene carbonate (VC) as an additive to electrolyte solutions for Li-ion batteries Aurbach, D.; Gamolsky, K.; Markovsky, B. Electrochimica Acta, Vol. 47, Issue 9 https://doi.org/10.1016/S0013-4686(01)00858-1	journal	February 2002
Real-Time NMR Investigations of Structural Changes in Silicon Electrodes for Lithium-Ion Batteries Key, Baris; Bhattacharyya, Rangeet; Morcrette, Mathieu Journal of the American Chemical Society, Vol. 131, Issue 26 https://doi.org/10.1021/ja8086278	journal	July 2009
Self‐consistent molecular orbital methods 25. Supplementary functions for Gaussian basis sets Frisch, Michael J.; Pople, John A.; Binkley, J. Stephen The Journal of Chemical Physics, Vol. 80, Issue 7 https://doi.org/10.1063/1.447079	journal	April 1984
Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes Ruffo, Riccardo; Hong, Seung Sae; Chan, Candace K. The Journal of Physical Chemistry C, Vol. 113, Issue 26, p. 11390-11398 https://doi.org/10.1021/jp901594g	journal	June 2009
Failure mechanisms of nano-silicon anodes upon cycling: an electrode porosity evolution model Radvanyi, Etienne; Porcher, Willy; De Vito, Eric Phys. Chem. Chem. Phys., Vol. 16, Issue 32 https://doi.org/10.1039/C4CP02324B	journal	January 2014
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Revealing lithium–silicide phase transformations in nano-structured silicon-based lithium ion batteries via in situ NMR spectroscopy Ogata, K.; Salager, E.; Kerr, C. J. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4217	journal	February 2014
Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy Nie, Mengyun; Chalasani, Dinesh; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 117, Issue 3, p. 1257-1267 https://doi.org/10.1021/jp3118055	journal	January 2013
Theoretical Studies To Understand Surface Chemistry on Carbon Anodes for Lithium-Ion Batteries: Reduction Mechanisms of Ethylene Carbonate Wang, Yixuan; Nakamura, Shinichiro; Ue, Makoto Journal of the American Chemical Society, Vol. 123, Issue 47 https://doi.org/10.1021/ja0164529	journal	November 2001
13C Solid State NMR Suggests Unusual Breakdown Products in SEI Formation on Lithium Ion Electrodes Leifer, N.; Smart, M. C.; Prakash, G. K. S. Journal of The Electrochemical Society, Vol. 158, Issue 5 https://doi.org/10.1149/1.3559551	journal	January 2011
Solvent Oligomerization during SEI Formation on Model Systems for Li-Ion Battery Anodes Tavassol, Hadi; Buthker, Joseph W.; Ferguson, Glen A. Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.067206jes	journal	January 2012
Structural Changes in Silicon Anodes during Lithium Insertion/Extraction Obrovac, M. N.; Christensen, Leif Electrochemical and Solid-State Letters, Vol. 7, Issue 5 https://doi.org/10.1149/1.1652421	journal	January 2004
Molecular Dynamics Simulations of Lithium Alkyl Carbonates Borodin, Oleg; Smith, Grant D.; Fan, Peng The Journal of Physical Chemistry B, Vol. 110, Issue 45 https://doi.org/10.1021/jp0639142	journal	November 2006

Similar Records

Thermal Decomposition of the Solid Electrolyte Interphase (SEI) on Silicon Electrodes for Lithium Ion Batteries

Journal Article · Fri Mar 17 00:00:00 EDT 2017 · Chemistry of Materials · OSTI ID:1234032

Yoon, Taeho; Milien, Mickdy S.; Parimalam, Bharathy S.; +1 more

Temperature-Dependent Solubility of Solid Electrolyte Interphase on Silicon Electrodes

Journal Article · Mon Oct 14 00:00:00 EDT 2019 · ACS Energy Letters · OSTI ID:1234032

Stetson, Caleb; Yin, Yanli; Jiang, Chun-Sheng; +5 more

Role of Surface Oxides in the Formation of Solid–Electrolyte Interphases at Silicon Electrodes for Lithium-Ion Batteries

Journal Article · Wed Dec 10 00:00:00 EST 2014 · ACS Applied Materials and Interfaces · OSTI ID:1234032

Schroder, Kjell W.; Dylla, Anthony G.; Harris, Stephen J.; +2 more

Title: Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products

Citation Formats

References (48)

Similar Records

Related Subjects