Visible light responsive iodine-doped TiO2 for photocatalytic reduction of CO2 to fuels

Zhang, Qianyi; Li, Ying; Ackerman, Erik A.; Gajdardziska-Josifovska, Marija; Li, Hailong

doi:10.1016/j.apcata.2011.04.032

Title: Visible light responsive iodine-doped TiO₂ for photocatalytic reduction of CO₂ to fuels

Journal Article · Wed Jun 01 00:00:00 EDT 2011 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2011.04.032· OSTI ID:1051024

Zhang, Qianyi; Li, Ying; Ackerman, Erik A.; Gajdardziska-Josifovska, Marija; Li, Hailong

Iodine-doped titanium oxide (I-TiO₂) nanoparticles that are photocatalitically responsive to visible light illumination have been synthesized by hydrothermal method. The structure and properties of I-TiO₂ nanocrystals prepared with different iodine doping levels and/or calcination temperatures were characterized by X-ray diffraction, transmission electron microscopy and diffraction, X-ray photoelectron spectroscopy, and UV-vis diffuse reflectance spectra. The three nominal iodine dopant levels (5, 10, 15 wt.%) and the two lower calcination temperatures (375, 450°C) produced mixture of anatase and brookite nanocrystals, with small fraction of rutile found at 550°C. The anatase phase of TiO₂ increased in volume fraction with increased calcination temperature and iodine levels. The photocatalytic activities of the I-TiO₂ powders were investigated by photocatalytic reduction of CO₂ with H₂O under visible light (λ > 400 nm) and also under UV-vis illumination. CO was found to be the major photoreduction product using both undoped and doped TiO₂. A high CO₂ reduction activity was observed for I-TiO² catalysts (highest CO yield equivalent to 2.4 micro mol g^-1 h^-1) under visible light, and they also had much higher CO₂ photoreduction efficiency than undoped TiO₂ under UV-vis irradiation. I-TiO₂ calcined at 375°C has superior activity to those calcined at higher temperatures. Optimal doping levels of iodine were identified under visible and UV-vis irradiations, respectively. This is the first study that investigates nonmetal doped TiO² without other co-catalysts for CO₂ photoreduction to fuels under visible light.

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Research Organization:: Univ. of Wisconsin, Milwaukee, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: FG02-06ER46328

OSTI ID:: 1051024

Report Number(s):: DOE/ER/46328-5

Journal Information:: Applied Catalysis. A, General, Vol. 400, Issue 1-2; ISSN 0926-860X

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

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Title: Visible light responsive iodine-doped TiO2 for photocatalytic reduction of CO2 to fuels

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Title: Visible light responsive iodine-doped TiO₂ for photocatalytic reduction of CO₂ to fuels