Study of the Thermoelectric Properties of Lead Selenide Doped with Boron, Gallium, Indium, or Thallium

Zhang, Qian; Cao, Feng; Lukas, K; Liu, W S; Esfarjani, Keivan; Opeil, C; Broido, D; Parker, David; Singh, David J.; Chen, Gang; Ren, Z. F.

doi:10.1021/ja307910u

Title: Study of the Thermoelectric Properties of Lead Selenide Doped with Boron, Gallium, Indium, or Thallium

Journal Article · Wed Oct 24 00:00:00 EDT 2012 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja307910u· OSTI ID:1080575

Zhang, Qian; Cao, Feng; Lukas, K; Liu, W S; Esfarjani, Keivan; Opeil, C; Broido, D; Parker, David; Singh, David J.; Chen, Gang; Ren, Z. F.

Group IIIA elements (B, Ga, In, and Tl) have been doped into PbSe for enhancement of thermoelectric properties. The electrical conductivity, Seebeck coefficient, and thermal conductivity were systematically studied. Room-temperature Hall measurements showed an effective increase in the electron concentration upon both Ga and In doping and the hole concentration upon Tl doping to 7 × 10{sup 19} cm{sup –3}. No resonant doping phenomenon was observed when PbSe was doped with B, Ga, or In. The highest room-temperature power factor 2.5 × 10{sup –3} W m{sup –1} K{sup –2} was obtained for PbSe doped with 2 atom % B. However, the power factor in B-doped samples decreased with increasing temperature, opposite to the trend for the other dopants. A figure of merit (ZT) of 1.2 at 873 K was achieved in PbSe doped with 0.5 atom % Ga or In. With Tl doping, modification of the band structure around the Fermi level helped to increase the Seebeck coefficient, and the lattice thermal conductivity decreased, probably as a result of effective phonon scattering by both the heavy Tl{sup 3+} ions and the increased grain boundary density after ball milling. The highest p-type ZT value was 1.0 at 723 K.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Solid-State Solar-Thermal Energy Conversion Center (S3TEC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001299; FG02-09ER46577

OSTI ID:: 1080575

Journal Information:: Journal of the American Chemical Society, Vol. 134; Related Information: S3TEC partners with Massachusetts Institute of Technology (lead); Boston College; Oak Ridge National Laboratory; Rensselaer Polytechnic Institute

Country of Publication:: United States

Language:: English

References (34)

