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Title: Dynamic crossover in deeply cooled water confined in MCM-41 at 4 kbar and its relation to the liquid-liquid transition hypothesis

Journal Article · · The Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.4930855· OSTI ID:1229671
 [1];  [1];  [1];  [2];  [3];  [1]
  1. Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
  2. National Institute of Standards and Technology Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA
  3. National Institute of Standards and Technology Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA, Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742, USA
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Sponsoring Organization:
USDOE
Grant/Contract Number:
FG02-90ER45429
OSTI ID:
1229671
Journal Information:
The Journal of Chemical Physics, Journal Name: The Journal of Chemical Physics Vol. 143 Journal Issue: 11; ISSN 0021-9606
Publisher:
American Institute of PhysicsCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 22 works
Citation information provided by
Web of Science

References (30)

Density and anomalous thermal expansion of deeply cooled water confined in mesoporous silica investigated by synchrotron X-ray diffraction journal August 2013
Suppression of the dynamic transition in surface water at low hydration levels: A study of water on rutile journal May 2009
Relation between the Widom line and the dynamic crossover in systems with a liquid-liquid phase transition journal November 2005
Viscosity of Several Liquid Hydrocarbons as a Function of Temperature, Pressure, and Free Volume journal April 1967
Temperature and Pressure Dependence of the Viscosity of the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluorophosphate journal September 2005
Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water journal April 1999
The dynamical crossover phenomenon in bulk water, confined water and protein hydration water journal January 2012
X‐ray and neutron scattering studies of the structure of water at a hydrophobic surface
  • Bellissent‐Funel, Marie‐Claire; Sridi‐Dorbez, Rachida; Bosio, Louis
  • The Journal of Chemical Physics, Vol. 104, Issue 24 https://doi.org/10.1063/1.471728
journal June 1996
Neutron spin echo measurements of monolayer and capillary condensed water in MCM-41 at low temperatures journal January 2012
Deeply-cooled water under strong confinement: neutron scattering investigations and the liquid–liquid critical point hypothesis journal January 2013
Phase behaviour of metastable water journal November 1992
Evidence of the existence of the low-density liquid phase in supercooled, confined water journal December 2006
The high-flux backscattering spectrometer at the NIST Center for Neutron Research journal May 2003
Pressure Dependence of Fragile-to-Strong Transition and a Possible Second Critical Point in Supercooled Confined Water journal September 2005
Relaxation Processes in Supercooled Confined Water and Implications for Protein Dynamics journal June 2006
Fragile-to-strong liquid transition in deeply supercooled confined water journal January 2004
Density hysteresis of heavy water confined in a nanoporous silica matrix journal July 2011
Model for single-particle dynamics in supercooled water journal June 1999
Boson Peak in Deeply Cooled Confined Water: A Possible Way to Explore the Existence of the Liquid-to-Liquid Transition in Water journal June 2014
Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures journal July 2014
Dynamical Transition of Protein-Hydration Water journal March 2010
Liquid–Liquid Phase Transition and Its Phase Diagram in Deeply-Cooled Heavy Water Confined in a Nanoporous Silica Matrix journal May 2015
Interplay of the Glass Transition and the Liquid-Liquid Phase Transition in Water journal May 2012
Dynamic Crossover in Supercooled Confined Water: Understanding Bulk Properties through Confinement journal January 2010
Hydration-dependent dynamics of deeply cooled water under strong confinement journal April 2013
Quasielastic and inelastic neutron scattering investigation of fragile-to-strong crossover in deeply supercooled water confined in nanoporous silica matrices journal August 2006
Comment on “Pressure Dependence of Fragile-to-Strong Transition and a Possible Second Critical Point in Supercooled Confined Water” journal November 2006
Chen, Liu, and Faraone Reply: journal November 2006
The fragile-to-strong dynamic crossover transition in confined water: nuclear magnetic resonance results journal April 2006
Comment on “Pressure Dependence of Fragile-to-Strong Transition and a Possible Second Critical Point in Supercooled Confined Water” journal November 2006

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