CsSnI[subscript 3]: Semiconductor or Metal? High Electrical Conductivity and Strong Near-Infrared Photoluminescence from a Single Material. High Hole Mobility and Phase-Transitions

Journal Article · Mon Oct 29 00:00:00 EDT 2012 · J. Am. Chem. Soc.

DOI:https://doi.org/10.1021/ja301539s· OSTI ID:1047915

Chung, In; Song, Jung-Hwan; Im, Jino; Androulakis, John; Malliakas, Christos D; Li, Hao; Freeman, Arthur J; Kenney, John T; Kanatzidis, Mercouri G ^[1]

---

1. NWU

CsSnI{sub 3} is an unusual perovskite that undergoes complex displacive and reconstructive phase transitions and exhibits near-infrared emission at room temperature. Experimental and theoretical studies of CsSnI{sub 3} have been limited by the lack of detailed crystal structure characterization and chemical instability. Here we describe the synthesis of pure polymorphic crystals, the preparation of large crack-/bubble-free ingots, the refined single-crystal structures, and temperature-dependent charge transport and optical properties of CsSnI{sub 3}, coupled with ab initio first-principles density functional theory (DFT) calculations. In situ temperature-dependent single-crystal and synchrotron powder X-ray diffraction studies reveal the origin of polymorphous phase transitions of CsSnI{sub 3}. The black orthorhombic form of CsSnI{sub 3} demonstrates one of the largest volumetric thermal expansion coefficients for inorganic solids. Electrical conductivity, Hall effect, and thermopower measurements on it show p-type metallic behavior with low carrier density, despite the optical band gap of 1.3 eV. Hall effect measurements of the black orthorhombic perovskite phase of CsSnI{sub 3} indicate that it is a p-type direct band gap semiconductor with carrier concentration at room temperature of {approx} 10{sup 17} cm{sup -3} and a hole mobility of {approx} 585 cm{sup 2} V{sup -1} s{sup -1}. The hole mobility is one of the highest observed among p-type semiconductors with comparable band gaps. Its powders exhibit a strong room-temperature near-IR emission spectrum at 950 nm. Remarkably, the values of the electrical conductivity and photoluminescence intensity increase with heat treatment. The DFT calculations show that the screened-exchange local density approximation-derived band gap agrees well with the experimentally measured band gap. Calculations of the formation energy of defects strongly suggest that the electrical and light emission properties possibly result from Sn defects in the crystal structure, which arise intrinsically. Thus, although stoichiometric CsSnI{sub 3} is a semiconductor, the material is prone to intrinsic defects associated with Sn vacancies. This creates highly mobile holes which cause the materials to appear metallic.

• Research Organization: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
• Sponsoring Organization: National Science Foundation (NSF)
• OSTI ID: 1047915
• Journal Information: J. Am. Chem. Soc., Vol. 134, Issue (20) ; 05, 2012; ISSN 0002-7863
• Country of Publication: United States
• Language: ENGLISH

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARRIER DENSITY
CHARGE TRANSPORT
CRYSTAL STRUCTURE
DEFECTS
ELECTRIC CONDUCTIVITY
FUNCTIONALS
HALL EFFECT
HEAT TREATMENTS
HOLE MOBILITY
INSTABILITY
OPTICAL PROPERTIES
ORIGIN
PEROVSKITE
PHOTOLUMINESCENCE
SYNCHROTRONS
SYNTHESIS
THERMAL EXPANSION
VACANCIES
X-RAY DIFFRACTION