MATERIALS SCIENCE: Enhanced: Thermoelectricity in Semiconductor Nanostructures Majumdar, A. Science, Vol. 303, Issue 5659 https://doi.org/10.1126/science.1093164	journal	February 2004
High-performance flat-panel solar thermoelectric generators with high thermal concentration Kraemer, Daniel; Poudel, Bed; Feng, Hsien-Ping Nature Materials, Vol. 10, Issue 7, p. 532-538 https://doi.org/10.1038/nmat3013	journal	May 2011
Convergence of electronic bands for high performance bulk thermoelectrics Pei, Yanzhong; Shi, Xiaoya; LaLonde, Aaron Nature, Vol. 473, Issue 7345, p. 66-69 https://doi.org/10.1038/nature09996	journal	May 2011
Stabilizing the Optimal Carrier Concentration for High Thermoelectric Efficiency Pei, Yanzhong; LaLonde, Aaron D.; Heinz, Nicholas A. Advanced Materials, Vol. 23, Issue 47 https://doi.org/10.1002/adma.201103153	journal	November 2011
Strained endotaxial nanostructures with high thermoelectric figure of merit Biswas, Kanishka; He, Jiaqing; Zhang, Qichun Nature Chemistry, Vol. 3, Issue 2 https://doi.org/10.1038/nchem.955	journal	January 2011
High Thermoelectric Performance in PbTe Due to Large Nanoscale Ag2Te Precipitates and La Doping Pei, Yanzhong; Lensch-Falk, Jessica; Toberer, Eric S. Advanced Functional Materials, Vol. 21, Issue 2 https://doi.org/10.1002/adfm.201000878	journal	November 2010
Reevaluation of PbTe1−xIx as high performance n-type thermoelectric material LaLonde, Aaron D.; Pei, Yanzhong; Snyder, G. Jeffrey Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01314a	journal	January 2011
Heavy Doping and Band Engineering by Potassium to Improve the Thermoelectric Figure of Merit in p-Type PbTe, PbSe, and PbTe _{1– y} Se _y Zhang, Qian; Cao, Feng; Liu, Weishu Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja301245b	journal	June 2012
Effect of Silicon and Sodium on Thermoelectric Properties of Thallium-Doped Lead Telluride-Based Materials Zhang, Qinyong; Wang, Hengzhi; Zhang, Qian Nano Letters, Vol. 12, Issue 5 https://doi.org/10.1021/nl3002183	journal	April 2012
Enhancement of Thermoelectric Efficiency in PbTe by Distortion of the Electronic Density of States Heremans, J. P.; Jovovic, V.; Toberer, E. S. Science, Vol. 321, Issue 5888, p. 554-557 https://doi.org/10.1126/science.1159725	journal	July 2008
Tuning the shape and thermoelectric property of PbTe nanocrystals by bismuth doping Zhang, Qian; Sun, Ting; Cao, Feng Nanoscale, Vol. 2, Issue 7 https://doi.org/10.1039/c0nr00115e	journal	January 2010
Doping-dependent thermopower of PbTe from Boltzmann transport calculations Singh, David J. Physical Review B, Vol. 81, Issue 19 https://doi.org/10.1103/PhysRevB.81.195217	journal	May 2010
Titanium forms a resonant level in the conduction band of PbTe König, Jan D.; Nielsen, Michele D.; Gao, Yi-Bin Physical Review B, Vol. 84, Issue 20 https://doi.org/10.1103/PhysRevB.84.205126	journal	November 2011
Thermoelectric Properties of In-Doped PbTe Guch, Mykhailo; Sankar, Cheriyedath Raj; Salvador, James Science of Advanced Materials, Vol. 3, Issue 4 https://doi.org/10.1166/sam.2011.1191	journal	August 2011
High thermoelectric figure of merit in heavy hole dominated PbTe Pei, Yanzhong; LaLonde, Aaron; Iwanaga, Shiho Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c0ee00456a	journal	January 2011
Chromium as resonant donor impurity in PbTe Nielsen, M. D.; Levin, E. M.; Jaworski, C. M. Physical Review B, Vol. 85, Issue 4 https://doi.org/10.1103/PhysRevB.85.045210	journal	January 2012
Mixed-valence impurities in lead telluride-based solid solutions Volkov, Boris A.; Ryabova, Ludmila I.; Khokhlov, Dmitrii R. Physics-Uspekhi, Vol. 45, Issue 8 https://doi.org/10.1070/PU2002v045n08ABEH001146	journal	August 2002
Low temperature thermal, thermoelectric, and thermomagnetic transport in indium rich Pb1−xSnxTe alloys Jovovic, V.; Thiagarajan, S. J.; Heremans, J. P. Journal of Applied Physics, Vol. 103, Issue 5 https://doi.org/10.1063/1.2890150	journal	March 2008
