Identification of solid-state forms of cucurbit[6]uril for carbon dioxide capture
Journal Article
·
· CrystEngComm, 15(8):1528-1531
Three novel crystalline forms of cucurbit[6]uril (CB[6], 1) have been identified by fine control over the mixing process of the hydrochloride solution of CB[6] with ethanol. The form that exists in nanoplate particles shows permanent porosity upon desolvation and the highest CO2 uptake (15 wt%) at 298 K and 1 bar among any known solid-state forms of CB[6].
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1068644
- Report Number(s):
- PNNL-SA-92716; KC0203020
- Journal Information:
- CrystEngComm, 15(8):1528-1531, Journal Name: CrystEngComm, 15(8):1528-1531
- Country of Publication:
- United States
- Language:
- English
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