Thermoelectric property studies on thallium-doped lead telluride prepared by ball milling and hot pressing Yu, Bo; Zhang, Qinyong; Wang, Hui Journal of Applied Physics, Vol. 108, Issue 1 https://doi.org/10.1063/1.3452323	journal	July 2010
Thermoelectric transport properties of the $n$ -type impurity Al in PbTe Jaworski, Christopher M.; Heremans, Joseph P. Physical Review B, Vol. 85, Issue 3 https://doi.org/10.1103/PhysRevB.85.033204	journal	January 2012
High-temperature thermoelectric performance of heavily doped PbSe Parker, David; Singh, David J. Physical Review B, Vol. 82, Issue 3, Article No. 035204 https://doi.org/10.1103/PhysRevB.82.035204	journal	July 2010
Heavily Doped p-Type PbSe with High Thermoelectric Performance: An Alternative for PbTe Wang, Heng; Pei, Yanzhong; LaLonde, Aaron D. Advanced Materials, Vol. 23, Issue 11, p. 1366-1370 https://doi.org/10.1002/adma.201004200	journal	February 2011
High-temperature thermoelectric properties of $n$ -type PbSe doped with Ga, In, and Pb Androulakis, John; Lee, Yeseul; Todorov, Iliya Physical Review B, Vol. 83, Issue 19, Article No. 195209 https://doi.org/10.1103/PhysRevB.83.195209	journal	May 2011
High-temperature charge and thermal transport properties of the $n$ -type thermoelectric material PbSe Androulakis, John; Chung, Duck-Young; Su, Xianli Physical Review B, Vol. 84, Issue 15 https://doi.org/10.1103/PhysRevB.84.155207	journal	October 2011
Enhancement of thermoelectric figure-of-merit by resonant states of aluminium doping in lead selenide Zhang, Qinyong; Wang, Hui; Liu, Weishu Energy Environ. Sci., Vol. 5, Issue 1, p. 5246-5251 https://doi.org/10.1039/C1EE02465E	journal	January 2012
Exploring the doping effects of Ag in p-type PbSe compounds with enhanced thermoelectric performance Wang, Shanyu; Zheng, Gang; Luo, Tingting Journal of Physics D: Applied Physics, Vol. 44, Issue 47 https://doi.org/10.1088/0022-3727/44/47/475304	journal	November 2011
Features of the electrical compensation of bismuth impurities in PbSe Nemov, S. A.; Gavrikova, T. A.; Zykov, V. A. Semiconductors, Vol. 32, Issue 7 https://doi.org/10.1134/1.1187484	journal	July 1998
Transport and magnetic properties of dilute rare-earth–PbSe alloys Jovovic, V.; Thiagarajan, S. J.; West, J. Journal of Applied Physics, Vol. 102, Issue 4 https://doi.org/10.1063/1.2771048	journal	August 2007
The mobility of free carriers in PbSe crystals Schlichting, U.; Gobrecht, K. H. Journal of Physics and Chemistry of Solids, Vol. 34, Issue 4 https://doi.org/10.1016/S0022-3697(73)80183-0	journal	April 1973
Electronic structure and transport properties of doped PbSe Peng, Haowei; Song, Jung-Hwan; Kanatzidis, M. G. Physical Review B, Vol. 84, Issue 12 https://doi.org/10.1103/PhysRevB.84.125207	journal	September 2011
Resonant levels in bulk thermoelectric semiconductors Heremans, Joseph P.; Wiendlocha, Bartlomiej; Chamoire, Audrey M. Energy Environ. Sci., Vol. 5, Issue 2 https://doi.org/10.1039/C1EE02612G	journal	January 2012
Combining alloy scattering of phonons and resonant electronic levels to reach a high thermoelectric figure of merit in PbTeSe and PbTeS alloys Jaworski, Christopher M.; Wiendlocha, Bartlomiej; Jovovic, Vladimir Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01895g	journal	January 2011
Experimental Studies on Anisotropic Thermoelectric Properties and Structures of n-Type Bi₂Te_2.7Se_0.3 Yan, Xiao; Poudel, Bed; Ma, Yi Nano Letters, Vol. 10, Issue 9, p. 3373-3378 https://doi.org/10.1021/nl101156v	journal	September 2010
High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys Poudel, B.; Hao, Q.; Ma, Y. Science, Vol. 320, Issue 5876, p. 634-638 https://doi.org/10.1126/science.1156446	journal	May 2008

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Contrasting role of antimony and bismuth dopants on the thermoelectric performance of lead selenide Lee, Yeseul; Lo, Shih-Han; Chen, Changqiang Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4640	journal	May 2014
Towards a high thermoelectric performance in CdO ceramics by introducing multiscale scattering centers via ZnCO ₃ doping Zha, Xinyu; Gao, Linjie; Bai, Hongchang Materials Research Express, Vol. 5, Issue 3 https://doi.org/10.1088/2053-1591/aab5ee	journal	March 2018
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High thermoelectric performance by resonant dopant indium in nanostructured SnTe Zhang, Q.; Liao, B.; Lan, Y. Proceedings of the National Academy of Sciences, Vol. 110, Issue 33, p. 13261-13266 https://doi.org/10.1073/pnas.1305735110	journal	July 2013
Influence of periodic table in designing solid-state metal chalcogenides for thermoelectric energy conversion Rathore, Ekashmi; Dutta, Moinak; Biswas, Kanishka Journal of Chemical Sciences, Vol. 131, Issue 12 https://doi.org/10.1007/s12039-019-1704-8	journal	December 2019
Carrier tuning and multiple phonon scattering induced high thermoelectric performance in n-type Sb-doped PbTe alloys Liu, Hangtian; Chen, Zhiyu; Yin, Cong Applied Physics A, Vol. 125, Issue 4 https://doi.org/10.1007/s00339-019-2525-9	journal	March 2019
BiCuSeO oxyselenides: new promising thermoelectric materials Zhao, Li-Dong; He, Jiaqing; Berardan, David Energy Environ. Sci., Vol. 7, Issue 9 https://doi.org/10.1039/c4ee00997e	journal	January 2014
Combining the AFLOW GIBBS and elastic libraries to efficiently and robustly screen thermomechanical properties of solids Toher, Cormac; Oses, Corey; Plata, Jose J. Physical Review Materials, Vol. 1, Issue 1 https://doi.org/10.1103/physrevmaterials.1.015401	journal	June 2017
Higher mobility in bulk semiconductors by separating the dopants from the charge-conducting band – a case study of thermoelectric PbSe Wang, Heng; Cao, Xianlong; Takagiwa, Yoshiki Materials Horizons, Vol. 2, Issue 3 https://doi.org/10.1039/c5mh00021a	journal	January 2015
Enhancement of thermoelectric performance across the topological phase transition in dense lead selenide Chen, Liu-Cheng; Chen, Pei-Qi; Li, Wei-Jian Nature Materials, Vol. 18, Issue 12 https://doi.org/10.1038/s41563-019-0499-9	journal	October 2019
High-throughput computational screening of thermal conductivity, Debye temperature, and Grüneisen parameter using a quasiharmonic Debye model Toher, Cormac; Plata, Jose J.; Levy, Ohad Physical Review B, Vol. 90, Issue 17 https://doi.org/10.1103/physrevb.90.174107	journal	November 2014
Tuning the carrier scattering mechanism to effectively improve the thermoelectric properties Shuai, Jing; Mao, Jun; Song, Shaowei Energy & Environmental Science, Vol. 10, Issue 3 https://doi.org/10.1039/c7ee00098g	journal	January 2017
Enhancing Thermoelectric Performance of PbSe by Se Vacancies Liu, Yefeng; You, Li; Wang, Chenyang Journal of Electronic Materials, Vol. 47, Issue 5 https://doi.org/10.1007/s11664-017-6040-5	journal	February 2018
Enhancement of Thermoelectric Performance of n-Type PbSe by Cr Doping with Optimized Carrier Concentration Zhang, Qian; Chere, Eyob Kebede; McEnaney, Kenneth Advanced Energy Materials, Vol. 5, Issue 8 https://doi.org/10.1002/aenm.201401977	journal	January 2015
Boosting the thermoelectric performance of PbSe through dynamic doping and hierarchical phonon scattering You, Li; Liu, Yefeng; Li, Xin Energy & Environmental Science, Vol. 11, Issue 7 https://doi.org/10.1039/c8ee00418h	journal	January 2018
Thermoelectric GeTe with Diverse Degrees of Freedom Having Secured Superhigh Performance Hong, Min; Zou, Jin; Chen, Zhi‐Gang Advanced Materials, Vol. 31, Issue 14 https://doi.org/10.1002/adma.201807071	journal	February 2019
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